Comments on Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown, P. 1 - 35
Published: March 28, 2024
Silver
orthophosphate
(Ag3PO4)
and
its
analogues
based
on
metal
oxides
are
promising
materials
for
improving
the
photocatalytic
activity
of
organic
transformations.
This
study
provides
a
concise
overview
distinctive
characteristics
diverse
range
uses
Ag3PO4
composites
in
field
photocatalysis.
discussion
concerns
synthesis
with
along
an
examination
structural
electrical
properties.
is
first
catalyzed
transformations
highlights
significance
identifying
optimal
settings
these
variables
to
enhance
catalytic
activity.
The
main
goal
this
was
determine
how
well
different
forms
work
as
photocatalysts
various
changes.
These
changes
include
creation
heterocyclic
compounds
oxidation,
coupling,
esterification,
reduction
reactions.
review
focuses
elucidating
mechanisms
underlying
their
ability
utilize
light
energy
effectively
chemical
investigation
using
photocatalyst
future
may
help
scientific
community
compounds.
Rib
fracture-related
infection
is
a
challenging
complication
of
thoracic
trauma
due
to
the
difficulty
treating
it
with
antibiotics
alone
and
need
for
second
operation
remove
infected
fixator
sterilize
surrounding
tissue.
In
this
study,
inspired
by
photocatalytic
performance
ion
release
from
silver-based
materials,
including
Ag3PO4
Ag2S,
hybrid
Ag3PO4-Ag2S
heterojunction
was
prepared
based
on
in
situ
anion
exchange
one-step
calcination
process
design
nonantibiotic
coating
aimed
at
preventing
rib
short-term
808
nm
near-infrared
irradiation.
Calcination
250
°C
enhanced
inductive
effect
phosphate
radical
led
formation
tight
nanoheterogeneous
interface
between
thereby
promoting
interfacial
electron
transfer
reducing
recombination
photogenerated
carriers.
The
result
improved
photodynamic
coating.
Moreover,
metal-Ag3PO4-Ag2S
had
significant
photothermal
released
only
small
amount
Ag+.
synergy
endowed
high
antibacterial
efficacy,
eliminating
99.90
±
0.05
99.95
0.03%
Staphylococcus
aureus
Escherichia
coli,
respectively,
after
15
min
NIR
irradiation
vitro,
99.66
0.13%
vivo.
This
biocompatible
exhibited
superb
efficacy
associated
inflammation.
