Industrial Chemistry and Materials,
Journal Year:
2023,
Volume and Issue:
1(1), P. 39 - 59
Published: Jan. 1, 2023
Lithium
batteries
have
received
a
lot
of
attention
in
recent
years.
This
comment
reviewed
the
application
ionic
liquid
and
poly(ionic
liquid)-based
electrolytes
lithium
batteries.
Chemical Society Reviews,
Journal Year:
2021,
Volume and Issue:
50(15), P. 8596 - 8638
Published: Jan. 1, 2021
Various
eutectic
systems
have
been
proposed
and
studied
over
the
past
few
decades.
Most
of
studies
focused
on
three
typical
types
eutectics:
metals,
salts,
deep
solvents.
On
one
hand,
they
are
all
systems,
their
principle
is
same.
other
representative
inorganic
organic
substances,
respectively.
They
applications
in
almost
fields
related
to
chemistry.
Their
different
but
overlapping
stem
from
very
properties.
In
addition,
proposal
new
has
greatly
boosted
development
cross-field
research
involving
chemistry,
materials,
engineering,
energy.
The
goal
this
review
provide
a
comprehensive
overview
these
eutectics
describe
task-specific
strategies
address
growing
demands.
Angewandte Chemie International Edition,
Journal Year:
2017,
Volume and Issue:
57(7), P. 1898 - 1902
Published: Dec. 25, 2017
Abstract
The
electrochemical
performance
of
the
aluminum‐sulfur
(Al‐S)
battery
has
very
poor
reversibility
and
a
low
charge/discharge
current
density
owing
to
slow
kinetic
processes
determined
by
an
inevitable
dissociation
reaction
from
Al
2
Cl
7
−
free
3+
.
6
Br
was
used
instead
as
reagent.
A
15‐fold
faster
rate
than
that
confirmed
function
theory
calculations
Arrhenius
equation.
This
accelerated
experimentally
verified
increase
exchange
during
electro‐deposition.
Using
,
kinetically
Al‐S
sulfur
utilization
more
80
%,
with
at
least
four
times
content
five
previous
work.
Angewandte Chemie International Edition,
Journal Year:
2021,
Volume and Issue:
60(41), P. 22148 - 22165
Published: May 25, 2021
Ionic
liquids
and
deep
eutectic
solvents
are
of
growing
interest
as
for
the
resource-efficient
synthesis
inorganic
materials.
This
Review
covers
chemical
reactions
various
types
ionic
liquids,
including
metal-containing
[BF4
]-
-
or
[PF6
-based
basic
chalcogen-containing
liquids.
Cases
in
which
cations,
anions,
both
incorporated
into
final
products
also
included.
The
purpose
this
is
to
raise
caution
about
reactivity
establish
a
guide
their
proper
use.
Energy Material Advances,
Journal Year:
2021,
Volume and Issue:
2021
Published: Jan. 1, 2021
Developing
post-lithium-ion
battery
technology
featured
with
high
raw
material
abundance
and
low
cost
is
extremely
important
for
the
large-scale
energy
storage
applications,
especially
metal-based
systems
such
as
aluminum,
sodium,
magnesium
ion
batteries.
However,
their
developments
are
still
in
early
stages,
one
of
major
challenges
to
explore
a
safe
reliable
electrolyte.
An
ionic
liquid-based
electrolyte
attractive
promising
developing
nonflammable
devices
wide
temperature
ranges
owing
several
unique
properties
ultralow
volatility,
conductivity,
good
thermal
stability,
flammability,
electrochemical
window,
tunable
polarity
basicity/acidity.
In
this
review,
recent
emerging
limitations
strategies
electrolytes
above
summarized.
particular,
aluminum-ion
batteries,
interfacial
reaction
between
electrode,
mechanism
aluminum
storage,
optimization
composition
fully
discussed.
Moreover,
solve
problems
corrosion
system
side
reactions
also
highlighted.
Finally,
general
conclusion
perspective
focusing
on
current
development
directions
proposed
along
an
outlook.
order
develop
novel
high-performance
liquid
electrolytes,
we
need
in-depth
understanding
research
fundamentals,
paving
way
designing
next-generation
products.
Angewandte Chemie International Edition,
Journal Year:
2021,
Volume and Issue:
60(26), P. 14636 - 14643
Published: May 19, 2021
Abstract
Polymerization
at
the
liquid–liquid
interface
has
attracted
much
attention
for
synthesizing
ultrathin
polymer
films
molecular
sieving.
However,
it
remains
a
major
challenge
to
conduct
this
process
outside
alkane–water
since
not
only
suffers
water‐caused
side
reactions
but
also
is
limited
water‐soluble
monomers.
Here,
we
report
interfacial
polymerization
alkane/ionic
liquid
(IP@AILI)
where
ionic
acts
as
universal
solvent
diversified
amines
synthesize
task‐specific
polyamide
nanofilms.
We
propose
that
IP@AILI
occurs
when
acyl
chloride
diffuses
from
alkane
into
instead
of
being
triggered
by
diffusion
in
conventional
system,
which
demonstrated
thermodynamic
partitioning
and
kinetic
monitoring.
The
prepared
nanofilms
with
precisely
adjustable
pore
sizes
display
unprecedented
permeability
selectivity
various
separation
processes.