Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 310, P. 123094 - 123094
Published: Jan. 3, 2023
Language: Английский
Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 310, P. 123094 - 123094
Published: Jan. 3, 2023
Language: Английский
Separation and Purification Technology, Journal Year: 2022, Volume and Issue: 298, P. 121448 - 121448
Published: June 10, 2022
Language: Английский
Citations
153AIChE Journal, Journal Year: 2022, Volume and Issue: 68(6)
Published: Feb. 22, 2022
Abstract The elimination and recycling of NH 3 from the vented circulating stream synthesis process is great significance to protection air environment saving product. Deep eutectic solvents (DESs) with as many weak acidic sites possible are anticipated exhibit high efficiency for absorption at low pressures. Herein, we designed prepared a series metal‐based DESs by mixing EaCl, metal chloride (SnCl 2 , ZnCl FeCl or CoCl ), Gly. physiochemical properties, performance, mechanism were investigated systematically. It found that considerably solubilities in can be achieved utilizing multiple coordination hydrogen‐bond interaction provided ions Gly respectively. values (17.55 mol/kg 298.2 K 103.0 kPa, 10.24 6.8 kPa) highest reported date.
Language: Английский
Citations
55Biomass and Bioenergy, Journal Year: 2023, Volume and Issue: 173, P. 106804 - 106804
Published: April 15, 2023
Language: Английский
Citations
25Biomass Conversion and Biorefinery, Journal Year: 2024, Volume and Issue: unknown
Published: April 23, 2024
Language: Английский
Citations
9AIChE Journal, Journal Year: 2023, Volume and Issue: 69(5)
Published: Jan. 24, 2023
Abstract The suitability of phenyl‐based deep eutectic solvents (DESs) as absorbents for toluene absorption was investigated by means thermodynamic modeling and molecular dynamics (MD). models perturbed‐chain statistical associating fluid theory (PC‐SAFT) conductor‐like screening model real (COSMO‐RS) were used to predict the vapor–liquid equilibrium DES–toluene systems. PC‐SAFT yielded quantitative results even without using any binary fitting parameters. Among five DESs studied in this work, [TEBAC][PhOH] consisting triethyl benzyl ammonium chloride (TEBAC) phenol (PhOH), considered most suitable absorbent. Systems with had lowest pressures mixtures, best characteristics (i.e., Henry's law constant, excess enthalpy, Gibbs free energy solvation toluene), highest self‐diffusion coefficient toluene. molecular‐level mechanism explored MD simulations, indicating that has strongest interaction compared other under study. This work provides guidance rationally design novel efficient aromatic volatile organic compounds absorption.
Language: Английский
Citations
20Green Chemistry, Journal Year: 2023, Volume and Issue: 25(5), P. 1898 - 1907
Published: Jan. 1, 2023
This work reveals a novel and green insight into the selective capture conversion of HCl under mild conditions using an imidazole-based DES.
Language: Английский
Citations
17RSC Sustainability, Journal Year: 2024, Volume and Issue: 2(4), P. 757 - 803
Published: Jan. 1, 2024
Hydrogen sulfide is an extremely toxic, poisonous and flammable gas often found in natural streams crude oil reservoirs.
Language: Английский
Citations
8Renewable Energy, Journal Year: 2024, Volume and Issue: 223, P. 120069 - 120069
Published: Jan. 27, 2024
Language: Английский
Citations
6Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 346, P. 127374 - 127374
Published: April 9, 2024
Language: Английский
Citations
6Separation and Purification Technology, Journal Year: 2022, Volume and Issue: 298, P. 121680 - 121680
Published: July 8, 2022
Language: Английский
Citations
23