A classical [V10O28]6− anion templated high-nuclearity silver thiolate cluster DOI
Li Li,

Yanjie Zhu,

Bao‐Liang Han

et al.

Chemical Communications, Journal Year: 2022, Volume and Issue: 58(66), P. 9234 - 9237

Published: Jan. 1, 2022

The largest known polyoxovanadate-templated silver nanocluster (Ag50) was synthesized, and the box-like {V 10 O 28 @Ag 50 } structure displays geometric inheritance from internal decavanadate to skeleton.

Language: Английский

Molybdate-Templated Luminescent Silver Alkynyl Nanoclusters: Total Structure Determination and Optical Property Analysis DOI
Le Yang, Fahime Bigdeli,

Xiaojiao Yang

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(17), P. 7631 - 7639

Published: April 16, 2024

Two novel MoO42–-templated luminescent silver alkynyl nanoclusters with 20-nuclearity ([(MoO42–)@Ag20(C≡CtBu)8(Ph2PO2)7(tfa)2]·(tfa–) (1)) and 18-nuclearity ([(MoO42–)@Ag18(C≡CtBu)8(Ph2PO2)7]·(OH) (2)) (tfa = trifluoroacetate) were synthesized the green light maximum emissions at 507 516 nm, respectively. The investigated characterized by single-crystal X-ray crystallography, electrospray ionization mass spectrum (ESI-MS), photoelectron spectroscopy, thermogravimetry (TG), photoluminescence (PL), ultraviolet–visible (UV–vis) density functional theory calculations (DFT). two differ in their structure a supplementary [Ag2(tfa)2] organometallic surface motif, which significantly participates frontier molecular orbitals of 1, resulting similar bonding patterns but different optical properties between clusters. Indeed, both show strong temperature-dependent properties, make them potential candidates fields devices for further applications.

Language: Английский

Citations

2
Polyoxometalates containing aluminum atoms DOI

Limin Cui,

Wei‐Hui Fang, Jian Zhang

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110386 - 110386

Published: Aug. 1, 2024

Citations

2
Oxocarbon Anions Templated in Silver Clusters DOI
Jian‐Hong Liao, Hao Chen,

Hong-Jhih You

et al.

Inorganic Chemistry, Journal Year: 2022, Volume and Issue: 61(35), P. 14115 - 14120

Published: Aug. 22, 2022

Three types of oxocarbon anions as templates were used to synthesize high-nuclear silver clusters, [Ag16(C2O4){S2P(OEt)2}12]2(PF6)4 (1), [Ag16(C4O4){S2P(OEt)2}12]2(PF6)4 (2), and [Ag32(S)2(C5O5)2{S2P(OEt)2}22](PF6)2 (3), characterized by multi-NMR spectroscopy X-ray crystallography. As the template size increases, shape clusters change accordingly. The effect in has been investigated this work.

Language: Английский

Citations

10
One-step assembly of Pd-Keggin-polyoxometalates for catalytic benzothiadiazole generation and derived cell-imaging probe application DOI
Xianqiang Huang, Wei-Long Cui, Sen Liu

et al.

Chinese Chemical Letters, Journal Year: 2022, Volume and Issue: 34(6), P. 107692 - 107692

Published: July 19, 2022

Language: Английский

Citations

10
A classical [V10O28]6− anion templated high-nuclearity silver thiolate cluster DOI
Li Li,

Yanjie Zhu,

Bao‐Liang Han

et al.

Chemical Communications, Journal Year: 2022, Volume and Issue: 58(66), P. 9234 - 9237

Published: Jan. 1, 2022

The largest known polyoxovanadate-templated silver nanocluster (Ag50) was synthesized, and the box-like {V 10 O 28 @Ag 50 } structure displays geometric inheritance from internal decavanadate to skeleton.

Language: Английский

Citations

9