Journal of new developments in Chemistry,
Journal Year:
2023,
Volume and Issue:
4(1), P. 30 - 79
Published: June 29, 2023
A
literature
review
was
undertaken
with
a
focus
on
1)
identifying
the
research
gaps
regarding
CECs,
2)
most
common
ones,
and
3)
typical
analytical
methods/technologies
employed,
for
their
analysis.
total
of
214
papers
were
noted,
21
articles
(9.8%).
Of
this
total,
surprisingly
high
number
from
South
Africa
alone:
117
(54.7%),
which
44
(20.6%)
reports
associated
Africa’s
Water
Research
Commission
(WRC).
The
top
three
CECs
(decreasing
rank:
Number
“gaps”,
%):
Toxicity/Risk/Impact
(260,
21.5%),
Analysis/Tests/Methods
(118,
9.8%)
Future
research/studies
9.8%),
Monitoring
(89,
7.4%).
classes
that
reported
on,
:
(i)
Chemical:
pharmaceuticals,
personal
care
products,
steroids,
chlorinated
brominated
contaminants,
PAHs,
PCBs,
phthalates,
alkyl
phenols,
herbicides,
organochlorine
pesticides,
engineered
nanomaterials
(ii)
“Microbiological”:
antibiotic
resistance
genes,
human
enteric
bacteria
viruses,
microbial
pathogens
(e.g.,
E
Coli,
rotavirus,
Crypto,
etc.),
infectious
biological
water
contaminants
Coli
isolates),
cyanobacterial
blooms
(Microcystis).
Common
test
methods
used
analysis
chemical
found
to
be
chromatography
(gas,
liquid)-mass
spectrometry;
they
culture-based
methods,
ELISA,
fluorescence
microscopy,
qPCR,
RT-qPCR,
gel
electrophoresis,
Raman
spectroscopy,
also
(largely
spectrometry,
used.
Some
proposals
additionally
made
address
very
common,
significant
noted
in
research,
especially
standardization
based
chromatography-mass
quantification.
Nature Reviews Earth & Environment,
Journal Year:
2024,
Volume and Issue:
5(7), P. 504 - 521
Published: June 6, 2024
Effective
management
of
water
resources
is
crucial
for
global
food
security
and
sustainable
development.
In
this
Review,
we
explore
the
potential
benefits
challenges
associated
with
treated
wastewater
(TW)
reuse
irrigation.
Currently,
400
km3
yr−1
generated
globally,
but
<20%
treated,
that
TW,
only
2–15%
reused
irrigation
depending
on
region.
The
main
limitation
TW
inability
current
treatment
technologies
to
completely
remove
all
micropollutants
contaminants
emerging
concern,
some
which
have
unknown
impacts
crops,
environment
health.
However,
advanced
schemes,
supported
by
quality
monitoring
regulations,
can
provide
a
stable
supply
agricultural
production,
as
demonstrated
in
regions
such
USA
Israel.
Such
schemes
could
potentially
serve
net
energy
source,
embedded
exceeds
needs
9
10
times.
Agriculturally
useful
nutrients
nitrogen,
phosphorus
potassium
be
also
recovered
reused.
act
major
contributor
circular
economy
development,
first
steps
will
funding
implementation
social
acceptance.
Treated
alleviate
imbalances
boost
production
water-scarce
regions,
thus
promoting
security.
This
Review
discusses
widespread
agriculture
framework.
Water Research X,
Journal Year:
2023,
Volume and Issue:
21, P. 100203 - 100203
Published: Sept. 22, 2023
Scarcity
of
freshwater
for
agriculture
has
led
to
increased
utilization
treated
wastewater
(TWW),
establishing
it
as
a
significant
and
reliable
source
irrigation
water.
However,
years
research
indicate
that
if
not
managed
adequately,
TWW
may
deleteriously
affect
soil
functioning
plant
productivity,
pose
hazard
human
environmental
health.
This
review
leverages
the
experience
researchers,
stakeholders,
policymakers
from
Israel,
United-States,
Europe
present
holistic,
multidisciplinary
perspective
on
maximizing
benefits
municipal
use
irrigation.
We
specifically
draw
extensive
knowledge
gained
in
world
leader
agricultural
implementation.
