ACS Sustainable Chemistry & Engineering,
Journal Year:
2024,
Volume and Issue:
12(4), P. 1625 - 1631
Published: Jan. 16, 2024
Photocatalytic
decomposition
of
formic
acid
(FA)
to
syngas
(H2
+
CO)
is
a
valuable
sustainable
energy
conversion
strategy.
In
this
study,
we
combine
In2S3
nanoparticles
with
Cd0.9Zn0.1S
nanorods
(In2S3/CZS)
construct
heterojunctions
for
directly
converting
under
visible
light
(λ
>
420
nm)
irradiation.
The
In2S3/CZS
composite
was
facilely
synthesized
by
hydrothermal
reaction.
showed
excellent
photocatalytic
activity
FA
decomposition.
optimal
generation
rates
H2
and
CO
can
reach
200
204
μmol·h–1,
respectively,
which
one
the
best
performances
in
synthesizing
syngas.
Under
irradiation
nm
monochromatic
light,
exhibit
apparent
quantum
yields
9.7%
10.6%,
respectively.
test
date
confirms
formation
type
II
heterojunction
between
nanoparticles.
It
effectively
promote
transport
separation
interfacial
charges.
This
work
also
provides
insight
into
development
an
efficient
system
production.
Biotechnology Advances,
Journal Year:
2023,
Volume and Issue:
69, P. 108276 - 108276
Published: Nov. 1, 2023
Microbial
fermentation
processes
are
expected
to
play
an
important
role
in
reducing
dependence
on
fossil-based
raw
materials
for
the
production
of
everyday
chemicals.
In
order
meet
growing
demand
biotechnological
products
future,
alternative
carbon
sources
that
do
not
compete
with
human
nutrition
must
be
exploited.
The
chemical
conversion
industrially
emitted
greenhouse
gas
CO
Catalysis Today,
Journal Year:
2024,
Volume and Issue:
432, P. 114587 - 114587
Published: Feb. 17, 2024
In
the
past
decades,
photocatalytic
and
photoelectrocatalytic
methods
have
been
widely
employed
for
degradation
of
harmful
compounds
present
both
is
gaseous
aqueous
effluents.
last
years
scientists
paid
great
attention
to
synthesis
valuable
hydrogen
production.
Organic
syntheses
are
generally
carried
out
in
organic
solvents,
under
high
temperature/pressure,
with
toxic
oxidants
such
as
permanganate.
On
other
hand,
photocatalysis
photoelectrocatalysis
using
water
solvent,
air
or
oxidant,
sunlight
energy
source,
can
be
an
efficient
alternative
traditional,
non-environmentally
friendly
methods.
This
review
summarizes
transformations
molecules
commercially
products
water,
sometimes
evaluating
also
contemporary
H2
The
reaction
conditions,
mechanisms
kinetics
presented
discussed.
Future
perspectives
given.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(16)
Published: Feb. 27, 2024
Light-driven
hydrogen
production
from
biomass
derivatives
offers
a
path
towards
carbon
neutrality.
It
is
often
however
operated
with
the
limitations
of
sluggish
kinetics
and
severe
coking.
Herein,
disruptive
air-promoted
strategy
explored
for
efficient
durable
light-driven
ethanol
over
core/shell
Cr
ACS Sustainable Chemistry & Engineering,
Journal Year:
2024,
Volume and Issue:
12(4), P. 1625 - 1631
Published: Jan. 16, 2024
Photocatalytic
decomposition
of
formic
acid
(FA)
to
syngas
(H2
+
CO)
is
a
valuable
sustainable
energy
conversion
strategy.
In
this
study,
we
combine
In2S3
nanoparticles
with
Cd0.9Zn0.1S
nanorods
(In2S3/CZS)
construct
heterojunctions
for
directly
converting
under
visible
light
(λ
>
420
nm)
irradiation.
The
In2S3/CZS
composite
was
facilely
synthesized
by
hydrothermal
reaction.
showed
excellent
photocatalytic
activity
FA
decomposition.
optimal
generation
rates
H2
and
CO
can
reach
200
204
μmol·h–1,
respectively,
which
one
the
best
performances
in
synthesizing
syngas.
Under
irradiation
nm
monochromatic
light,
exhibit
apparent
quantum
yields
9.7%
10.6%,
respectively.
test
date
confirms
formation
type
II
heterojunction
between
nanoparticles.
It
effectively
promote
transport
separation
interfacial
charges.
This
work
also
provides
insight
into
development
an
efficient
system
production.
