Research Gaps In Contaminants Of Emerging Concern (CECs): Routes To The Standardization Of Chemical Test Methods By GC/LC-Mass Spectrometry: A Review DOI Open Access
Thavrin Manickum

Journal of new developments in Chemistry, Journal Year: 2023, Volume and Issue: 4(1), P. 30 - 79

Published: June 29, 2023

A literature review was undertaken with a focus on 1) identifying the research gaps regarding CECs, 2) most common ones, and 3) typical analytical methods/technologies employed, for their analysis. total of 214 papers were noted, 21 articles (9.8%). Of this total, surprisingly high number from South Africa alone: 117 (54.7%), which 44 (20.6%) reports associated Africa’s Water Research Commission (WRC). The top three CECs (decreasing rank: Number “gaps”, %): Toxicity/Risk/Impact (260, 21.5%), Analysis/Tests/Methods (118, 9.8%) Future research/studies 9.8%), Monitoring (89, 7.4%). classes that reported on, : (i) Chemical: pharmaceuticals, personal care products, steroids, chlorinated brominated contaminants, PAHs, PCBs, phthalates, alkyl phenols, herbicides, organochlorine pesticides, engineered nanomaterials (ii) “Microbiological”: antibiotic resistance genes, human enteric bacteria viruses, microbial pathogens (e.g., E Coli, rotavirus, Crypto, etc.), infectious biological water contaminants Coli isolates), cyanobacterial blooms (Microcystis). Common test methods used analysis chemical found to be chromatography (gas, liquid)-mass spectrometry; they culture-based methods, ELISA, fluorescence microscopy, qPCR, RT-qPCR, gel electrophoresis, Raman spectroscopy, also (largely spectrometry, used. Some proposals additionally made address very common, significant noted in research, especially standardization based chromatography-mass quantification.

Language: Английский

Sustainable wastewater reuse for agriculture DOI Creative Commons
Anastasis Christou, Vasiliki G. Beretsou, Iakovos C. Iakovides

et al.

Nature Reviews Earth & Environment, Journal Year: 2024, Volume and Issue: 5(7), P. 504 - 521

Published: June 6, 2024

Effective management of water resources is crucial for global food security and sustainable development. In this Review, we explore the potential benefits challenges associated with treated wastewater (TW) reuse irrigation. Currently, 400 km3 yr−1 generated globally, but <20% treated, that TW, only 2–15% reused irrigation depending on region. The main limitation TW inability current treatment technologies to completely remove all micropollutants contaminants emerging concern, some which have unknown impacts crops, environment health. However, advanced schemes, supported by quality monitoring regulations, can provide a stable supply agricultural production, as demonstrated in regions such USA Israel. Such schemes could potentially serve net energy source, embedded exceeds needs 9 10 times. Agriculturally useful nutrients nitrogen, phosphorus potassium be also recovered reused. act major contributor circular economy development, first steps will funding implementation social acceptance. Treated alleviate imbalances boost production water-scarce regions, thus promoting security. This Review discusses widespread agriculture framework.

Language: Английский

Citations

32

Mitigating risks and maximizing sustainability of treated wastewater reuse for irrigation DOI Creative Commons
David Yalin, Hillary A. Craddock, S. Assouline

et al.

Water Research X, Journal Year: 2023, Volume and Issue: 21, P. 100203 - 100203

Published: Sept. 22, 2023

Scarcity of freshwater for agriculture has led to increased utilization treated wastewater (TWW), establishing it as a significant and reliable source irrigation water. However, years research indicate that if not managed adequately, TWW may deleteriously affect soil functioning plant productivity, pose hazard human environmental health. This review leverages the experience researchers, stakeholders, policymakers from Israel, United-States, Europe present holistic, multidisciplinary perspective on maximizing benefits municipal use irrigation. We specifically draw extensive knowledge gained in world leader agricultural implementation. The first two sections work set foundation understanding current challenges involved with TWW, detailing known emerging agronomic issues (such salinity phytotoxicity) public health risks contaminants concern pathogens). then presents solutions address these challenges, including technological management-based well control policies. concluding section suggestions path forward, emphasizing importance improving links between policy, better outreach practitioners. this platform call action, form global harmonized data system will centralize scientific findings agronomic, effects Insights such collaboration help mitigate risks, facilitate more sustainable food production future.

