IPr^# Complexes─Highly-Hindered, Sterically-Bulky Cu(I) and Ag(I) N-Heterocyclic Carbenes: Synthesis, Characterization, and Reactivity

Organometallics, Journal Year: 2024, Volume and Issue: 43(19), P. 2305 - 2313

Published: Sept. 21, 2024

Metal-N-heterocyclic carbene (M-NHC) complexes are well-known as an important class of organometallic compounds widely used in transition-metal catalysis. Taking into account that the steric hindrance around metal center is one major effects M-NHC catalysis, development new, sterically hindered ongoing interest this field research. Herein, we report synthesis and characterization exceedingly hindered, well-defined, air- moisture-stable Cu(I) Ag(I) complexes, [Cu(NHC)Cl] [Ag(NHC)Cl], recently discovered IPr

Language: Английский

Sustainable and Advanced LED-Implanted Microfluidic Photoreactor with Coupled Optical Fiber Enabling Efficient Photocatalytic Synthesis Beside Online Reaction Progress Monitoring

ACS Omega, Journal Year: 2024, Volume and Issue: 9(41), P. 42267 - 42277

Published: Oct. 4, 2024

The conventional methods for the photoinduced synthesis of benzimidazoles may need further improvement regarding a safer and energy-efficient platform with in-process monitoring maximum yield within much reduced reaction time. This work describes use novel optofluidic Lab-on-a-Chip technology safer, energy-efficient, expedited benzimidazole derivatives in excellent yields along real-time quantitative measurement during product formation. innovative method involves LED-embedded microfluidic reactors, allowing rapid via condensation cyclization reactions aryl aldehydes

Language: Английский

Facile synthesis of substituted 2-styrylnaphthyridine and its derivatives via sp3C-H functionalization under mild conditions and their antimicrobial activity and Electrochemical properties.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1324, P. 140604 - 140604

Published: Nov. 8, 2024

Language: Английский