Decorated and sculpted zeolitic imidazolate frameworks for electrocatalytic carbon dioxide reduction to formate DOI
Yan-Hong Zou, Yayu Guan, Yuyu Liu

et al.

Journal of Electroanalytical Chemistry, Journal Year: 2024, Volume and Issue: 966, P. 118400 - 118400

Published: June 1, 2024

Language: Английский

In-situ constructing Bi@Bi2O2CO3 nanosheet catalyst for ampere-level CO2 electroreduction to formate DOI

Xiao-Du Liang,

Qizheng Zheng,

Nian Wei

et al.

Nano Energy, Journal Year: 2023, Volume and Issue: 114, P. 108638 - 108638

Published: June 25, 2023

Language: Английский

Citations

49
MOF-based materials for electrochemical reduction of carbon dioxide DOI

Jian-Mei Huang,

Xiang‐Da Zhang,

Jiayi Huang

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 494, P. 215333 - 215333

Published: July 28, 2023

Language: Английский

Citations

45
Revealing the Intrinsic Restructuring of Bi2O3 Nanoparticles into Bi Nanosheets during Electrochemical CO2 Reduction DOI Creative Commons
Beatriz Ávila‐Bolívar, Mauricio López Luna, Fengli Yang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(9), P. 11552 - 11560

Published: Feb. 26, 2024

Bismuth is a catalyst material that selectively produces formate during the electrochemical reduction of CO

Language: Английский

Citations

12
A review of electroreduction of CO2 to C1 products: Catalysts design, characterizations and performance evaluation DOI
Chang Cui, Qing Cao, Hongyu Jing

et al.

Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: 48, P. 104353 - 104353

Published: April 16, 2024

Language: Английский

Citations

10
Integrated strategies on cobalt phosphides-based electrocatalysts for efficient hydrogen evolution reaction DOI
Thanh Dam, Ha Huu

Tungsten, Journal Year: 2024, Volume and Issue: 6(3), P. 488 - 503

Published: Feb. 28, 2024

Language: Английский

Citations

8
Formate‐Mediated Electroenzymatic Synthesis via Biological Cofactor NADH DOI
Chuanjun Wang, Wenjin Dong,

Pengye Zhang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(41)

Published: July 22, 2024

Abstract Synthetic biohybrid systems by coupling artificial system with nature's machinery may offer a disruptive solution to address the global energy crisis. We developed versatile electroenzymatic pathway for continuous synthesis of valuable chemicals, facilitated formate‐driven NADH regeneration. Utilizing bismuth electrocatalyst, we achieved stable CO 2 reduction formate approximately 90 % Faraday efficiency at current density 150 mA cm −2 . The generated acts as mediator regenerate NADH, which is then coupled immobilized redox enzymes—alcohol dehydrogenase (ADH), L ‐lactate (LDH), and ‐glutamate (GDH)—to produce targeted chemicals significant rates exceptionally high turnover numbers (1.8×10 6 3.1×10 ). These achievements not only underscore but also its practical applicability in industrial settings. By leveraging situ formate, this innovative approach demonstrates potential integrating electrocatalysis enzymatic reactions sustainable efficient chemical production on scale.

Language: Английский

Citations

8
In-situ electrochemical transformation of F-modified metallic bismuth for highly-efficient CO2 electroreduction and Zn-CO2 battery DOI
Wenbo Wu, Yun Tong, Yutong Ye

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 494, P. 153105 - 153105

Published: June 13, 2024

Language: Английский

Citations

7
Vanadium Oxide Clusters Mediated Bismuth‐Tin Alloy for Accelerated Dynamics of Electrocatalytic CO2 Conversion DOI Open Access

Jiaye Zhu,

Guorong Zhou, Yun Tong

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 16, 2024

Abstract The electrocatalytic conversion of carbon dioxide (CO 2 ) to formate is significant for neutrality. How improve the reaction kinetics electrocatalysts one important challenges. An innovative electrodeposition strategy presented herein rationally synthesize vanadium oxide (VO x clusters decorated Bi‐Sn alloy (BiSn(VO )) catalyst. Theoretical and in situ spectral studies confirm simultaneously improved CO activation subsequent protonation via VO mediated water dissociation process, thereby optimizing activity selectivity formate. Remarkably, this BiSn(VO catalyst achieves high Faradic efficiency (FE) over 90% within wide potential window 800 mV excellent stability 100 h at −0.6 V versus RHE. Moreover, cathode integrated rechargeable Zn‐CO battery realizes largest power density 3.8 mW cm −2 , while assembled co‐electrolysis electrolyzer delivers a total FE 182% cell voltage 0.6 V, outperforming highest value so far. work provides promising way develop advanced electrolysis.

Language: Английский

Citations

7
Tuning strategies and electrolyzer design for Bi-based nanomaterials towards efficient CO2 reduction to formic acid DOI
Di Wang, Qingsong Chen,

Yiran Lin

et al.

Chinese Journal of Structural Chemistry, Journal Year: 2024, Volume and Issue: 43(8), P. 100346 - 100346

Published: May 21, 2024

Language: Английский

Citations

6
Surface‐Enriched Room‐Temperature Liquid Bismuth for Catalytic CO2 Reduction DOI Creative Commons
J.-D. Guo, Xing Zhi, Dingqi Wang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: May 15, 2024

Bismuth-based electrocatalysts are effective for carbon dioxide (CO

Language: Английский

Citations

5