Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 652, P. 636 - 645
Published: July 25, 2023
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 652, P. 636 - 645
Published: July 25, 2023
Language: Английский
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(5), P. 2505 - 2524
Published: Jan. 1, 2024
This work summarizes a review on the selective oxidation of glycerol via photocatalysis/photoelectrocatalysis. We elucidate unique reaction pathways induced by photo-generated reactive species from green chemistry point view.
Language: Английский
Citations
35ACS Nano, Journal Year: 2024, Volume and Issue: 18(31), P. 20740 - 20750
Published: July 23, 2024
High-entropy materials (HEMs) have garnered extensive attention owing to their diverse and captivating physicochemical properties. Yet, fine-tuning morphological properties of HEMs remains a formidable challenge, constraining potential applications. To address this, we present rapid, low-energy consumption diethylenetriamine (DETA)-assisted microwave hydrothermal method for synthesizing series two-dimensional high-entropy selenides (HESes). Subsequently, the obtained HESes are harnessed photocatalytic water splitting. Noteworthy is optimized HESes, Cd
Language: Английский
Citations
22Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 348, P. 123834 - 123834
Published: April 24, 2024
Language: Английский
Citations
20Nature Synthesis, Journal Year: 2024, Volume and Issue: 3(4), P. 438 - 451
Published: March 26, 2024
Language: Английский
Citations
17International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 102, P. 963 - 971
Published: Jan. 13, 2025
Language: Английский
Citations
2Green Chemistry, Journal Year: 2023, Volume and Issue: 25(21), P. 8313 - 8327
Published: Jan. 1, 2023
This review highlights the recent advances in various electrochemical and photochemical reactions using methanol as a sustainable C1 source.
Language: Английский
Citations
39Accounts of Chemical Research, Journal Year: 2023, Volume and Issue: 56(24), P. 3558 - 3571
Published: Nov. 29, 2023
ConspectusIn recent years, significant efforts have been directed toward achieving efficient and mild lignocellulosic biomass conversion into valuable chemicals fuels, aiming to address energy environmental concerns realize the goal of carbon neutrality. Lignin is one three primary building blocks lignocellulose only aromatic renewable feedstock. However, complex diverse nature lignin feedstocks, characterized by their three-dimensional, highly branched polymeric structure intricate C-O/C-C chemical bonds, results in substantial challenges. To tackle these challenges, we carried out extensive research on selectively activating transforming bonds for synthesis. In this Account, discuss our progress catalytic conversion.Our work focused two main objectives: (i) precise selective transformation (and its model compounds) (ii) fully utilizing nuclei side chains present produce chemicals. consists interconnected phenylpropanoid subunits linked interlaced C-C/C-O bonds. unlock full potential lignin, propose concept "the utilization lignin", which encompasses both (e.g., methoxyl polyhydroxypropyl groups).For nuclei, activation C-O and/or C-C crucial synthesizing targeted products. We begin with compounds (such as anisole, phenol, guaiacol, etc.) then transition protolignin feedstocks. Various reaction routes are developed, including self-supported hydrogenolysis, direct Caryl-Csp3 cleavage, coupled cleavage Caryl-O tandem hydrogenation hydrolysis processes. These tailored pathways enable high-yield sustainable production a wide range derived) products, arenes (benzene, toluene, alkylbenzenes), phenols, ketones, acids.In terms chain utilization, developed innovative strategies such methyl transfer, coupling depolymerization-methyl shift, acetyl new methods amine-assisted prefunctionalization. synthesis methyl-/alkyl-derived acetic acid, 4-ethyltoluene, dimethylethylamine, amides. Additionally, residues can be transformed or functionalized ingredients that serve catalysts functional biopolymer materials. findings highlight promising opportunities harnessing creative manner, thereby improving overall atom economy upgrading.Through catalyst engineering route strategies, achieves various from lignin. By integrating rings, successfully synthesized aromatic-derived products high yields. The not minimizes waste but also opens up possibilities generating novel approaches untapped expand boundaries upgrading, enhance efficiency economic viability biorefining.
Language: Английский
Citations
30Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 655, P. 943 - 952
Published: Nov. 7, 2023
Language: Английский
Citations
25Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 92, P. 705 - 729
Published: Feb. 6, 2024
Language: Английский
Citations
16Advanced Science, Journal Year: 2024, Volume and Issue: 11(29)
Published: May 30, 2024
Abstract Hydrogen (H 2 ) has emerged as a clean and versatile energy carrier to power carbon‐neutral economy for the post‐fossil era. generation from low‐cost renewable biomass by virtually inexhaustible solar presents an innovative strategy process organic solid waste, combat crisis, achieve carbon neutrality. Herein, progress breakthroughs in solar‐powered H production are reviewed. The basic principles of solar‐driven first introduced better understanding reaction mechanism. Next, merits shortcomings various semiconductors cocatalysts summarized, strategies addressing related issues also elaborated. Then, bio‐based feedstocks reviewed with emphasis on effect photocatalysts catalytic systems performance. Of note, concurrent value‐added chemicals reforming is emphasized well. Meanwhile, emerging photo‐thermal coupling that shows grand prospect maximally utilizing entire spectrum discussed. Further, direct utilization hydrogen green reductant producing via reactions highlighted. Finally, challenges perspectives photoreforming toward envisioned.
Language: Английский
Citations
16