Language: Английский

Citations

35

Exploration of novel solid-phase extraction modes for analysis of multiclass emerging contaminants DOI Creative Commons
Aleksander Kravos, Helena Prosen

Analytica Chimica Acta, Journal Year: 2024, Volume and Issue: 1319, P. 342955 - 342955

Published: July 9, 2024

Solid-phase extraction (SPE) has gained an essential role in environmental analytical chemistry. Classic off-line SPE coupled with LC-MS/MS systems creates powerful procedures for ultratrace analysis of contaminants emerging concern (CECs) water. But, being associated tedious work and large consumption materials, alternative modes are becoming interesting. As so, the study focuses on development, evaluation, overall comparison established novel modes. Off-line SPE, dispersive micro (DMSPE), 'fast' single-pump on-line were explored, using commercially available sorbents. Their efficiency was evaluated their performance water 20 multiclass CECs. Hydrophilic-lipophilic sorbent mixture C18/C8 sorbents best choice DMSPE, respectively. All optimized UHPLC-MS/MS reached environmentally-relevant limits detection (LODs 0.1-12 ng L

Language: Английский

Citations

5

Dissipation of twelve organic micropollutants in three different soils: Effect of soil characteristics and microbial composition DOI

Sunil Paul M. Menacherry,

Radka Kodešová, Ganna Fedorová

et al.

Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 459, P. 132143 - 132143

Published: July 26, 2023

Language: Английский

Citations

11

Presence of Micropollutants and Transformation Products During Subsurface Irrigation with Treated Wastewater Assessed by Non-Target Screening Analysis DOI Creative Commons

Alessia Ore,

Rick Helmus, Dominique M. Narain-Ford

et al.

ACS ES&T Water, Journal Year: 2025, Volume and Issue: 5(2), P. 891 - 901

Published: Jan. 15, 2025

While wastewater treatment plant (WWTP) effluent offers a potential alternative source for irrigation, the fate of organic micropollutants (OMPs), including transformation products (TPs), in effluent-irrigated fields remains largely unknown. Using non-target analysis (NTA), we investigated OMPs WWTP and their distribution throughout full-scale subsurface irrigation (SSI) field where was used irrigation. Our results indicate that TPs accounted approximately 80% detected OMPs. Weather SSI hydrology seem to influence OMP transformation. Wetter conditions promoted deeper leaching soil, drier favored capillary rise biotransformation, as shown by detection 37% more rhizons during dry year. On average 45 OMPs, at least 50% with logD <3, were −2.3 m depth, highlighting reach groundwater importance further risk assessment. This approach demonstrates how NTA subsequent data tools can support identification (unknown) contribute understanding under conditions, which is first step an exposure-driven environmental Overall, our study emphasizes carefully considering responsible reuse.

Language: Английский

Citations

0

Activation of peroxymonosulfate by(sunlight)FeCl3-modified biochar for efficient degradation of contaminants of emerging concern: Comparison with H2O2 and effect of microplastics DOI Creative Commons
Mister Adeel,

Carla Fernanda Grasel Frois,

Ilaria Berruti

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160782 - 160782

Published: Feb. 1, 2025

Language: Английский

Citations

0

Impact of the wastewater treatment technology and storage on micropollutant profiles during reclaimed water irrigation: A wide-scope HRMS screening in a water-soil-lettuce-leachate system DOI
Iakovos C. Iakovides, Vasiliki G. Beretsou, Anastasis Christou

et al.

Water Research, Journal Year: 2025, Volume and Issue: 279, P. 123319 - 123319

Published: Feb. 18, 2025

Language: Английский

Citations

0

Occurrence of contaminants of emerging concern in the Eerste River, South Africa: Towards the optimisation of an urban water profiling approach for public- and ecological health risk characterisation DOI Creative Commons
Edward Archer, Elizabeth Holton, James Fidal

et al.

