International Journal of Electrochemical Science,
Journal Year:
2023,
Volume and Issue:
18(12), P. 100390 - 100390
Published: Oct. 21, 2023
Due
to
its
advantageous
features,
the
electrochemical
technique
has
garnered
considerable
attention
in
detecting
4-nitrophenol
(4-NP).
And
modified
materials
of
such
working
electrode
significantly
influence
sensitivity
sensor.
In
this
investigation,
a
sensitive
and
selective
sensor
for
4-NP
real
water
samples
was
developed
by
using
spherical
onion-like
carbon
(OLC)
as
new
material
modification.
By
comparing
with
generally
used
nanotube
(CNT),
OLC
exhibits
higher
electroactive
surface
area
conductibility.
The
glassy
(OLC/GCE)
CNT
GCE
(CNT/GCE)
determined
be
0.1508
cm2
0.1231
respectively.
Notably,
OLC/GCE
(Ipc:-139
μA)
exhibited
reduction
peak
current
contrast
CNT/GCE
(Ipc:-94
cyclic
voltammetry
test.
Remarkably,
under
ideal
conditions,
displayed
linear
detection
range
spanning
from
0.05
120
μM,
an
exceptionally
low
identifying
limit
3.74
nM.
addition,
excellent
selectivity,
reproducibility,
repeatability
determining
4-NP.
response
remains
about
92%
primal
value
15
days
later,
demonstrating
outstanding
stability
OLC/GCE.
Furthermore,
successfully
employed
authentic
samples,
yielding
satisfactory
recovery
rates
ranging
96.14%
102.1%.
This
investigation
exemplifies
sensing
capabilities
promising
potential
field
electrochemically
environmental
settings,
which
provides
method
simple,
quantitative
ACS Omega,
Journal Year:
2024,
Volume and Issue:
9(31), P. 33335 - 33350
Published: July 25, 2024
This
review
emphasizes
the
progress
in
identifying
and
eliminating
para-nitrophenol
(4-NP),
a
toxic
organic
compound.
It
covers
various
strategical
methods
materials,
including
inorganic
nanomaterials,
for
detecting
reducing
4-NP.
Detection
techniques
such
as
electrochemical
methods.
Optical
fiber-based
surface
plasmon
resonance
photoluminescence,
well
mechanisms
of
Förster
Resonance
Energy
Transfer
(FRET)
Inner
Filter
Effect
(IFE)
fluorescence
detection,
are
presented.
Removal
this
contaminant
include
homogeneous
catalysis,
electrocatalysis,
photocatalysis,
thermocatalysis,
their
reaction
also
discussed.
Further,
theoretical
perspectives
4-NP
detection
reduction,
parameters
influencing
activities,
future
reviewed
detail.
Chemical Physics Impact,
Journal Year:
2024,
Volume and Issue:
8, P. 100619 - 100619
Published: April 25, 2024
Due
to
the
dearth
of
extremely
capable,
sensitive,
and
stable
catalysts,
efficient
detection
catalytic
removal
4-nitrophenol
(4-NP)
in
industrial
wastewater
remains
a
serious
challenge.
The
determination
presence
environment
is
matter
paramount
importance
because
it
high-priority
hazardous
pollutant
that
can
affect
people,
animals,
plants.
Here,
we
present
promising
economically
viable
green
synthetic
route
for
fabricating
CuFe2O4
CuFe2O4@Ag
hybrid
nanocomposites
from
leaf
extract
Senna
didymobotrya.
UV–Vis,
FTIR,
XRD,
FE-SEM,
EDXA,
BET
VSM
analysis
were
performed
characterize
synthesis
nanocomposite.
To
evaluate
electrocatalytic
capacity
CuFe2O4@Ag,
electrochemical
sensing
stratergy
was
with
cyclic
voltammetry
(CV)
differential
pulse
(DPV).
modified
glassy
carbon
electrode
(GCE)
(CuFe2O4@Ag/GCE)
demonstrated
linear
response
range
0.01-15
μg/ml
(71
nm-107
μM)
ability
detect
4-NP
at
low
concentration
(0.006
(43
nM)).
increased
surface
area
CuFe2O4@Ag/GCE
by
̴
1.5-fold,
greater
cathodic
current
(-16
μA/cm2)
potential
-0.81
V
observed
compared
CuFe2O4/GCE
alone
4-NP.
Additonally,
showed
excellent
reduction
towards
using
NaBH4
an
efficiency
96.4
%
which
higher
than
(only
87.3
%)
12
min
due
synergistic
relationship
among
Ag
NPs
nanostructures.
outcomes
this
study
shows
bi-functional
electrocatalyst
holds
vast
environmental
remediation.
Chemosensors,
Journal Year:
2023,
Volume and Issue:
11(7), P. 390 - 390
Published: July 13, 2023
4-nitrophenol
(4-NP)
is
one
of
the
organic
pollutants
that
can
come
up
from
pesticides,
explosives,
dyes,
and
pharmaceutical
industries.
Since
it
be
extremely
harmful
to
humans
other
living
organisms,
crucial
have
a
system
effectively
detect
presence
4-NP.
Here,
we
report
microplasma
synthesis
nitrogen-doped
graphene
quantum
dots
(N-GQDs)
for
fluorescence-based
detection
Through
Förster
resonance
energy
transfer
(FRET)
between
donor
N-GQDs
acceptor
4-NP,
synthesized
employed
4-NP
starting
0.5
100
µM
with
limit
as
low
95.14
nM.
also
demonstrates
remarkable
stability
over
all
pH
values
wide
temperatures
(10–60
°C),
indicating
high
possibility
robust
pollution
monitoring.
Our
work
provides
insight
into
simple,
fast,
environmentally
friendly
method
synthesizing
at
ambient
conditions
usable
environmental
nanosensors.