Inorganic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(20), P. 6794 - 6852
Published: Jan. 1, 2024
This
review
comprehensively
summarizes
the
advancements
in
MOF
photocatalysts
under
visible
light,
covering
construction,
optimization
and
application.
The
existing
challenges
future
prospects
this
area
are
also
discussed.
Journal of Applied Polymer Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 27, 2025
ABSTRACT
Fe‐based
metal
organic
framework
was
used
to
load
macroporous
resin
by
repurposing
waste
polyethylene
terephthalate
for
congo
red
removal.
framework/resin
systematically
analyzed
and
various
adsorption
factors
were
optimized.
Adsorption
mechanisms
investigated
based
on
kinetics,
isotherms,
thermodynamics,
instruments.
The
pseudo‐second‐order
(
R
2
>
0.997)
Langmuir
model
0.987)
suggest
that
the
process
followed
a
homogeneous
monomolecular
layer
chemisorption.
thermodynamic
analysis
indicated
spontaneous
endothermic.
At
pH
=
7,
maximum
capacity
766
mg/g.
In
addition,
exhibited
favorable
selectivity
towards
with
Cl
−
,
SO
4
2−
CO
3
.
It
could
be
conveniently
separated
reused.
With
help
of
density
functional
theory
calculations,
analyze
mechanism
in
depth.
pore
filling,
electrostatic
interactions,
π–π
stacking,
hydrogen
bonding.
Thus,
terephthalate‐derived
adsorbents
well
applied
water
purification,
environmental
protection,
separation
processes.
ACS Omega,
Journal Year:
2024,
Volume and Issue:
9(13), P. 15074 - 15084
Published: March 22, 2024
Polyethylene
terephthalate
(PET)
accounts
for
a
significant
portion
of
textile
waste,
and
recycling
strategies
this
material
have
attracted
much
attention.
This
study
proposes
facile
innovative
PET
method
applicable
to
environmental
remediation
that
involves
the
conversion
dyed
fabric
waste
into
value-added
fabric.
Herein,
template-based
synthesis
approach
capable
growing
UiO-66
metal–organic
framework
(MOF)
directly
on
is
reported.
The
advantage
process
lies
in
its
simplicity,
where
partial
hydrolysis
followed
by
zirconium
chloride
treatment
results
successful
growth
with
concurrent
removal
dye
without
additional
steps.
catalytic
performance
UiO-66-grown
was
evaluated
through
degradation
dimethyl
4-nitrophenyl
phosphate
(DMNP),
nerve
agent
simulant.
produced
simple
metal
(Zr@PEThyd)
exhibited
excellent
DMNP
t1/2
=
43.3
min
maintained
functional
stability
after
harsh
washing
procedure,
an
outcome
attributed
surface-assisted
ensured
good
bonding
stability.
developed
it
uses
as
template
direct
UiO-66,
simplifying
compromising
functionality.
research
provides
informative
option
sustainable
strategy
transforming
advanced
self-detoxifying
material.