The
first
two
sections
work
set
foundation
understanding
current
challenges
involved
with
TWW,
detailing
known
emerging
agronomic
issues
(such
salinity
phytotoxicity)
public
health
risks
contaminants
concern
pathogens).
then
presents
solutions
address
these
challenges,
including
technological
management-based
well
control
policies.
concluding
section
suggestions
path
forward,
emphasizing
importance
improving
links
between
policy,
better
outreach
practitioners.
this
platform
call
action,
form
global
harmonized
data
system
will
centralize
scientific
findings
agronomic,
effects
Insights
such
collaboration
help
mitigate
risks,
facilitate
more
sustainable
food
production
future.
Analytica Chimica Acta,
Journal Year:
2024,
Volume and Issue:
1319, P. 342955 - 342955
Published: July 9, 2024
Solid-phase
extraction
(SPE)
has
gained
an
essential
role
in
environmental
analytical
chemistry.
Classic
off-line
SPE
coupled
with
LC-MS/MS
systems
creates
powerful
procedures
for
ultratrace
analysis
of
contaminants
emerging
concern
(CECs)
water.
But,
being
associated
tedious
work
and
large
consumption
materials,
alternative
modes
are
becoming
interesting.
As
so,
the
study
focuses
on
development,
evaluation,
overall
comparison
established
novel
modes.
Off-line
SPE,
dispersive
micro
(DMSPE),
'fast'
single-pump
on-line
were
explored,
using
commercially
available
sorbents.
Their
efficiency
was
evaluated
their
performance
water
20
multiclass
CECs.
Hydrophilic-lipophilic
sorbent
mixture
C18/C8
sorbents
best
choice
DMSPE,
respectively.
All
optimized
UHPLC-MS/MS
reached
environmentally-relevant
limits
detection
(LODs
0.1-12
ng
L
ACS ES&T Water,
Journal Year:
2025,
Volume and Issue:
5(2), P. 891 - 901
Published: Jan. 15, 2025
While
wastewater
treatment
plant
(WWTP)
effluent
offers
a
potential
alternative
source
for
irrigation,
the
fate
of
organic
micropollutants
(OMPs),
including
transformation
products
(TPs),
in
effluent-irrigated
fields
remains
largely
unknown.
Using
non-target
analysis
(NTA),
we
investigated
OMPs
WWTP
and
their
distribution
throughout
full-scale
subsurface
irrigation
(SSI)
field
where
was
used
irrigation.
Our
results
indicate
that
TPs
accounted
approximately
80%
detected
OMPs.
Weather
SSI
hydrology
seem
to
influence
OMP
transformation.
Wetter
conditions
promoted
deeper
leaching
soil,
drier
favored
capillary
rise
biotransformation,
as
shown
by
detection
37%
more
rhizons
during
dry
year.
On
average
45
OMPs,
at
least
50%
with
logD
<3,
were
−2.3
m
depth,
highlighting
reach
groundwater
importance
further
risk
assessment.
This
approach
demonstrates
how
NTA
subsequent
data
tools
can
support
identification
(unknown)
contribute
understanding
under
conditions,
which
is
first
step
an
exposure-driven
environmental
Overall,
our
study
emphasizes
carefully
considering
responsible
reuse.
The Science of The Total Environment,
Journal Year:
2022,
Volume and Issue:
859, P. 160254 - 160254
Published: Nov. 17, 2022
The
study
evaluated
the
presence
and
fate
of
various
contaminants
emerging
concern
(CECs)
from
a
South
African
wastewater
treatment
works
(WWTW)
surface
waters
located
around
an
urban
setting.
A
total
45
CECs
were
quantified
nine
sampling
locations
over
11-month
period.
Daily
loads
(g/day)
target
analytes
in
WWTW
showed
persistence
some
CECs,
along
with
population-normalised
daily
(mg/day/1000inh)
pharmaceuticals
drugs
abuse
(DOA)
that
estimated
for
first
time
area.
Multiple
chemical
markers
recorded
river
water
upstream
discharge
throughout
period,
suggesting
high
degree
diffuse
pollution
communities
area
are
not
connected
to
sewage
networks
or
where
sanitation
services
limited.
potential
using
defined
perform
community-wide
substance
use
profiling
non-sewered
was
also
explored.
