Synergistic Integration of Halide Perovskite and Rare‐Earth Ions toward Photonics

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 13, 2025

Abstract Halide perovskites (HPs), emerging as a noteworthy class of semiconductors, hold great promise for an array optoelectronic applications, including anti‐counterfeiting, light‐emitting diodes (LEDs), solar cells (SCs), and photodetectors, primarily due to their large absorption cross section, high fluorescence efficiency, tunable emission spectrum within the visible region, tolerance lattice defects, well adaptability solution‐based fabrication processes. Unlike luminescent HPs with band‐edge emission, trivalent rare‐earth (RE) ions typically emit low‐energy light through intra‐4f optical transitions, characterized by narrow spectra long lifetimes. When fused, cooperative interactions between REs endow resulting binary composites not only properties inherited from parent materials but also introduce new attributes unattainable either component alone. This review begins fundamental characteristics REs, followed particular focus on impact electronic structures associated energy transfer The advanced synthesis methods utilized prepare HPs, RE‐doped compounds, are overviewed. Furthermore, potential applications summarized across diverse domains, high‐fidelity anticounterfeiting, bioimaging, LEDs, photovoltaics, photodetection, photocatalysis, conclude remaining challenges future research prospects.

Language: Английский

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Comparative Study of Distinct Halide Composites for Highly Efficient Cesium-Based Perovskite Solar Cells

Energy & Fuels, Journal Year: 2023, Volume and Issue: 37(20), P. 16035 - 16049

Published: Oct. 2, 2023

In recent years, perovskite solar cells (PSCs) have appeared as frontrunners in the renewable photovoltaic (PV) landscape. This study presents a substantially improved material, showcasing enhanced optoelectronic performance and potential for streamlined fabrication processes. Our main focus lies identifying optimal cesium halide composition, conjunction with TiO2 CuI charge transport layers (CTLs), that yield highest efficiency. Through meticulous optimization encompassing absorber thickness, CTL defect density, interface properties, our findings reveal CsPbI2Br-based PSCs exhibit remarkable boost power conversion efficiency (PCE) of approximately 15.52%. contrast, CsPbBr3-based comparatively lower values short-circuit current density (JSC) open circuit voltage (VOC), which results PCE 13.96%. investigation extends to exploring various parameters, including temperature effects, impedance characteristics, series resistance, quantum (QE), current–voltage (J–V) behavior. The comprehensive nature this bears substantial significance advancing efficient cesium-based PSC devices. demonstrated material holds immense promise across diverse applications foreseeable future, owing its cost-effectiveness favorable optical absorption properties.

Language: Английский

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Optimized High-Efficiency Solar Cells with Dual Hybrid Halide Perovskite Absorber Layers

Energy & Fuels, Journal Year: 2023, Volume and Issue: 37(20), P. 16022 - 16034

Published: Oct. 2, 2023

The single, double absorbers-based perovskite solar cells (PSCs) have attracted considerable attention of researchers in the past few years due to their promising photovoltaic parameters. present work discusses a comparative performance analysis two configurations, namely ITO/C60/MAPb(I1–xClx)3/CuSCN/Au, ITO/C60/MAPbI3/CuSCN/Au, and ITO/C60/MAPb(I1–xClx)3/MAPbI3/CuSCN/Au composed single layer as absorber different halide perovskites materials, respectively. MAPb(I1–xClx)3-based PSCs provide lower parameters when compared with MAPbI3-based limit output for applications. Nevertheless, need find maximum absorbance novel grading approach leads absorbing wider quantity light spectra, boosting efficiency. SCAPS-1D, software simulator, is used examine our proposed models. optimal obtained this simulation are JSC 21.41 mA/cm3, VOC 1.278 V, FF about 88.03%, PCE 24.10%,

Language: Английский

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An appraisal of the role of lanthanide doping in stabilization and performance improvement of [Sm3+-Eu3+-Tm3+]:CsPbI2.2Br0.8 for high-performance energy systems

Electrochimica Acta, Journal Year: 2024, Volume and Issue: 487, P. 144186 - 144186

