Advanced Materials,
Journal Year:
2023,
Volume and Issue:
35(40)
Published: June 26, 2023
Artificial
photosynthetic
diluted
CO2
reduction
directly
driven
by
natural
sunlight
is
a
challenging,
but
promising
way
to
realize
carbon-resources
recycling
utilization.
Herein,
three-in-one
photocatalytic
system
of
enrichment,
and
H2
O
oxidation
sites
designed
for
reduction.
A
Zn-Salen-based
covalent
organic
framework
(Zn-S-COF)
with
reductive
synthesized;
then,
ionic
liquids
(ILs)
are
loaded
into
the
pores.
As
result,
[Emim]BF4
@Zn-S-COF
shows
visible-light-driven
-to-CO
conversion
rate
105.88
µmol
g-1
h-1
under
(15%)
atmosphere,
even
superior
than
most
photocatalysts
in
high
concentrations
.
Moreover,
also
reaches
126.51
5
h.
Further
experiments
theoretical
calculations
reveal
that
triazine
ring
Zn-S-COF
promotes
activity
sites,
ILs
provide
an
enriched
realizing
efficient
Biophysical Reviews,
Journal Year:
2018,
Volume and Issue:
10(3), P. 691 - 706
Published: April 26, 2018
Abstract
There
is
no
doubt
that
ionic
liquids
have
become
a
major
subject
of
study
for
modern
chemistry.
We
used
to
ever
more
publications
in
the
field
each
year,
although
there
some
evidence
this
beginning
plateau
at
approximately
3500
papers
year.
They
been
several
reviews
and
books,
dealing
with
different
applications
aspects
their
behaviours.
In
article,
I
will
show
little
how
interest
grew
developed.
Chemical Reviews,
Journal Year:
2019,
Volume and Issue:
119(8), P. 5416 - 5460
Published: April 4, 2019
This
comprehensive
Review
focuses
on
the
key
challenges
and
recent
progress
regarding
sodium-metal
anodes
employed
in
batteries
(SMBs).
The
metal
anode
is
essential
component
of
emerging
energy
storage
systems
such
as
sodium
sulfur
selenium,
which
are
discussed
example
full-cell
applications.
We
begin
with
a
description
differences
chemical
physical
properties
Na
versus
oft-studied
Li
metal,
corresponding
discussion
number
ways
does
not
follow
Li-inherited
paradigms
its
electrochemical
behavior.
detail
major
for
Na-metal
that
at
this
time
limit
feasibility
SMBs.
core
problems
following
interrelated
degradation
mechanisms:
An
unstable
solid
electrolyte
interphase
most
organic
electrolytes,
"mossy"
"lath-like"
dendrite
growth
liquid
systems,
poor
Coulombic
efficiency,
gas
evolution.
Even
solid-state
immune,
dendrites
being
reported.
solutions
may
be
subdivided
into
taxonomy:
Improved
electrolytes
additives
tailored
anodes,
interfacial
engineering
between
or
electrolyte,
electrode
architectures
both
reduce
current
density
during
plating–stripping
serve
effective
hosts
shield
from
excessive
reactions,
alloy
design
to
tune
bulk
per
se.
For
instance,
stable
extremely
difficult
conventional
carbonate
solvents
but
has
been
reported
ethers
glymes.
Solid-state
(SSEs)
beta-alumina
(BASE),
superionic
conductor
(NASICON),
thiophosphate
(75Na2S·25P2S5)
present
highly
exciting
opportunities
SMBs
avoid
dangers
flammable
liquids.
SSEs
immune
dendrites,
however,
grow
through
defects
pellet,
controlled
modification.
conclude
research
areas
we
feel
fruitful
further
pursuit.
In
our
opinion,
greatly
improved
understanding
control
SEI
structure
cycling
stability.
A
holistic
approach
involving
complementary
post-mortem,
situ,
operando
analyses
elucidate
full
battery
cell
level
structure–performance
relations
advocated.
