Throwing Light on Synthetic Molecular Photoelectrocatalysis (Part II): selected recent transformations of organic compounds and a future perspective in organic synthesis
Current Opinion in Electrochemistry,
Journal Year:
2025,
Volume and Issue:
unknown, P. 101674 - 101674
Published: Feb. 1, 2025
Language: Английский
Photoelectrochemistry-Promoted Ni-Catalyzed C–O Cross-Couplings
Zhao‐Ran Liu,
No information about this author
Ye Wang,
No information about this author
Cong Ma
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et al.
Precision Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 10, 2025
Language: Английский
TEMPO-Mediated Electrochemical α-Allylation of Tetrahydroisoquinolines
Youliang He,
No information about this author
Zhen‐Hua Wang,
No information about this author
Huilin Liu
No information about this author
et al.
Organic Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 25, 2025
A
C(sp3)-H
allylation
of
tetrahydroisoquinolines
has
been
developed
by
combining
Shono
oxidation
with
a
vinylogous
Mannich-type
reaction.
TEMPO
was
used
as
the
electrocatalyst
to
lower
electrode
potential,
improving
functional
group
compatibility.
This
method
provided
practical
and
efficient
tandem
procedure
for
α-allylation
tetrahydroisoquinolines.
The
reaction
proceeded
through
formation
an
iminium
cation
intermediate,
which
generated
in
situ
anodic
oxidation,
followed
nucleophilic
addition
2-allylazaarenes.
Language: Английский