Molecules,
Journal Year:
2025,
Volume and Issue:
30(2), P. 353 - 353
Published: Jan. 16, 2025
Thanks
to
their
unique
physicochemical
properties,
ionic
liquids
(ILs)
have
moved
from
niche
academic
interest
critical
components
in
various
industrial
applications.
The
textile
industry,
facing
significant
environmental
and
economic
pressures,
has
begun
explore
ILs
as
sustainable
alternatives
traditional
solvents
chemicals.
This
review
summarizes
research
on
the
use
of
processes,
including
dyeing,
finishing,
fiber
recycling,
where
high
thermal
stability,
tunable
solubility,
low
volatility
are
exploited
reduce
resource
consumption
impact.
discussion
also
extends
integration
waste
highlighting
innovative
approaches
dissolution
regeneration
aimed
at
circular
economy
goals.
Despite
these
advances,
challenges
such
production
costs
scalability
remain
barriers
widespread
adoption
sector.
Addressing
through
continued
development
is
essential
fully
realize
potential
for
transformation
textiles.
Molecules,
Journal Year:
2020,
Volume and Issue:
25(21), P. 5207 - 5207
Published: Nov. 9, 2020
Since
their
conception,
ionic
liquids
(ILs)
have
been
investigated
for
an
extensive
range
of
applications
including
in
solvent
chemistry,
catalysis,
and
electrochemistry.
This
is
due
to
designation
as
designer
solvents,
whereby
the
physiochemical
properties
IL
can
be
tuned
specific
applications.
has
led
significant
research
activity
both
by
academia
industry
from
1990s,
accelerating
many
fields
leading
filing
numerous
patents.
However,
while
ILs
received
great
interest
patent
literature,
only
a
limited
number
processes
are
known
commercialised.
review
aims
provide
perspective
on
successful
commercialisation
IL-based
processes,
date,
advantages
disadvantages
associated
with
use
industry.
Chemical Reviews,
Journal Year:
2020,
Volume and Issue:
120(13), P. 5798 - 5877
Published: April 15, 2020
Ionic
liquids
(ILs)
are
a
special
category
of
molten
salts
solely
composed
ions
with
varied
molecular
symmetry
and
charge
delocalization.
The
versatility
in
combining
cation-anion
moieties
functionalizing
different
atoms
groups
contributes
to
their
peculiar
interactions
ranging
from
weak
isotropic
associations
strong,
specific,
anisotropic
forces.
A
delicate
interplay
among
intra-
intermolecular
facilitates
the
formation
heterogeneous
microstructures
liquid
morphologies,
which
further
striking
dynamical
properties.
Microstructural
heterogeneities
ILs
lead
multifaceted
properties
described
by
an
inherent
designer
feature,
makes
important
candidates
for
novel
solvents,
electrolytes,
functional
materials
academia
industrial
applications.
Due
massive
number
combinations
ion
pairs
species
having
distinct
structures
IL
mixtures
containing
comprehensive
understanding
hierarchical
structural
quantities
is
great
significance
rational
selection
appropriate
thereafter
advancing
macroscopic
functionalities
In
this
review,
we
comprehensively
trace
recent
advances
strong
that
underpin
complex
phase
behaviors
particular
emphasis
on
dynamics
bulk
liquids,
cosolvents,
interfacial
regions.
Green Chemistry,
Journal Year:
2021,
Volume and Issue:
23(14), P. 4980 - 5005
Published: Jan. 1, 2021
The
entrapment
of
enzymes
in
organic,
inorganic
or
biomaterials
can
yield
active
immobilized
biocatalysts
for
chemical
transformations
without
the
need
to
form
covalent
bonds
with
protein.
Green Chemistry,
Journal Year:
2020,
Volume and Issue:
22(23), P. 8116 - 8139
Published: Jan. 1, 2020
This
critical
review
highlights
the
recent
advancements
of
using
biocompatible
ionic
liquids
as
“green”
designer
solvents
and/or
materials
to
overcome
limitations
caused
by
conventional
organic
solvents/materials
in
pharmaceutics
and
medicine.
