Journal of Materials Chemistry B, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 2, 2024
Integration of MOF-MXene hybrid material into an EGFET configuration for enzyme-free and non-invasive glucose detection to diagnose diabetes mellitus.
Language: Английский
Sustainable materials and technologies, Journal Year: 2025, Volume and Issue: 43, P. e01239 - e01239
Published: Jan. 6, 2025
Language: Английский
Citations
0
ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: March 28, 2025
In this study, we present the effect of catalytic performance in Mn-MOF upon incorporating varied concentrations phthalocyanine derivative (H2PcP8OH16) for ascorbic acid detection an extended gate field-effect transistor (EGFET) configuration. The fabricated Mn-OM-MOF-2/CP electrode demonstrated notable selectivity toward physiological conditions sweat, with a sensitivity 71.375 μA·mM–1·cm–2, response time less than 6 s, and linear range from 5 to 240 μM. limit (LOD) quantification (LOQ) were found be 0.26 0.78 μM, respectively. Remarkably, prepared electrodes followed Michaelis–Menten kinetics. Among them, highest affinity acid, Km value 0.142 mM. To gain deeper insights into charge transfer mechanism during interaction Mn-OM-MOF-2/CP, employed scanning Kelvin probe (SKP) technique conducted post-FTIR analysis understand sensing mechanism. Additionally, post-UV–visible (UV–vis) measurements performed explore how incorporation enhances affinity. Additional studies using standard artificial sweat have confirmed electrode's good recovery. Overall, results EGFET method suitability rapid, noninvasive, single-use 1× phosphate buffer saline (1× PBS).
Language: Английский
Citations
0
ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(44), P. 61204 - 61217
Published: Oct. 22, 2024
Functionalization of hybrid organic molecules as layers on ZnO nanoflowers (NFs) gives an excellent combination sensing toward visible light and vapors various volatile compounds (VOCs). In this work, functionalized NFs were utilized for the photoinduced detection benzylamine at room temperature. The synthesized via a facile solution route with four different porphyrin-conjugated namely (i) pyrene-porphyrin (PP), (ii) pyrene- porphyrinato zinc (ZnPP), (iii) triphenylamine- porphyrin (TP) (iv) (ZnTP). diameter flower-like structure was found to be ∼3.2 μm thickness petals being ∼24.1 nm. gas adsorption performance activation temperature studied by using scanning Kelvin probe (SKP) system. improved properties samples can attributed heterojunctions activation. particular, enhanced response ZnTP (ZnTPZ) observed. Further, static experiments ZnTPZ under concentrations (1, 3, 5, 10, 15, 25 ppm) both in dark conditions have exhibited linear increase response. selectively compared that pristine thus confirmed 1 ppm benzylamine. sensitivity limit sensor calculated 0.0292 ppm-1 197 ppb, respectively. coordination metal (Zn) has helped effective charge transfer between providing additional active sites interactions. Also, density functional theory calculations demonstrated role surface improving adsorption. fresh cabbage real sample analysis proposed illumination conditions, obtained low evaluation Overall, results suggest development novel ZnTPZ-based light-activated sensors These kinds used track freshness vegetables they are transported from farms commercial outlets.
Language: Английский
Citations
1
Journal of Materials Chemistry B, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 2, 2024
Integration of MOF-MXene hybrid material into an EGFET configuration for enzyme-free and non-invasive glucose detection to diagnose diabetes mellitus.
Language: Английский
Citations
1