Green Energy & Environment,
Journal Year:
2019,
Volume and Issue:
4(2), P. 95 - 115
Published: Feb. 5, 2019
Biomass
is
renewable,
abundant,
cheap,
biocompatible,
and
biodegradable
materials
has
been
used
to
produce
chemicals,
materials,
energy,
fuels.
However,
most
of
the
biomass,
especially
biomass
polymers
are
not
soluble
in
common
solvents,
which
hinders
their
pretreatment
conversion.
Deep
eutectic
solvents
(DESs)
environmental-friendly,
highly
tunable,
with
high
solubility,
renders
them
potential
applications
They
could
be
as
or
catalysts
so
on.
This
paper
intends
review
application
DESs
for
conversion
value-added
products.
We
focus
on
following
topics
related
DESs:
(1)
biomass;
(2)
dissolution
separation
extraction
chemicals
from
(3)
conversion;
(4)
Drawbacks,
recyclability
biomass.
Angewandte Chemie International Edition,
Journal Year:
2019,
Volume and Issue:
58(35), P. 11978 - 11996
Published: Jan. 28, 2019
Abstract
Aluminum
battery
systems
are
considered
as
a
system
that
could
supplement
current
lithium
batteries
due
to
the
low
cost
and
high
volumetric
capacity
of
aluminum
metal,
safety
whole
system.
However,
first
use
ionic
liquid
electrolytes
leading
AlCl
4
−
instead
Al
3+
,
different
intercalation
reagents,
sluggish
solid
diffusion
process
fast
fading
during
cycling
in
all
need
be
thoroughly
explored.
To
provide
good
understanding
opportunities
challenges
newly
emerging
batteries,
this
Review
discusses
reaction
mechanisms
difficulties
caused
by
trivalent
medium
electrolytes,
electrodes,
electrode–electrolyte
interfaces.
It
is
hoped
will
stimulate
scientists
engineers
develop
more
reliable
batteries.
Bioengineered,
Journal Year:
2020,
Volume and Issue:
11(1), P. 116 - 129
Published: Jan. 1, 2020
The
richness
of
high-value
bio-compounds
derived
from
microalgae
has
made
a
promising
and
sustainable
source
useful
product.
present
work
starts
with
review
on
the
usage
open
pond
photobioreactor
in
culturing
various
strains,
followed
by
an
in-depth
evaluation
common
harvesting
techniques
used
to
collect
culture
medium.
methods
discussed
include
filtration,
centrifugation,
flocculation,
flotation.
Additionally,
advanced
extraction
technologies
using
ionic
liquids
as
extractive
solvents
applied
extract
such
lipids,
carbohydrates,
proteins,
other
bioactive
compounds
biomass
are
summarized
discussed.
However,
more
needs
be
done
fully
utilize
potential
for
application
large-scale
production
biofuels,
food
additives,
nutritive
supplements.
Advanced Functional Materials,
Journal Year:
2020,
Volume and Issue:
30(24)
Published: April 6, 2020
Abstract
Ionic
liquids
(ILs)
have
emerged
as
a
novel
class
of
chemical
compounds
for
the
development
advanced
(multi)functional
materials
with
outstanding
potential
in
applications
several
areas
due
to
their
unique
properties
and
functionalities.
The
combination
ILs
polymers,
composite,
allows
developing
smart
materials,
which
synergistically
combine
features
specific
polymers
ILs.
Moreover,
can
be
extensively
modified
by
incorporation
functional
groups
into
cation,
anion,
or
both.
Thus,
it
is
possible
tune
IL,
polymer,
both
obtain
broad
spectrum
multifunctional
composites
address
requirements
many
applications.
This
work
focusses
on
strategies
concerning
IL/polymer‐based
including
responsive
sensitive
sensors,
actuators,
environment,
batteries,
fuel
cells,
biomedical
