Optimizing Glyphosate Removal from Water Using a Peracetic Acid-Assisted Advanced Oxidation Process: A Response Surface Methodology Approach

Sustainability, Journal Year: 2024, Volume and Issue: 16(13), P. 5741 - 5741

Published: July 5, 2024

Glyphosate (GLY), one of the most used pesticides in world, has been frequently detected water, posing chronic and remote hazards to human health environment. Consequently, it become necessary develop efficient sustainable treatment processes able remove GLY from polluted aquatic environments. In this context, use advanced oxidation is great interest, as allows for a significant reduction concentrations recalcitrant pollutants. study, peracetic acid (PAA) was first time water. particular, process parameters (oxidant dose, activation by UV radiation, concentration, time) were optimized using central composite design (CCD) response surface methodology (RSM). The degradation pollutant, i.e., GLY, monitored ion chromatography, optimizing instrumental parameters. During process, residual oxidant also constantly reference methods (i.e., UV-visible spectroscopy). Based on results obtained, best removals (over 90%) achieved under following conditions: PAA/GLY molar ratio 3 (concentration 3.0 mg/L 4.0 PAA), irradiation, 45 min. possibility achieving total glyphosate removal small amounts increases environmental sustainability proposed pollution mitigation strategy.

Language: Английский

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Green Glyphosate Treatment with Ferrihydrite and CaO₂ via Forming Surface Ternary Complex

Environmental Science & Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 30, 2025

Glyphosate (PMG) is a globally used broad-spectrum herbicide and receives environmental concerns because of its moderate persistence potential carcinogenicity. Traditional PMG treatment methods often suffer from the generation more toxic persistent aminomethylphosphonic acid (AMPA) intermediate. Herein, we develop green method with ferrihydrite (FH) CaO2 (FH/CaO2) via regulating coordination FH Ca2+, where phosphonate group preferentially binds to carboxylate side complexes Ca2+ released by CaO2, forming FH-PMG-Ca ternary surface complex. This unique complex can redistribute electrons within molecule for C-P activation C-N bond stabilization, favoring selective attack superoxide radical produced Fenton reaction between CaO2-derived H2O2 FH, thus generating environment-friendly glycine instead AMPA. The FH/CaO2 process realizes over 99% degradation in industrial wastewater 1 h, residual < 0.1 ppm AMPA 40 ppb. More importantly, consumption was as low 3.1 mg CaO2/mg PMG, one-fifth those previously reported CaO2-based counterparts. study provides an effective strategy highlights importance modes on pathway PMG.

Language: Английский

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A 7-year feed study on the long-term effects of genetically modified maize containing cry1Ab/cry2Aj and EPSPS genes on gut microbiota and metabolite profiles across two generations of cynomolgus macaques

Food and Chemical Toxicology, Journal Year: 2025, Volume and Issue: unknown, P. 115419 - 115419

Published: March 1, 2025

Language: Английский

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Mitigation of benzoic acid-driven autotoxicity in waste nutrient solution using O3 and O3/H2O2 treatments: Seed germination and root growth of Lactuca sativa L.

Environmental Pollution, Journal Year: 2023, Volume and Issue: 331, P. 121930 - 121930

Published: June 1, 2023

Language: Английский

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The recent development of innovative photoelectro-Fenton processes for the effective and cost-effective remediation of organic pollutants in waters

Chemosphere, Journal Year: 2024, Volume and Issue: unknown, P. 143465 - 143465

Published: Oct. 1, 2024

Language: Английский

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A Review of Pathogen Removal from Municipal Wastewater using Advanced Oxidation Processes: Agricultural Application, Regrowth Risks, and New Perspectives

Heliyon, Journal Year: 2024, Volume and Issue: 10(20), P. e39625 - e39625

Published: Oct. 1, 2024

Language: Английский

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FeS and Fe3O4 Co-modified biochar to build a highly resistant advanced oxidation process system for quinclorac degradation in irrigation water

