TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 178, P. 117862 - 117862
Published: July 10, 2024
Language: Английский
TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 178, P. 117862 - 117862
Published: July 10, 2024
Language: Английский
Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(14), P. 9811 - 9818
Published: March 26, 2024
Perfluorooctanoic acid (PFOA) is an environmental contaminant ubiquitous in water resources, which as a xenobiotic and carcinogenic agent, severely endangers human health. The development of techniques for its efficient removal therefore highly sought after. Herein, we demonstrate unprecedented zirconium-based MOF (PCN-999) possessing Zr6 biformate-bridged (Zr6)2 clusters simultaneously, exhibits exceptional PFOA uptake 1089 mg/g (2.63 mmol/g), representing ca. 50% increase over the previous record MOFs. Single-crystal X-ray diffraction studies computational analysis revealed that offer additional open coordination sites hosting PFOA. coordinated PFOAs further enhance interaction between free physical adsorption, boosting adsorption capacity to unparalleled high standard. Our findings represent major step forward fundamental understanding MOF-based mechanism, paving way toward rational design next-generation adsorbents per- polyfluoroalkyl substance (PFAS) removal.
Language: Английский
Citations
27TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 178, P. 117830 - 117830
Published: June 24, 2024
Language: Английский
Citations
21Talanta, Journal Year: 2024, Volume and Issue: 275, P. 126100 - 126100
Published: April 13, 2024
Language: Английский
Citations
20Advances in Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 331, P. 103210 - 103210
Published: June 5, 2024
Language: Английский
Citations
19TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 178, P. 117862 - 117862
Published: July 10, 2024
Language: Английский
Citations
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