Molecules,
Journal Year:
2022,
Volume and Issue:
27(4), P. 1368 - 1368
Published: Feb. 17, 2022
Recently,
deep
eutectic
solvent
(DES)
or
ionic
liquid
(IL)
analogues
have
been
considered
as
the
newest
green
solvent,
demonstrating
potential
to
replace
harsh
volatile
organic
solvents.
DESs
are
mainly
a
combination
of
two
compounds:
hydrogen
bond
acceptor
(HBA)
and
donor
(HBD),
which
ability
interact
through
extensive
bonds.
A
thorough
understanding
their
physicochemical
properties
is
essential,
given
successful
applications
on
an
industrial
scale.
The
appropriate
blend
HBA
HBD
can
easily
fine-tune
DES
for
desired
applications.
In
this
context,
we
reviewed
basic
information
related
DESs,
most
studied
(density
viscosity),
performance
in
(i)
drug
delivery
(ii)
extraction
biomolecules.
broader
approach
various
factors
affecting
has
considered,
giving
detailed
picture
current
status
research
development.
Chemical Reviews,
Journal Year:
2023,
Volume and Issue:
123(19), P. 11392 - 11487
Published: Sept. 20, 2023
From
scientific
and
technological
points
of
view,
poly(vinylidene
fluoride),
PVDF,
is
one
the
most
exciting
polymers
due
to
its
overall
physicochemical
characteristics.
This
polymer
can
crystalize
into
five
crystalline
phases
be
processed
in
form
films,
fibers,
membranes,
specific
microstructures,
being
physical
properties
controllable
over
a
wide
range
through
appropriate
chemical
modifications.
Moreover,
PVDF-based
materials
are
characterized
by
excellent
chemical,
mechanical,
thermal,
radiation
resistance,
for
their
outstanding
electroactive
properties,
including
high
dielectric,
piezoelectric,
pyroelectric,
ferroelectric
response,
best
among
systems
thus
noteworthy
an
increasing
number
technologies.
review
summarizes
critically
discusses
latest
advances
PVDF
copolymers,
composites,
blends,
main
characteristics
processability,
together
with
tailorability
implementation
areas
sensors,
actuators,
energy
harvesting
storage
devices,
environmental
microfluidic,
tissue
engineering,
antimicrobial
applications.
The
conclusions,
challenges
future
trends
concerning
application
also
presented.
Chemical Society Reviews,
Journal Year:
2023,
Volume and Issue:
52(7), P. 2497 - 2527
Published: Jan. 1, 2023
This
review
describes
the
most
recent
developments
in
materials
design
and
advanced
features
of
ionogels,
as
well
their
emerging
biomedical
applications.
Environmental Science & Technology,
Journal Year:
2021,
Volume and Issue:
55(3), P. 1419 - 1435
Published: Jan. 12, 2021
Ionic
liquids
(ILs)
as
novel
functional
desulfurization
materials
have
attracted
increasing
attentions.
Metal-based
ionic
(MILs)
are
classified
into
three
types
of
metal
chloride
ILs,
oxide
and
complex
ILs
based
on
the
definition
basic
structure
MILs
in
this
critical
review.
On
basis
properties
such
designability,
super
dissolution
performance,
good
thermal
chemical
stability,
nonflammability,
wide
electrochemical
window,
exhibit
unique
advantages
hydrophobicity,
oxidation
Brönsted-Lewis
acidity.
Therefore,
possess
both
absorption
centers
for
intramolecular
adsorption
to
improve
oxidative
(ODS)
process.
During
nonaqueous
wet
process
(Nasil),
H2S
can
be
oxidized
elemental
sulfur
with
hydrophobic
MILs,
which
regenerated
by
oxygen
recycle,
solve
problems
low
capacity,
quality,
severe
secondary
pollution
aqueous
Lo-Cat
Another
outstanding
feature
ODS
is
biomimetic
catalysis,
has
function
activating
molecular
improving
performance.
Metal
used
combination
hydrogen
peroxide
or
existing
water
generate
a
Fenton-like
reaction
convert
organic
SO2
hydrophilic
sulfoxide/sulfone
acid,
respectively.
However,
corrosion
Cl-
equipment
emulsification
phenomenon
extraction
separation
still
need
further
study.
Furthermore,
promising
strategies
construct
highly
efficient
green
processes
large-scale
applications
provided.
