Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(14), P. 4041 - 4053
Published: Jan. 1, 2024
This
paper
primarily
focuses
on
the
editing
of
nitrogen
atoms,
encompassing
insertion
N,
substitution
C
with
and
utilization
15
N
in
place
14
for
construction
N-heterocycles.
Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(4), P. 1323 - 1463
Published: Feb. 14, 2024
This
review
surveys
the
synthesis
and
reactivity
of
low-oxidation
state
metalate
anions
d-block
elements,
with
an
emphasis
on
contributions
reported
between
2006
2022.
Although
field
has
a
long
rich
history,
chemistry
transition
been
greatly
enhanced
in
last
15
years
by
application
advanced
concepts
complex
ligand
design.
In
recent
years,
potential
highly
reactive
complexes
fields
small
molecule
activation
homogeneous
catalysis
become
increasingly
evident.
Consequently,
exciting
applications
have
developed,
including
catalytic
transformations.
article
intends
to
guide
reader
through
fascinating
world
low-valent
metalates.
The
first
part
describes
metalates
stabilized
assortment
frameworks,
carbonyls,
isocyanides,
alkenes
polyarenes,
phosphines
phosphorus
heterocycles,
amides,
redox-active
nitrogen-based
ligands.
Thereby,
will
be
familiarized
impact
different
types
physical
chemical
properties
addition,
ion-pairing
interactions
metal–metal
bonding
may
dramatic
influence
structures
reactivities.
ramifications
these
effects
are
examined
separate
section.
second
is
devoted
toward
inorganic
molecules
such
as
H2,
N2,
CO,
CO2,
P4
related
species.
It
shown
that
use
electron-rich
translates
into
impressive
hydrogenation
organic
reduction
CO2.
results
discussed
this
illustrate
being
tapped
for
challenging
processes
relevance
energy
conversion.
Therefore,
it
hoped
serve
useful
resource
inspire
further
developments
dynamic
research
field.
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(12), P. 7979 - 7984
Published: March 15, 2024
The
synthesis
of
pyridines
from
dinitrogen
in
homogeneous
solution
is
known
to
be
challenging
considering
that
an
N2
cleavage
step
needs
combined
with
two
N–C
coupling
steps.
Herein,
a
tungsten
complex
bearing
tailor-made
2,2′-(tBu2As)2-substituted
tolane
ligand
scaffold
was
shown
split
afford
the
corresponding
nitride,
which
not
case
for
(iPr2As)2-substituted
derivative.
former
nitride
then
reacted
2,4,6-trimethylpyrylium
triflate,
led
formation
oxo
complex,
along
collidine.
Over
course
this
reaction,
O
atom
pyrylium
starting
material
replaced
N
via
hitherto
unprecedented
skeletal
editing
process.
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(14), P. 4041 - 4053
Published: Jan. 1, 2024
This
paper
primarily
focuses
on
the
editing
of
nitrogen
atoms,
encompassing
insertion
N,
substitution
C
with
and
utilization
15
N
in
place
14
for
construction
N-heterocycles.