Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
32(28)
Published: April 28, 2022
Abstract
Conductive
hydrogels
have
shown
great
promise
in
the
field
of
sustainable
power
sources
due
to
their
unique
features
sufficient
flexibility,
durability,
and
functional
diversification.
However,
time‐
energy‐consuming
polymerization
process
poor
adaptability
extreme
environments
severely
impede
practical
application
such
an
emerging
field.
Herein,
a
facile
universal
self‐catalytic
system
(AL‐Cu
2+
)
based
on
alkali
lignin
(AL)
macromolecule
has
been
designed
rapidly
fabricate
conductive
transparent
organohydrogels
alkaline
water–ethylene
glycol
(EG)
binary
solvent,
which
displays
environment
applicability
(‒40
60
°C),
eligible
stretchability
(≈800%
elongation),
robust
self‐adhesion
(≈31.4
kPa).
Interestingly,
introduced
EG
accelerates
polymerization,
endows
freezing/drying
resistance,
improves
for
organohydrogels.
The
organohydrogel
(water/EG
=
2/3)
that
combines
above
merits
inspires
construction
triboelectric
nanogenerator
(O‐TENG)
mechanical
energy
harvesting
converting
regardless
low‐
or
high‐temperature
environments.
generated
electricity
by
O‐TENG
can
be
used
directly
stored
drive
commercial
electronics
installed
human
joints
movement
monitoring.
This
work
sheds
light
designing
environment‐resistant
flexible
TENGs
multifunctional
soft
materials
with
fast
gelation
strategy,
provoking
more
attention
high‐value
utilization
advanced
applications.
Small,
Journal Year:
2021,
Volume and Issue:
18(5)
Published: Oct. 17, 2021
Abstract
Conductive
hydrogels
can
be
prepared
by
incorporating
various
conductive
materials
into
polymeric
network
hydrogels.
In
recent
years,
have
been
developed
and
applied
in
the
field
of
strain
sensors
owing
to
their
unique
properties,
such
as
electrical
conductivity,
mechanical
self‐healing,
anti‐freezing
properties.
These
remarkable
properties
allow
hydrogel‐based
show
excellent
performance
for
identifying
external
stimuli
detecting
human
body
movement,
even
at
subzero
temperatures.
This
review
summarizes
application
fabrication
working
different
modes.
Finally,
a
brief
prospectus
development
future
is
provided.
Materials Horizons,
Journal Year:
2020,
Volume and Issue:
8(2), P. 351 - 369
Published: Sept. 3, 2020
As
one
of
the
most
outstanding
materials,
analysis
structure
and
function
hydrogels
has
been
extensively
carried
out
to
tailor
adapt
them
various
fields
application.
The
high
water
content,
which
is
beneficial
for
plenty
applications
in
biomedical
setting,
prevents
adoption
flexible
electronics
sensors
real
life
applications,
because
lose
their
excellent
properties,
including
conductivity,
transparency,
flexibility,
etc.,
upon
freezing
at
sub-zero
temperatures.
Therefore,
depressing
liquid-solid
phase
transition
temperature
a
powerful
means
expand
application
scope
hydrogels,
will
benefit
chemical
engineering
materials
science
communities.
This
review
summarizes
recent
research
progress
anti-freezing
hydrogels.
At
first,
approaches
generation
(hydro)gels
are
introduced
mechanisms
performances
briefly
discussed.
These
either
based
on
addition
salts,
alcohols
(cryoprotectants
organohydrogels),
ionic
liquids
(ionogels),
modification
polymer
network
or
combination
several
techniques.
Then,
concise
overview
leveraged
by
widened
resistance
provided
future
areas
developments
envisaged.
Advanced Materials,
Journal Year:
2020,
Volume and Issue:
32(8)
Published: Jan. 19, 2020
Stretchable
conductive
fibers
are
key
elements
for
next-generation
flexible
electronics.
Most
existing
electron-based,
opaque,
relatively
rigid,
and
show
a
significant
increase
in
resistance
during
stretching.
Accordingly,
soft,
stretchable,
transparent
ion-conductive
hydrogel
have
attracted
attention.
However,
difficult
to
manufacture
easy
dry
freeze,
which
significantly
hinders
their
wide
range
of
applications.
Herein,
organohydrogel
designed
address
these
challenges.
First,
newly
hybrid
crosslinking
strategy
continuously
wet-spins
fibers,
transformed
into
by
simple
solvent
replacement.
