Spectral Characteristics of Dissolved Organic Matter in Farmland Soils around Urumqi, China DOI Creative Commons
Jianhua Zhu, Jia Duo, Zizhao Zhang

et al.

Toxics, Journal Year: 2023, Volume and Issue: 11(4), P. 376 - 376

Published: April 16, 2023

The dissolved organic matter (DOM) is one of the most sensitive indicators changes in soil environment, and it mobile active component that serves as an easily available source nutrients energy for microbes other living organisms. In this paper, DOM structural characteristics main properties were investigated by three-dimensional fluorescence spectroscopy (EEM) UV–visible spectrum technology farmland soils around Urumqi China, its possible sources pathways analyzed spectroscopic indices. results showed humic-like substances composition DOM, autogenesis not obvious. Main such aromatability, hydrophobicity, molecular weight, size, humification degree southern region higher than those northern Fukang on upper layers (0–0.1 0.2 m) deeper layer (0.2–0.3 m).This may be because tilled more subjected to fertilization conducive microbial activities. analysis these regions mainly from metabolites. These provide basic scientific data further research environmental chemical behavior pollutants pollution control region.

Language: Английский

Critical assessment of an equilibrium-based method to study the binding of waterborne organic contaminants to natural dissolved organic matter (DOM) DOI
Simone Rizzuto, Kevin C. Jones, Hao Zhang

et al.

Chemosphere, Journal Year: 2021, Volume and Issue: 285, P. 131524 - 131524

Published: July 12, 2021

Language: Английский

Citations

16

Non-targeted (ultra-)high-resolution mass spectrometry of dissolved organic matter to predict the formation of disinfection byproducts DOI Creative Commons
Patricia Aguilar-Alarcón, Meritxell Gros, María José Farré

et al.

Trends in Environmental Analytical Chemistry, Journal Year: 2024, Volume and Issue: 42, P. e00231 - e00231

Published: March 15, 2024

Dissolved organic matter (DOM) is a complex mixture of compounds, which significant relevance in the context drinking water treatment. This importance stems from its well-established role as primary precursor potentially harmful disinfection byproducts (DBPs) when subjected to chemical processes. Characterizing DOM challenging task due inherent heterogeneity and wide range compounds it contains. Additionally, composition can vary based on source quality specific treatment processes employed. Advanced analytical techniques, such non-targeted analyses using ultrahigh- or high-resolution mass spectrometry [(U-)HRMS], are improving our understanding nature present their potential form DBPs. In this review, most commonly used (U-)HRMS approaches for analyzing raw treated waters reported, application monitoring tool track changes formation DBPs assessed. Moreover, recommendations achieving common comparable fingerprint approach among different laboratories instruments provided. The results reviewed here provide indexes ranges that assist tracking various effects Overall, characterization presented an effective evaluating processes, predicting DBP formation, assessment human consumption.

Language: Английский

Citations

2

A quantitative method of PPCPs in DOM-PPCPs coexisting system by differential spectroscopy DOI
Fan Yang,

Jiao Liu,

Yanjie Xie

et al.

Microchemical Journal, Journal Year: 2024, Volume and Issue: 200, P. 110357 - 110357

Published: March 21, 2024

Language: Английский

Citations

2

Combined effects of pH and dissolved organic matter on the availability of pharmaceuticals and personal care products in aqueous environment DOI

Huazhi Aolin,

Lanxue Qin,

Sihan Zhu

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 929, P. 172637 - 172637

Published: April 23, 2024

Language: Английский

Citations

2

Optimization and application of a continuous flow photo-electro-Fenton system for the removal of pharmaceutical active compounds detected in irrigation water of Bogotá – Savanna (Colombia) Crops DOI Creative Commons
Carlos Andrés Delgado-Vargas,

Johan S. Barreneche-Vasquez,

Natalia González Cógua

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(5), P. 111030 - 111030

Published: Sept. 16, 2023

In this study, a continuous flow photo-electro-Fenton (PEF) system was evaluated for its ability to remove pharmaceutically active compounds (PhACs) from irrigation water used in Bogotá-savanna crops. The PEF consisted of dimensionally stable anode and graphite diffusion gas cathode, which were irradiated with LEDs. Firstly, the optimized using response surface methodology (RSM) ultrapure water. most favorable conditions efficient generation oxidants (the variable) found be rate 210 mL/min, current density 15 mA/cm2, an electrolyte concentration 0.1 mol NaCl/L. Subsequently, model PhACs, including losartan (LOS), sulfamethoxazole (SMX), diclofenac (DCF), eliminated after only 10 minutes treatment under previously established conditions. After demonstrating potential eliminate applied real evaluate degradation seven namely carbamazepine (CBZ), ciprofloxacin (CIP), clarithromycin (CLR), valsartan (VAL), trimethoprim (TMP). results showed that 30 system, these drastically reduced remaining undetected. This demonstrates high reduce presence PhACs associated environmental food health risks.