Environmental
risk
characterisation
effluent
period
provided
multiple
quotients
(RQ)
list
spanning
sentinel
trophic
levels.
High
profiles
(RQ
>
1.0)
frequency
exceedance
(FoE)
larger
than
75
%
several
both
suggest
long-term
ecological
health
impacts
hotspot
areas
catchment
situated
We
present
challenges
quality
within
is
relatable,
may
even
more
challenging,
other
low-
middle-income
country
(LMICs)
settings.
highlighted
limitations
associated
much-needed
application
wastewater-based
epidemiology
(WBE)
intervention
can
inform
on
public
communal
entire
The Science of The Total Environment,
Journal Year:
2023,
Volume and Issue:
900, P. 165735 - 165735
Published: July 25, 2023
The
use
of
reclaimed
water
for
irrigation
is
an
option
that
becoming
increasingly
widespread
to
alleviate
scarcity
and
cope
with
drought.
However,
water,
if
used
irrigation,
may
introduce
Contaminants
Emerging
Concern
(CECs)
into
the
agroecosystems,
which
be
taken
up
by
crops
subsequently
enter
food
chain.
number
CECs
steadily
increasing
due
their
continuous
introduction
on
market
different
uses.
There
urgent
need
draw
a
short
list
potential
high
priority
CECs,
are
substances
could
plants
accumulated
in
produce,
and/or
have
negative
effects
human
health
environment.
This
review
presents
discusses
approaches
developed
prioritize
when
(re-)used
irrigation.
They
divided
quantitative
methodologies,
estimate
risk
environmental
compartments
(soil
water),
predators
humans
through
equations,
qualitative
instead
conceptual
frameworks
or
procedures
based
simultaneous
combination
data/information/practices
judgment
experts.
Three
antibiotics
(erythromycin,
sulfamethoxazole
ciprofloxacin),
one
estrogen
(17-α
ethinylestradiol)
analgesic
(ibuprofen)
were
found
at
least
two
lists,
although
comparison
among
studies
still
difficult.
remarks
it
advisable
harmonize
methodologies
order
identify
include
monitoring
programs
reuse
projects
ensure
level
protection
Journal of Chromatography A,
Journal Year:
2023,
Volume and Issue:
1701, P. 464061 - 464061
Published: May 9, 2023
Multiclass
screening
methods
involving
hundreds
of
structurally
unrelated
compounds
are
becoming
essential
in
many
control
labs
and
research
areas.
Accurate
mass
a
theoretically
unlimited
number
chemicals
can
be
undertaken
using
liquid
chromatography
coupled
to
high
resolution
spectrometry
(LCHRMS),
but
the
lack
comprehensive
sample
treatments
hinders
this
potential.
In
research,
capability
supramolecular
solvents
(SUPRAS)
for
making
liquid-liquid
microextraction
(LLME)
multiclass
based
on
LCHRMS
was
firstly
explored.
For
purpose,
SUPRAS
made
up
1,2-hexanediol,
sodium
sulphate
water
synthesized
directly
urine
applied
compound
extraction
interference
removal
eighty
prohibited
substances
sports
by
LC-electrospray
ionization-time
flight
spectrometry.
Selected
included
wide
range
polarities
(log
P
from
-2.4
9.2)
functionalities
(e.g.
alcohol,
amine,
amide,
carboxyl,
ether,
ester,
ketone,
sulfonyl,
etc.).
No
interfering
peaks
were
observed
any
80
investigated.
Around
84-93%
drugs
efficiently
extracted
(recoveries
70-120%)
83-94%
analytes
did
not
show
matrix
effects
(±20%)
ten
tested
urines.
Method
detection
limits
interval
0.002-12.9
ng
mL-1,
which
accordance
with
Minimum
Required
Performance
Levels
values
established
World
Anti-Doping
Agency.
The
applicability
method
evaluated
thirty-six
blinded
anonymized
samples,
previously
analyzed
gas
or
chromatography-triple
quadrupole.
Seven
samples
lead
an
adverse
analytical
finding
line
results
obtained
conventional
methods.
This
proves
that
LLME
constitutes
efficient,
economic,
simple
treatment
methods,
application
is
unaffordable
organic
solvents.