The
excellent
antifreezing
(<
-80
°C)
capability,
stability
(>5
months),
transparency,
stretchability.
predominantly
covalently
crosslinked
network
ensures
the
high
dynamic
mechanical
with
negligible
hysteresis
creep,
from
previous
usually
suffer.
strain
sensors
made
accurately
capture
high-frequency
(4
Hz)
high-speed
(24
cm
s-1
)
motion
exhibit
little
drift
1000
stretch-release
cycles,
powerful
detecting
rapid
cyclic
motions
such
as
engine
valves
reach
previously
reported
fibers.
also
demonstrate
potential
wearable
anisotropic
sensors,
data
gloves,
soft
electrodes,
optical
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
31(24)
Published: April 8, 2021
Abstract
Conductive
hydrogels
(CHs)
have
been
highlighted
in
the
design
of
flexible
strain
sensors
and
stretchable
triboelectric
nanogenerators
(TENGs)
on
basis
their
excellent
physicochemical
properties
such
as
large
stretchability
high
conductivity.
Nevertheless,
incident
freezing
drying
behaviors
CHs
by
using
water
solvent
dispersion
medium
limit
application
scopes
significantly.
Herein,
an
environment
tolerant
ultrastretchable
organohydrogel
is
demonstrated
a
simple
solvent‐replacement
strategy,
which
partial
as‐synthesized
polyacrylamide/montmorillonite/carbon
nanotubes
hydrogel
replaced
with
glycerol,
leading
to
temperature
toleration
(−60
60
°C)
good
stability
(30
days
under
normal
environment)
without
sacrificing
The
exhibits
ultrawide
sensing
range
(0–4196%)
sensitivity
8.5,
enabling
effective
detection
discrimination
human
activities
that
are
gentle
or
drastic
various
conditions.
Furthermore,
assembled
single‐electrode
TENG,
displays
energy
harvesting
ability
even
500%
robustness
directly
power
wearable
electronics
harsh
cold
This
work
inspires
route
for
multifunctional
promises
practical
self‐powered
devices
extreme
environments.
EcoMat,
Journal Year:
2020,
Volume and Issue:
2(4)
Published: Oct. 11, 2020
Abstract
Triboelectric
nanogenerator
(TENG)
technology
is
a
promising
research
field
for
energy
harvesting
and
nanoenergy
nanosystem
(NENS)
in
the
aspect
of
mechanical,
electrical,
optical,
acoustic,
fluidic,
so
on.
This
review
systematically
reports
progress
TENG
technology,
terms
energy‐boosting,
emerging
materials,
self‐powered
sensors,
NENS,
its
further
integration
with
other
potential
technologies.
Starting
from
mechanisms
including
ways
charge
generation
we
introduce
applications
harvesters
to
various
kinds
that
is,
physical
chemical/gas
sensors.
After
that,
NENS
are
discussed,
such
as
blue
energy,
human‐machine
interfaces
(HMIs),
neural
interfaces/implanted
devices,
optical
interface/wearable
photonics.
Moving
new
directions
beyond
TENG,
depict
hybrid
technologies,
dielectric‐elastomer‐enhancement,
self‐healing,
shape‐adaptive
capability,
self‐sustained
and/or
internet
things
(IoT).
Finally,
outlooks
conclusions
about
future
development
trends
technologies
discussed
toward
multifunctional
intelligent
systems.
image
ACS Applied Bio Materials,
Journal Year:
2020,
Volume and Issue:
4(1), P. 85 - 121
Published: Aug. 17, 2020
Natural
biopolymer-based
conductive
hydrogels,
which
combine
inherent
renewable,
nontoxic
features,
biocompatibility
and
biodegradability
of
biopolymers,
excellent
flexibility
conductivity
exhibit
great
potential
in
applications
wearable
stretchable
sensing
devices.
Compared
to
traditional
flexible
substrates
deriving
from
petro-materials-derived
polymers,
hydrogels
consisting
continuous
cross-linked
polymer
networks
a
large
amount
water
more
fantastic
combination
stretchability
because
their
endow
the
with
mechanical
offers
them
consecutive
ionic
transport
property.
Different
biopolymers
that
are
extracted
bioresource
intrinsic
commonly
considered
as
appropriate
candidates
for
constructing
For
example,
such
cellulose,
chitosan,
silk
fibroin
usually
chosen
promising
construct
endowing
enhanced
properties
remarkable
biocompatibility.
This
review
summarizes
recent
progress
natural
utilized
electrical
devices
series
typical
including
fibroin,
gelatin.
The
chemical
structures
physicochemical
four
demonstrated,
diverse
hydrogel
sensors
discussed
detail.
Finally,
remaining
challenges
expectations
discussed.