Published: March 28, 2024

Language: Английский

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Probing the synergetic impacts of temperature modulation and lanthanide doping on [Sm3+-Eu3+-Tm3+]:CsPbI2.7Br0.3 designed for advanced energy technologies

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 84, P. 110869 - 110869

Published: Feb. 9, 2024

Language: Английский

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GeO2 – ZnO nanocomposite rosettes for enhancement of performance in energy technologies: coupling organic templated synthesis with microwave treatment

Physica E Low-dimensional Systems and Nanostructures, Journal Year: 2025, Volume and Issue: unknown, P. 116198 - 116198

Published: Feb. 1, 2025

Language: Английский

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Microwave abetted nano-hybrids driven high performance in catalytic, energy storage, and photovoltaic applications using RuO2–ZnO nano-hexagons anchored spheres

Optical Materials, Journal Year: 2023, Volume and Issue: 144, P. 114326 - 114326

Published: Sept. 5, 2023

Language: Английский

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‘Out of the glovebox’ studies of a multifunctional [Gd³⁺‐Ho³⁺‐Dy³⁺]:CsPbI_2.7Br_0.3 perovskite semiconductor system for energy applications

Journal of Chemical Technology & Biotechnology, Journal Year: 2024, Volume and Issue: 99(4), P. 830 - 841

Published: Jan. 19, 2024

Abstract BACKGROUND This work deciphers the first report on treble lanthanide‐doped perovskite heterosystem [Gd 3+ ‐Ho ‐Dy ]:CsPbI 2.7 Br 0.3 (GHD:C‐PVSK) and subsequently explores its prospects for solar cells, energy generation, charge storage. RESULTS GHD:C‐PVSK remained optically active a period of 28 days with band gap 1.62–1.76 eV. The developed material possesses cubic phase typical ABX 3 geometry deposited thin films have compact morphology. As light absorber layer, GHD:C‐PVSK‐based solution‐processed cell executed an efficiency 15.11% improved fill factor 71.25%. In electrocatalytic assays, emerged as bifunctional catalyst oxygen hydrogen generation greater tendency towards pure production, exuding overpotential ( η HER ) – that is, 143 mV 123.4 dec −1 Tafel slope value. With remarkable service life 100 min inside electrolyte, electrode was characterized by excellent It has unit capacity 383 mA h g is marked reduced equivalent series resistance R s 0.66 Ω. CONCLUSION Through photoelectrical electrical analysis, sustainable energy‐efficient can be stabilized suitable thermal modulation lanthanide doping. © 2024 Society Chemical Industry (SCI).

Language: Английский

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Enhancing the Electrical and Photoelectrical Efficacy with the Synergistic SrO–ZnO Nano‐Heterosystem

Energy Technology, Journal Year: 2024, Volume and Issue: 12(5)

Published: Feb. 1, 2024

Development of the sustainable materials for consolidation energy sustainability needs special emphasis in current era increasing demand. In compliance with this, present investigation reports first on amended production conjugated microwave process strontium oxide (SrO) and zinc oxid (ZnO) forming SrO–ZnO nanoscale heterostructure. The band gap prepared green nanomaterial was tuned reducing it from 5.8 to 3.6 eV upon formation nanocomposite. With mixed cubic hexagonal phase, these particles have average crystallite size 66.4 nm irregular shape. electro‐catalytic assays expressed bifunctional role towards generation oxygen hydrogen. However, has an excellent hydrogen capacity lower overpotential 126 mV Tafel slopes 123.6 dec −1 . addition, this also exhibited superior electrochemical charge storage batter applications unit 541.7 mAH g R s = 0.4 Ω, reflecting facilitated diffusion at interface. terms photovoltaic applications, nanocomposite effectively passivated perovskite solar cells by improving efficiency 7.2% 15.1%. Such improved performance is associated chemical synergism.

Language: Английский

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Transmogrifying the potential of [Gd-Ho-Dy]:CsPbI2Br1 energy: High performance heterosystem for sustainable energy applications

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 88, P. 111566 - 111566

Published: April 7, 2024

Language: Английский

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