ChemElectroChem,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 10, 2024
Abstract
In
the
present
work,
novel
composite
material
comprising
of
corn
husk
derived
activated
carbon
and
siloxene
nanosheets
have
been
explored
as
new
class
multicomponent
electrode
for
fabricating
high
energy
density
supercapacitors
with
wide
temperature
tolerance.
The
obtained
from
(ACH–900)
surface
area
pore
volume
acts
an
ideal
framework
hosting
(S)
that
allows
overall
siloxene–corn
(ACH–900/S)
to
deliver
excellent
electrochemical
performance.
as‐prepared
ACH–900/S
exhibited
a
specific
capacitance
415
F
g
−1
at
0.25
A
retained
73.4
%
its
initial
even
current
30
in
1
M
Na
2
SO
4
electrolyte.
addition,
symmetric
supercapacitor
assembled
“acetonitrile/water‐in‐salt
(AWIS)”
electrolyte
57.2
W
h
kg
338
cyclic
stability
92.8
after
10000
cycles
5
density.
Besides,
fabricated
can
operate
over
range
0
100
°C.
This
work
opens
up
frontiers
develop
low‐cost
safe
tolerance
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(23)
Published: Feb. 27, 2024
Ionic
liquids
and
their
various
analogues
are
without
doubt
the
scientific
sensation
of
last
few
decades,
paving
way
to
a
more
sustainable
society.
Their
versatile
suite
properties,
originating
from
an
almost
inconceivably
large
number
possible
cation
anion
combinations,
allows
tuning
structure
serve
desired
purpose.
hence
offer
myriad
useful
applications
solvents
catalysts,
through
lubricants,
gas
absorbers,
azeotrope
breakers.
The
purpose
this
review
is
explore
unexpected
these
applications,
particularly
in
energy
space.
It
guides
reader
application
ionic
as
i)
phase
change
materials
for
thermal
storage,
ii)
organic
plastic
crystals,
which
have
been
studied
battery
electrolytes
separation,
iii)
key
components
nitrogen
reduction
reaction
ammonia
generation,
iv)
aluminum-ion
batteries,
v)
other
emerging
technologies.
concluded
that
there
tremendous
scope
further
optimizing
liquid
its
task,
subject
sustainability
imperatives
line
with
current
global
priorities,
assisted
by
artificial
intelligence.
ACS Nano,
Journal Year:
2024,
Volume and Issue:
18(10), P. 7633 - 7643
Published: Feb. 27, 2024
The
potential
for
optimizing
ion
transport
through
triply
periodic
minimal
surface
(TPMS)
structures
renders
promising
electrochemical
applications.
In
this
study,
as
a
proof-of-concept,
we
extend
the
inherent
efficiency
and
mathematical
beauty
of
TPMS
to
fabricate
liquid-crystalline
electrolytes
with
high
ionic
conductivity
superior
structural
stability
aqueous
rechargeable
zinc-ion
batteries.
specific
topological
configuration
electrolytes,
featuring
Gyroid
geometry,
enables
formation
continuous
conduction
pathway
enriched
confined
water.
This,
in
turn,
promotes
smooth
charge
carriers
contributes
conductivity.
Meanwhile,
quasi-solid
hydrophobic
phase
assembled
by
alkyl
chains
exhibits
notable
rigidity
toughness,
enabling
uniform
compact
dendrite-free
Zn
deposition.
These
merits
synergistically
enhance
overall
performance
corresponding
full
This
work
highlights
distinctive
role
developing
high-performance,
which
can
provide
viable
route
rational
design
next-generation
quasi-solid-state
electrolytes.
Advanced Science,
Journal Year:
2023,
Volume and Issue:
10(8)
Published: Jan. 16, 2023
Abstract
Novel
electrolyte
is
being
pursued
toward
exploring
Zn
chemistry
in
zinc
ion
batteries.
Here,
a
fluorine‐free
liquid
crystal
(LC)
ionomer‐type
presented,
achieving
simultaneous
regulated
water
activity
and
long‐range
ordering
of
conduction
channels
SEI.
Distinct
from
network
or
local
current
advances,
layered
realized.
Via
manipulating
activity,
conductivities
range
≈0.34
to
15
mS
cm
−1
,
electrochemical
window
can
be
tuned
≈2.3–4.3
V.
