Sandwich structured Zn–W–Bi–O catalysts with low activation energy for highly effective oxidative desulfurization of oil DOI

Guangqiang Lin,

Chunfeng Mao, Meng-Hua Li

et al.

Reaction Kinetics Mechanisms and Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 16, 2024

Language: Английский

Poly(ionic liquid)s: an emerging platform for green chemistry DOI
Maiyong Zhu, Yang Yu

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(9), P. 5022 - 5102

Published: Jan. 1, 2024

This tutorial review provides a comprehensive and authoritative summary on the exciting research activities in fields of poly(ionic liquid)s (PILs), covering their synthesis applications number areas.

Language: Английский

Citations

35

Construction of imidazole-based ionic liquid modified MoO3-x for enhancing photocatalytic oxidation desulfurization in diesel DOI Creative Commons
Suhang Xun,

Chenchao Hu,

Bohan Yang

et al.

Green Energy & Environment, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Language: Английский

Citations

1

Ionic Liquids as Green and Efficient Desulfurization Media Aiming at Clean Fuel DOI Open Access
Peng Wang, Rui Wang, V.E. Matulis

et al.

International Journal of Environmental Research and Public Health, Journal Year: 2024, Volume and Issue: 21(7), P. 914 - 914

Published: July 12, 2024

With increasingly stringent emission limits on sulfur and sulfur-containing substances, the reduction removal of compounds from fuels has become an urgent task. Emissions pose a significant threat to environment human health. Ionic liquids (ILs) have attracted much attention in recent years as green solvents functional materials, their unique properties make them useful alternatives conventional desulfurization organic solvents. This paper reviews advantages disadvantages traditional technologies such hydrodesulfurization, oxidative desulfurization, biological adsorptive extractive etc. It focuses synthesis ionic applications catalytic it analyzes problems that need be solved urgently looking forward development sulfuric kind new emerging solvent field desulfurization.

Language: Английский

Citations

7

Unraveling the Mechanism of Extractive Desulfurization to Rationally Design Functional Ionic Liquids and Deep Eutectic Solvents: A Comprehensive Review DOI
Xinmiao Zhang, Jinrui Zhang,

Jie Yin

et al.

Energy & Fuels, Journal Year: 2025, Volume and Issue: 39(9), P. 4095 - 4118

Published: Feb. 24, 2025

Fuel desulfurization is of utmost importance to mitigate multiple environmental issues. Ionic liquids with unique adjustable properties have emerged as highly promising solvents for fuel extractants. Nevertheless, it remains challenging rationally design ionic in view the extraction mechanism. This review comprehensively discusses recent progress research on extractive desulfurization. The commonly adopted methods explore mechanism are summarized, including characterization and computational methods. In terms different functional groups, classified into six categories, imidazolium-, metal-, amino or phosphonium-, polyether glycol-, pyridinium-based, protic liquids. According mechanisms discussed detail, emphasis placed role dominant interactions sulfur-containing compounds, π···π, S–M complexation, C–H···π, hydrogen bonding. aims provide a theoretical foundation designing functionalized by summarizing More importantly, will guidance utilizing targeted

Language: Английский

Citations

0

In-situ construction of spherical N-doped carbon loaded with catalytic tungsten semicarbide nanoparticles for highly efficient sulfur removal from fuel oils DOI
Li Xu, Fei Wang, Li Yu

et al.

Advanced Powder Technology, Journal Year: 2025, Volume and Issue: 36(5), P. 104838 - 104838

Published: March 16, 2025

Language: Английский

Citations

0

Zinc Tungstate Supported on Graphitic Carbon Nitride for Efficient Oxidative Desulfurization of Oil DOI

Ran Wu,

Chunfeng Mao, Yifei Zhou

et al.

Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(5)

Published: April 10, 2025

ABSTRACT Binary metal oxides hold immense potential in catalysis; however, their efficient utilization remains a significant challenge. Zinc tungstate (ZnWO 4 ) was loaded onto graphitic carbon nitride (g‐C 3 N via highly and energy‐saving room‐temperature stirring method to prepare ZnWO /g‐C (ZnWO/CN) composite with sandwich structure for oxidative desulfurization. The appearance, structure, stability of ZnWO/CN were characterized by X‐ray diffraction (XRD), Fourier transform infrared (FT‐IR) spectroscopy, photoelectron spectroscopy (XPS), some other characterization tests. Results demonstrate the successful incorporation nanoparticles within layered porous g‐C , achieving dispersed state. In addition, exhibits significantly higher specific surface area enhanced compared pure effectively mitigates propensity towards agglomeration. catalytic performance evaluation indicates that (30 wt%) achieves exceptional desulfurization efficiency at lower preparation cost. A near‐complete sulfur removal rate 99.89% achieved 180 min under optimized conditions ( m (catalyst) 20.00 mg, V (ILs)/ (Oil) 1/20, (H 2 O 0.2 mL, 80°C). Furthermore, catalyst retained high even after eight consecutive cycles. Notably, adsorption affinity reactants enabled reduction ionic liquid dosages. By combining testing, quenching experiment, EPR test, reaction mechanism oxidation ultimately obtained. this provides research ideas new supported catalysts.

Language: Английский

Citations

0

Fast electron migration for efficient sodium desulfurization by producing activated sodium metal microspheres with large reaction interfaces DOI

Rongxin Zhu,

Dongdong Yin,

Xuemei Liu

et al.

Fuel, Journal Year: 2024, Volume and Issue: 381, P. 133659 - 133659

Published: Nov. 13, 2024

Language: Английский

Citations

0

Sandwich structured Zn–W–Bi–O catalysts with low activation energy for highly effective oxidative desulfurization of oil DOI

Guangqiang Lin,

Chunfeng Mao, Meng-Hua Li

et al.

Reaction Kinetics Mechanisms and Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 16, 2024

Language: Английский

Citations

0