Analytica Chimica Acta, Journal Year: 2024, Volume and Issue: 1320, P. 342994 - 342994
Published: July 20, 2024
Language: Английский
Analytica Chimica Acta, Journal Year: 2024, Volume and Issue: 1320, P. 342994 - 342994
Published: July 20, 2024
Language: Английский
TrAC Trends in Analytical Chemistry, Journal Year: 2024, Volume and Issue: 180, P. 117961 - 117961
Published: Sept. 7, 2024
Language: Английский
Citations
9Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 531, P. 216520 - 216520
Published: Feb. 12, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160763 - 160763
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Hazardous Materials, Journal Year: 2025, Volume and Issue: 490, P. 137778 - 137778
Published: Feb. 26, 2025
Language: Английский
Citations
0Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 27, 2025
Abstract The domain‐limited catalytic enhancement has opened novel avenues for the advancement of highly efficient aggregation‐induced electrochemiluminescence (AIECL). Herein, a (ECL) sensing platform is constructed through in situ encapsulation emission (AIE) molecules, tetraphenylethylene, within metal‐organic frameworks (NH 2 ‐MIL‐88). These are uniquely enriched with atomically dispersed active sites that serve as nanoconfined co‐reactant accelerators. This innovative design leads to creation an integrated AIE nanoconfinement reactor. Within this reactor, accelerators catalyze co‐reactants into reactive species (RS) situ, facilitating direct interaction molecules spatially confined composite. Density functional theory calculations and electrochemical electron paramagnetic resonance demonstrate ECL attributed localized amplification, where space formed by coordination self‐assembly alters activation energy barriers improves absorption capacity catalyzing K S O 8 SO 4 ·‐ OH ·− . Additionally, utilizing MATLAB‐mediated image technology deep learning algorithms, smartphone‐adopted self‐reporting AIECL imaging system designed achieve accurate intelligent analysis cardiac troponin I (cTnI). method presents advanced strategy enhance local RS concentrations via catalysis. developed offers facile screening cTnI monitoring.
Language: Английский
Citations
0Food Chemistry, Journal Year: 2025, Volume and Issue: 475, P. 143246 - 143246
Published: Feb. 6, 2025
Language: Английский
Citations
0Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113241 - 113241
Published: March 1, 2025
Language: Английский
Citations
0Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: May 5, 2025
Nanoplastic pollution has emerged as a significant issue in both the environmental and human health fields. However, developing highly sensitive approaches to promptly identify detect low concentrations of nanoplastics within complex systems remains considerable challenge. Here, we utilized amphiphilic perylene diimide (PDI-NH2) probe combination with electrochemiluminescence (ECL) for detection polypropylene (PP) nanoplastics. The PDI-NH2 shows remarkable enhancement ECL signal on PP aqueous solutions, presenting concentration-dependent response. This enables ultrasensitive specific solutions limit 0.948 mg·L-1. A series comprehensive experiments indicate that binds through electrostatic hydrophobic interactions. Moreover, isothermal titration calorimetry density functional theory (DFT) calculations further confirm can be attributed strong affinity between leads significantly high electron transfer rate. Additionally, it is notable proved its effectiveness detecting actual samples, opening up possibilities application monitoring assessing various industrial settings.
Language: Английский
Citations
0Analytical Chemistry, Journal Year: 2024, Volume and Issue: 96(49), P. 19473 - 19482
Published: Nov. 29, 2024
Herein, the bovine serum albumin (BSA)-loaded tetrakis[4-(4′-cyanophenyl)phenyl]ethane nanoaggregates (NAs) (BSA@TBPE-(CN)4 NAs) as a novel electrochemiluminescence (ECL) emitter were first prepared, which exhibited superior ECL performance via newly defined protein-induced enhancement. Impressively, BSA not only restricted intramolecular motions by its hydrophobic cavity to improve optical radiation for enhancing efficiency but also promoted electrochemical excitation of BSA@TBPE-(CN)4 NAs in amino acid residues altered surface states and narrowed energy gap further boosting efficiency. Furthermore, displayed more dispersed state due electrostatic repulsion caused considerable negative charges, was conducive reacting fully with coreactants improving emission. Excitingly, threefold stronger intensity 4.8-fold higher compared those TBPE-(CN)4 NAs. Thus, an application, biosensor fabricated based on efficient mismatch-fueled three-dimensional (3D) DNA walker effective signal amplifier rapid ultrasensitive detection microRNA-21 limit (LOD) 19.1 aM, it successfully applied assess expression human cancer cells MCF-7 HeLa. This work developed avenue reasonably synthesize highly organic emitters motivating their potential application biosensing high-resolution bioimaging.
Language: Английский
Citations
1Current Opinion in Electrochemistry, Journal Year: 2024, Volume and Issue: 49, P. 101627 - 101627
Published: Dec. 5, 2024
Language: Английский
Citations
1