Language: Английский

Citations

5

Size and polarity fractions of mobile organic matter from manure affect the sorption of sulfadiazine, caffeine and atenolol in soil DOI Creative Commons
Wei Zhang, Xiangyu Tang, Benny Chefetz

et al.

Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 477, P. 135277 - 135277

Published: July 22, 2024

Waste-derived organics introduced to soils along with pharmaceutical active compounds (PhAC) are a crude mixture of occurring in various size and polarity fractions. They affect the sorption PhACs soil; however, relevant knowledge is still insufficient. The effects different fractions manure-derived mobile organic matter (<63 µm) on sulfadiazine, caffeine atenolol five topsoils were investigated. Mobilization was strongest presence dissolved (mDOM, <0.45 µm), reduction K

Language: Английский

Citations

1

A Bioavailability Model to Predict the Impact of pH and Dissolved Organic Carbon on Ciprofloxacin Ecotoxicity to the Cyanobacterium Microcystis aeruginosa DOI
Qiyun Zhang, Kristof Demeestere, Karel De Schamphelaere

et al.

Environmental Toxicology and Chemistry, Journal Year: 2022, Volume and Issue: 41(11), P. 2835 - 2847

Published: Aug. 3, 2022

Abstract Ciprofloxacin (CIP) is a pseudopersistent antibiotic detected in freshwater worldwide. As an ionizable chemical, its fate influenced by water chemistry factors such as pH, hardness, and dissolved organic carbon (DOC) content. We investigated the effect of DOC, Ca 2+ levels on toxicity CIP to Microcystis aeruginosa developed bioavailability model basis these experimental results. found that zwitterion (CIP +/− ) most bioavailable species M. , whereas DOC dominant factor reducing toxicity, possibly via binding both + DOC. pH likely also regulates CIP–DOC indirectly through influence speciation. In addition, higher tolerance was observed at < 7.2, but underlying mechanism yet unclear. Calcium identified insignificant bioavailability. When parameterized with data obtained from experiments, our able provide accurate predictions because predicted total median effective concentrations deviated <28% each other. Our predicts changes conditions can affect up 10‐fold, suggesting many natural environments less toxic than standard laboratory experiments. Environ Toxicol Chem 2022;41:2835–2847. © 2022 SETAC

Language: Английский

Citations

7

Size and Polarity Fractions of Mobile Organic Matter from Manure Affect the Sorption of Sulfadiazine, Caffeine and Atenolol in Soil DOI
Wei Zhang, Xiangyu Tang, Benny Chefetz

et al.

Published: Jan. 1, 2024

Download This Paper Open PDF in Browser Add to My Library Share: Permalink Using these links will ensure access this page indefinitely Copy URL DOI

Language: Английский

Citations

0

Exploring the combination characteristics of dissolved organic matter with erythromycin in a soil infiltration system DOI

Donghai Yuan,

Yiwen Pang,

Linxiao Zhai

et al.

Environmental Technology, Journal Year: 2023, Volume and Issue: 45(16), P. 3263 - 3275

Published: May 15, 2023

Erythromycin (ERY), as a common macrolides antibiotic, is widely used for sterilisation and disinfection of humans or livestock whose migration transformation in the surface water environment are significantly related to dissolved organic matter (DOM). The characteristics DOM can be greatly influenced by complexation between ERY with itself soil infiltration system. Using spectroscopic techniques (excitation-emission matrices, parallel factor analysis, Fourier infrared spectroscopy, synchronous fluorescence spectroscopies) explore properties each component binding order functional groups was determined two-dimensional correlation spectroscopy combined FTIR. amide I band v(C = O) exhibited stronger affinity. After treatment, intensity sharply decreased concentration declined 88.36%. Thus, degradation may occur them. result integrated indicated that sequencing ability changed There more sites effluent than influent. A protein-like showed priority stable had highest Log KM value 3.61. These results demonstrated system could take out most fluorescent DOM, reduce risk body.

Language: Английский

Citations

1

Insight into the interaction of tetrabromobisphenol A with sediment-derived dissolved organic carbon in a multiphase system by direct immersion solid phase microextraction DOI
Xiaohui Zhu, Liangzhong Li, Zhenyu Lu

et al.

The Science of The Total Environment, Journal Year: 2023, Volume and Issue: 912, P. 169037 - 169037

Published: Dec. 4, 2023

Language: Английский

Citations

1