Advanced Materials,
Journal Year:
2023,
Volume and Issue:
35(40)
Published: June 26, 2023
Artificial
photosynthetic
diluted
CO2
reduction
directly
driven
by
natural
sunlight
is
a
challenging,
but
promising
way
to
realize
carbon-resources
recycling
utilization.
Herein,
three-in-one
photocatalytic
system
of
enrichment,
and
H2
O
oxidation
sites
designed
for
reduction.
A
Zn-Salen-based
covalent
organic
framework
(Zn-S-COF)
with
reductive
synthesized;
then,
ionic
liquids
(ILs)
are
loaded
into
the
pores.
As
result,
[Emim]BF4
@Zn-S-COF
shows
visible-light-driven
-to-CO
conversion
rate
105.88
µmol
g-1
h-1
under
(15%)
atmosphere,
even
superior
than
most
photocatalysts
in
high
concentrations
.
Moreover,
also
reaches
126.51
5
h.
Further
experiments
theoretical
calculations
reveal
that
triazine
ring
Zn-S-COF
promotes
activity
sites,
ILs
provide
an
enriched
realizing
efficient
ACS Energy Letters,
Journal Year:
2021,
Volume and Issue:
7(1), P. 247 - 260
Published: Dec. 15, 2021
Metal-ion
batteries
(MIBs)
are
promising
for
large-scale
energy
storage
because
they
can
alleviate
the
inherent
intermittency
of
renewable
energy.
As
an
indispensable
part
MIBs,
electrolytes
influence
electrochemical
performance.
Recently,
new
concept
eutectic
has
aroused
extensive
research
attention
in
field
MIBs
due
to
their
simple
synthesis
and
eco-friendly
features.
Nevertheless,
development
is
still
its
infancy
deserves
further
attention.
This
review
focuses
on
systematic
understanding
relationship
between
corresponding
performances
MIBs.
First,
fundamentals
described.
Then,
recent
progress
use
introduced,
including
correlations
structure
properties,
chemistry
at
electrode
interface,
ion/charge
transport
mechanism.
Finally,
challenges
prospects
related
discussed.
Focus
Review
will
provide
better
directions
devise
advanced
high-performance
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(37)
Published: July 5, 2022
Ionic
liquids
(ILs)
and
deep
eutectic
solvents
(DESs)
debuted
with
a
promise
of
superior
sustainability
footprint
due
to
their
low
vapor
pressure.
However,
toxicity
high
cost
compromise
this
footprint,
impeding
real-world
applications.
Fortunately,
property
tunability
through
rational
selection
precursors,
including
bioderived
ones,
provides
strategy
ameliorate
toxicity,
lower
cost,
endow
new
functions.
This
Review
discusses
whether
ILs
DESs
are
sustainable
how
they
contribute
chemical
processes.
Cellulose,
Journal Year:
2022,
Volume and Issue:
29(6), P. 3079 - 3129
Published: March 7, 2022
Abstract
Cellulose,
a
natural,
renewable,
and
environment
friendly
biopolymer,
has
been
considered
as
sustainable
feedstock
in
the
near
future.
However,
only
0.3%
of
cellulose
is
today
processed
since
it
not
soluble
conventional
solvents
due
to
strong
hydrogen
bonding
network
highly
ordered
structure.
Hence,
search
effective
eco-friendly
for
dissolution
key
pillar
decades.
In
recent
years,
ionic
liquids
(ILs)
have
proposed
green
applied
production
cellulose-based
fibers.
This
review
aims
focus
attention
toward
fiber
spinning
methods
based
on
ILs,
well
progress
using
ILs.
Moreover,
development
cellulosic
fibers
blended
with
other
biopolymers,
composites
are
presented.
Finally,
different
applications
summarized
discussed.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
35(40)
Published: June 26, 2023
Artificial
photosynthetic
diluted
CO2
reduction
directly
driven
by
natural
sunlight
is
a
challenging,
but
promising
way
to
realize
carbon-resources
recycling
utilization.
Herein,
three-in-one
photocatalytic
system
of
enrichment,
and
H2
O
oxidation
sites
designed
for
reduction.
A
Zn-Salen-based
covalent
organic
framework
(Zn-S-COF)
with
reductive
synthesized;
then,
ionic
liquids
(ILs)
are
loaded
into
the
pores.
As
result,
[Emim]BF4
@Zn-S-COF
shows
visible-light-driven
-to-CO
conversion
rate
105.88
µmol
g-1
h-1
under
(15%)
atmosphere,
even
superior
than
most
photocatalysts
in
high
concentrations
.
Moreover,
also
reaches
126.51
5
h.
Further
experiments
theoretical
calculations
reveal
that
triazine
ring
Zn-S-COF
promotes
activity
sites,
ILs
provide
an
enriched
realizing
efficient