Journal of Environmental Management, Journal Year: 2023, Volume and Issue: 348, P. 119492 - 119492

Published: Nov. 1, 2023

Language: Английский

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Effects of Water Deficit on Growth and Productivity in Tomato Crops Irrigated with Water Treated with Very Low-Frequency Electromagnetic Resonance Fields

Plants, Journal Year: 2023, Volume and Issue: 12(21), P. 3721 - 3721

Published: Oct. 30, 2023

The tomato crop is very sensitive to stress conditions. A water deficit defined as when precipitation less than the evapotranspiration (ETc) of in a given period, and this scenario climate change, it identified responsible for global productivity losses. use potential technologies better irrigation management, such electromagnetically treated water, remains controversial. Thus, objective present work was investigate effects low-frequency electromagnetic resonance field treatment on crops submitted different rates. For this, an experiment carried out under controlled conditions with types water: (WTVLF) untreated (UNW), well four replacement rates: 40, 60, 80, 100% ETc. using commercial equipment AQUA4D®. pots five replications per treatment. Lower activity SOD, POD, CAT, APX enzymes observed plants irrigated fields (WTVLF), indicating oxidative caused by deficit. Water reduced chlorophyll content, but were harmful WTVLF water. resulted accumulation dry matter linear relationship. However, showed increments about 20% fruit production concerning independent We can conclude that be solution reduce damage deficits increase crops.

Language: Английский

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Electrochemical Processes Used to Degrade Thiamethoxam in Water and Toxicity Analyses in Non-Target Organisms

Processes, Journal Year: 2024, Volume and Issue: 12(5), P. 887 - 887

Published: April 27, 2024

Pesticides ensure greater productivity in less time; however, they spread beyond the perimeters to which are applied reach non-target organisms, thereby affecting plant, animal, and human health. Thiamethoxam (TMX) is considered be one of main agents responsible for poisoning bees potentially contaminating surface groundwater. Conventional water-treatment protocols unable degrade thiamethoxam; therefore, electrochemically advanced oxidative processes (EAOPs) have become promising alternatives owing their ease operation cost-effectiveness. Herein, we examined use EAOPs oxidize thiamethoxam commercial Actara® analyzed treatment efficiencies through phytotoxicity studies using cucumber maize seeds as bioindicators. In addition, cost each process was based on resulting current efficiency. The treated solutions were used germinate that total protein, hydrogen peroxide, lipid peroxidation (MDA), superoxide dismutase (SOD), catalase (CAT) activities. found effectively TMX, with more than 50% degraded 80% COD removed under all conditions, even when product used. photoelectro-Fenton 10 mg L−1 FeSO4 100 H2O2 exhibited best results, 79% TMX 83% removed, additionally exhibiting lowest estimated operating (USD 1.01 dm−3). Higher enzymatic SOD CAT activities, protein content, concentration observed; no significant changes MDA recorded. This protocol oxidizes reduces its seedlings.

Language: Английский

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Fuzzy Modeling Development for Lettuce Plants Irrigated with Magnetically Treated Water

Plants, Journal Year: 2023, Volume and Issue: 12(22), P. 3811 - 3811

Published: Nov. 9, 2023

Due to the worldwide water supply crisis, sustainable strategies are required for a better use of this resource. The magnetic has been shown have potential improving irrigation efficacy. However, lack modelling methods that correspond experimental results and minimize error is observed. This study aimed estimate replacement rates provided by lettuce production using mathematical model based on fuzzy logic compare multiple polynomial regression analysis model. A greenhouse was conducted with two types water, (MW) conventional (CW), five levels (25, 50, 75, 100 125%) crop evapotranspiration. Plant samples biometric were taken at 14, 21, 28 35 days after transplanting. data analyzed via modeling, followed an inference models comparison between methods. highest values observed when irrigated MW during different phenological stage evaluated. more exact adjustment compared regressions.

Language: Английский

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