ACS Applied Materials & Interfaces,
Journal Year:
2021,
Volume and Issue:
13(18), P. 21516 - 21526
Published: April 30, 2021
Energetic
metal–organic
frameworks
(EMOFs)
with
a
high
oxygen
content
are
currently
hot
spot
in
the
field
of
energetic
materials
research.
In
this
article,
two
series
EMOFs
different
ligands
were
obtained
by
reacting
1-(trinitromethyl)-1H-1,2,4-triazole-3-carboxylic
acid
(tntrza)
metal
iodide
and
nitrate,
respectively.
Furthermore,
their
structure,
thermal
stability,
decomposition
kinetics,
energy
performance
fully
characterized.
The
research
results
revealed
that
synthesized
possess
wide
range
density
(ρ
=
1.88∼2.595
g
cm–3),
balance
(OB(CO2)
−21.1∼
−4.3%),
acceptable
(D
7.73∼8.74
km
s–1
P
28.1∼41.1
GPa).
difference
OB(CO2)
caused
ligand
structure
properties
has
great
impact
on
distribution
gas-phase
products
after
these
EMOFs.
Noteworthy,
[Ag(tntrza)]n
is
particularly
prominent
among
EMOFs,
not
only
because
its
excellent
detonation
8.74
41.1
GPa)
endowed
extremely
2.595
cm–3)
−4.3%)
but
also
effective
catalytic
effect
ammonium
perchlorate
(AP).
This
article
broadens
horizon
for
study
oxygen-enriched
effects
helps
understand
mechanism
nitroform
dinitro
groups.
Inorganic Chemistry,
Journal Year:
2022,
Volume and Issue:
61(9), P. 4143 - 4149
Published: Feb. 22, 2022
In
recent
years,
molecular
perovskite
energetic
materials
have
attracted
more
attention
because
of
their
simple
synthesis
processes,
high
thermal
stabilities,
excellent
performances,
and
great
significance
as
a
design
platform
for
materials.
To
explore
the
possibility
application
in
heat-resistant
explosives,
four
silver(I)-based
compounds,
(H2A)[Ag(ClO4)3],
where
H2A
=
piperazine-1,4-diium
(H2pz2+)
PAP-5,
1-methyl-piperazine-1,4-diium
(H2mpz2+)
PAP-M5,
homopiperazine-1,4-diium
(H2hpz2+)
PAP-H5,
1,4-diazabicyclo[2.2.2]octane-1,4-diium
(H2dabco2+)
DAP-5,
were
synthesized
by
one-pot
self-assembly
strategy
structurally
characterized.
The
single-crystal
structures
indicated
that
DAP-5
possess
cubic
while
PAP-H5
possesses
hexagonal
structure.
Differential
analyses
showed
onset
decomposition
temperatures
are
>308.3
°C.
For
PAP-5
they
not
only
exceptional
calculated
detonation
parameters
(D
values
8.961
8.534
km
s-1
P
42.4
37.9
GPa,
respectively)
but
also
proper
mechanical
sensitivity
(impact
sensitivities
≤10
J
3
friction
≤5N
both
DAP-5)
thus
interest
potential
primary
explosive
components.
Small,
Journal Year:
2022,
Volume and Issue:
18(13)
Published: Feb. 10, 2022
It
is
highly
desired
but
still
remains
challenging
to
design
a
primary
explosive-based
nanoparticle-encapsulated
conductive
skeleton
for
the
development
of
powerful
yet
safe
energetic
films
employed
in
miniaturized
explosive
systems.
Herein,
proof-of-concept
electrochemical
preparation
metal-organic
frameworks
(MOFs)
derived
porous
carbon
embedding
copper-based
azide
(Cu(N3
)2
or
CuN3
,
CA)
nanoparticles
on
copper
substrate
described.
A
Cu-based
MOF,
i.e.,
Cu-BTC
fabricated
based
anodized
Cu(OH)2
nanorods,
as
template,
achieve
CA/C
film
through
pyrolysis
and
azidation.
Such
film,
which
woven
by
numerous
ultrafine
nanofibers,
favorably
demonstrates
excellent
energy
release
(945-2090
J
g-1
),
tunable
electrostatic
sensitivity
(0.22-1.39
mJ),
considerable
initiation
ability.
The
performance
superior
most
reported
explosives,
since
CA
contribute
high
brisance
protection
network.
Notably,
growth
mechanism
further
disclosed
detailed
experimental
investigation
density
functional
theory
(DFT)
calculation.
This
work
will
offer
new
insight
develop
CA-based
applications
advanced
Inorganic Chemistry Frontiers,
Journal Year:
2022,
Volume and Issue:
9(22), P. 5884 - 5892
Published: Jan. 1, 2022
The
unique
type
of
molecular
architectures
with
a
remarkable
initiation
ability
and
enhanced
stability
is
proposed.
relationship
between
the
structure
sensitivity
Cu(N
3
)
2
-based
primary
explosive
revealed.