The
Zn|Zn
symmetric
cell
with
LC
gel
exhibits
highly
reversible
stripping/plating
at
5
mA
−2
mAh
for
800
h,
retained
channels.
capability
inducing
situ
formation
ordered
layer
SEI
associated
alkylbenzene
sulfonate
anion
uncovered.
V
2
O
/Zn
the
shows
much
improved
cycling
stability
comparing
conventional
electrolytes,
where
preserved
structure
efficiently
stabilized
anode
by
gel.
ordering‐induced
regulation
on
transport,
stability,
interfacial
reaction,
development
provides
pathway
advancing
aqueous
rechargeable
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(52)
Published: Nov. 9, 2023
It
is
found
that
the
disordered
growth
of
bottom
perovskite
film
deteriorates
buried
interface
solar
cells
(PSCs),
so
developing
a
new
material
to
modify
for
regulating
crystal
and
defect
passivation
an
effective
approach
improving
photovoltaic
performance
PSCs.
Here,
we
developed
ionic
liquid
(ILC,
1-Dodecyl-3-methylimidazolium
tetrafluoroborate)
as
both
regulator
passivator
The
high
lattice
matching
between
this
ILC
promotes
preferential
along
[001]
direction,
while
oriented
with
mesomorphic
phase
has
strong
chemical
interaction
passivate
defect,
result,
modified
exhibits
suppressed
defects,
improved
band
alignment,
reduced
nonradiative
recombination
losses,
enhanced
charge
extraction.
ILC-modified
PSC
delivers
power
conversion
efficiency
24.92
%
maintains
94
original
value
after
storage
in
ambient
3000
h.
Journal of Materiomics,
Journal Year:
2024,
Volume and Issue:
11(1), P. 100833 - 100833
Published: Feb. 7, 2024
Ionogels
are
an
attractive
class
of
materials
for
smart
and
flexible
electronics
prepared
from
the
combination
a
polymer
ionic
liquid
which
is
entrapped
in
this
matrix.
provide
continuous
conductive
phase
with
high
thermal,
mechanical,
chemical
stability.
However,
because
higher
percentage
liquids
it
difficult
to
obtain
ionogel
conductivity
mechanical
stability,
very
important
application
point
view.
In
work,
films
flexibility,
excellent
conductivity,
exceptional
stability
were
using
polyvinyl
alcohol
as
host
matrix
1-ethyl-3-methylimidazolium
hydrogen
sulfate
water
solvent
energy
storage
application.
The
exhibited
good
along
sustaining
strain
more
than
100%
at
room
temperature
low
temperature,
ability
withstand
twisting
up
360°
different
bending
conditions,
5.12
×
10−3
S/cm.
supercapacitor
cell
fabricated
optimized
film
showed
capacitance
39.9
F/g
power
densities
5.5
Wh/kg
0.3
kW/kg,
respectively
confirming
suitability
ionogels
Inorganics,
Journal Year:
2024,
Volume and Issue:
12(7), P. 186 - 186
Published: July 3, 2024
The
current
study
focuses
on
reviewing
the
actual
progress
of
use
ionic
liquids
and
derivatives
in
several
electrochemical
application.
Ionic
can
be
prepared
at
room
temperature
conditions
by
including
a
solution
that
salt
water,
or
base
acid,
are
composed
organic
cations
many
charge-delocalized
inorganic
anions.
properties,
electronic
conductivities
these
innovative
fluids
hybrids,
addressed
depth,
together
with
their
key
influencing
parameters
type,
fraction,
functionalization
nanoparticles,
operating
temperature,
as
well
incorporation
surfactants
additives.
Also,
present
review
assesses
recent
applications
corresponding
hybrids
addition
nanoparticles
diverse
equipment
processes,
critical
evaluation
related
feasibility
concerns
different
applications.
Those
ranging
from
metal-ion
batteries,
which
possess
prominent
role
electrolytes
reference
electrodes
passing
through
dye
sensitized
solar
cells
fuel
cells,
to
finishing
processes
like
ones
low-grade
heat
harvesting
supercapacitors.
Moreover,
overview
scientific
articles
theme
resulted
comparatively
brief
examination
benefits
closely
linked
such
improved
conductivity,
thermal
stabilities,
tunability,
comparison
traditional
solvents,
electrolytes,
electrodes.
Finally,
this
work
analyzes
fundamental
limitations
novel
corrosivity
potential,
elevated
dynamic
viscosity,
leakage
risk,
highlights
essential
prospects
for
research
exploration
various
devices
procedures.