The Science of The Total Environment, Journal Year: 2022, Volume and Issue: 859, P. 160254 - 160254

Published: Nov. 17, 2022

The study evaluated the presence and fate of various contaminants emerging concern (CECs) from a South African wastewater treatment works (WWTW) surface waters located around an urban setting. A total 45 CECs were quantified nine sampling locations over 11-month period. Daily loads (g/day) target analytes in WWTW showed persistence some CECs, along with population-normalised daily (mg/day/1000inh) pharmaceuticals drugs abuse (DOA) that estimated for first time area. Multiple chemical markers recorded river water upstream discharge throughout period, suggesting high degree diffuse pollution communities area are not connected to sewage networks or where sanitation services limited. potential using defined perform community-wide substance use profiling non-sewered was also explored. Environmental risk characterisation effluent period provided multiple quotients (RQ) list spanning sentinel trophic levels. High profiles (RQ > 1.0) frequency exceedance (FoE) larger than 75 % several both suggest long-term ecological health impacts hotspot areas catchment situated We present challenges quality within is relatable, may even more challenging, other low- middle-income country (LMICs) settings. highlighted limitations associated much-needed application wastewater-based epidemiology (WBE) intervention can inform on public communal entire

Language: Английский

Citations

15

Quantitative and qualitative approaches for CEC prioritization when reusing reclaimed water for irrigation needs – A critical review DOI Creative Commons
Paola Verlicchi, Engracia Lacasa, Vittoria Grillini

et al.

The Science of The Total Environment, Journal Year: 2023, Volume and Issue: 900, P. 165735 - 165735

Published: July 25, 2023

The use of reclaimed water for irrigation is an option that becoming increasingly widespread to alleviate scarcity and cope with drought. However, water, if used irrigation, may introduce Contaminants Emerging Concern (CECs) into the agroecosystems, which be taken up by crops subsequently enter food chain. number CECs steadily increasing due their continuous introduction on market different uses. There urgent need draw a short list potential high priority CECs, are substances could plants accumulated in produce, and/or have negative effects human health environment. This review presents discusses approaches developed prioritize when (re-)used irrigation. They divided quantitative methodologies, estimate risk environmental compartments (soil water), predators humans through equations, qualitative instead conceptual frameworks or procedures based simultaneous combination data/information/practices judgment experts. Three antibiotics (erythromycin, sulfamethoxazole ciprofloxacin), one estrogen (17-α ethinylestradiol) analgesic (ibuprofen) were found at least two lists, although comparison among studies still difficult. remarks it advisable harmonize methodologies order identify include monitoring programs reuse projects ensure level protection

Language: Английский

Citations

9

Supramolecular solvents for making comprehensive liquid-liquid microextraction in multiclass screening methods for drugs of abuse in urine based on liquid chromatography-high resolution mass spectrometry DOI Creative Commons
Soledad González-Rubio, Noelia Caballero‐Casero, Ana Ballesteros‐Gómez

et al.

Journal of Chromatography A, Journal Year: 2023, Volume and Issue: 1701, P. 464061 - 464061

Published: May 9, 2023

Multiclass screening methods involving hundreds of structurally unrelated compounds are becoming essential in many control labs and research areas. Accurate mass a theoretically unlimited number chemicals can be undertaken using liquid chromatography coupled to high resolution spectrometry (LCHRMS), but the lack comprehensive sample treatments hinders this potential. In research, capability supramolecular solvents (SUPRAS) for making liquid-liquid microextraction (LLME) multiclass based on LCHRMS was firstly explored. For purpose, SUPRAS made up 1,2-hexanediol, sodium sulphate water synthesized directly urine applied compound extraction interference removal eighty prohibited substances sports by LC-electrospray ionization-time flight spectrometry. Selected included wide range polarities (log P from -2.4 9.2) functionalities (e.g. alcohol, amine, amide, carboxyl, ether, ester, ketone, sulfonyl, etc.). No interfering peaks were observed any 80 investigated. Around 84-93% drugs efficiently extracted (recoveries 70-120%) 83-94% analytes did not show matrix effects (±20%) ten tested urines. Method detection limits interval 0.002-12.9 ng mL-1, which accordance with Minimum Required Performance Levels values established World Anti-Doping Agency. The applicability method evaluated thirty-six blinded anonymized samples, previously analyzed gas or chromatography-triple quadrupole. Seven samples lead an adverse analytical finding line results obtained conventional methods. This proves that LLME constitutes efficient, economic, simple treatment methods, application is unaffordable organic solvents.

Language: Английский

Citations

6