Water Framework Directive micropollutant monitoring mirrors catchment land use: Importance of agricultural and urban sources revealed DOI Creative Commons
Nele Markert, Christian Schürings, Christian K. Feld

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 917, P. 170583 - 170583

Published: Feb. 1, 2024

River monitoring programs worldwide consistently unveil micropollutant concentrations (pesticide, pharmaceuticals, and industrial chemicals) exceeding regulatory quality targets with deteriorating effects on aquatic communities. However, both the composition individual of micropollutants are likely to vary catchment land use, in particular regarding urban agricultural area as primary sources micropollutants. In this study, we used a dataset 109 governmental sites monitored across Federal State North Rhine-Westphalia, Germany, investigate relationship between high-resolution use (distinguishing urban, forested grassland well 22 different crop types) 39 using Linear Mixed Models (LMMs). Ecotoxicological risks were indicated for mixtures pharmaceutical chemicals 100 % pesticides 55 sites. The proportion was positively related most pharmaceuticals (R2 up 0.54), whereas proportions areas generally showed negative relations. Cropland overall weak positive relationships 0.29). Individual types, particularly vegetables permanent crops, higher relations 0.46). findings suggest that type-specific pesticide applications mirrored detected concentrations. This highlights need spatial magnitude dynamics exposure relevant pollution sources, which would remain undetected highly aggregated classifications. Moreover, imply tailored management measures reduce from their ecological effects. Urban point could be managed by advanced wastewater treatment. reduction diffuse uses requires additional measures, prevent entering environment targets.

Language: Английский

Bioavailability (BA)-based risk assessment of soil heavy metals in provinces of China through the predictive BA-models DOI

Jiawen Zhang,

Xiaonan Wang, Jihong Li

et al.

Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 465, P. 133327 - 133327

Published: Dec. 20, 2023

Language: Английский

Citations

14
Encapsulation of Fennel and Basil Essential Oils in β-Cyclodextrin for Novel Biopesticide Formulation DOI Creative Commons
Nina Devrnja, Boban Anđelković, Jovana Ljujić

et al.

Biomolecules, Journal Year: 2024, Volume and Issue: 14(3), P. 353 - 353

Published: March 14, 2024

β-cyclodextrin (β-CD) is a good host for the encapsulation of fennel and basil essential oils (FEO BEO, respectively) formation inclusion complexes (ICs) using co-precipitation method. According to results GC/MS analysis conducted in this study, monoterpenes monoterpenoids were dominant chemical groups total FEO, while these two occurred along with sesquiterpenes sesquiterpenoids. The presence compounds from both EOs was validated FT-IR spectra ICs, which indicated successful complexation. Analyses SPME/GC-MS showed continuous emission volatiles over 24 h ICs. Under SEM, particles ICs appeared have rectangular or rhomboid morphology few aggregates. insecticidal properties β-CD tested on Colorado potato beetle (CPB) as model pest. complex FEO altered developmental dynamic body mass CPB. initial increase proteolytic activity CPB larvae fed plants sprayed not maintained long, efficacy treated remained line that control larvae. Future investigations will focus manipulating volume used treatment duration optimal potential application.

Language: Английский

Citations

5
An actionable definition and criteria for “sustainable chemistry” based on literature review and a global multisectoral stakeholder working group DOI Creative Commons

Amy Cannon,

Sally Edwards, Molly Jacobs

et al.

RSC Sustainability, Journal Year: 2023, Volume and Issue: 1(8), P. 2092 - 2106

Published: Jan. 1, 2023

Sustainable chemistry is the development and application of chemicals, chemical processes, products that benefit current future generations without harmful impacts to humans or ecosystems.

Language: Английский

Citations

12
Cutting-edge computational chemical exposure research at the U.S. Environmental Protection Agency DOI Creative Commons
Timothy J. Buckley, Peter Egeghy, Kristin Isaacs

et al.

Environment International, Journal Year: 2023, Volume and Issue: 178, P. 108097 - 108097

Published: July 13, 2023

Exposure science is evolving from its traditional "after the fact" and "one chemical at a time" approach to forecasting exposures rapidly enough keep pace with constantly expanding landscape of chemicals exposures. In this article, we provide an overview approaches, accomplishments, plans for advancing computational exposure within U.S. Environmental Protection Agency's Office Research Development (EPA/ORD). First, characterize universe in commerce environment, carefully curated, web-accessible resource has been created. This DSSTox database unambiguously identifies more than 1.2 million unique substances reflecting potential environmental human includes computationally accessible links each compound's corresponding data resources. Next, EPA developing, applying, evaluating predictive models. These models increasingly rely on data, tools like quantitative structure activity relationship (QSAR) models, machine learning/artificial intelligence timely efficient prediction (and associated uncertainty) thousands time. Integral modeling effort, developing resources across continuum that application high-resolution mass spectrometry (HRMS) non-targeted analysis (NTA) methods providing measurement capability scale number commerce. research efforts are integrated well-tailored support population assessment prioritize as critical input risk management. addition, forecasts will allow wide variety stakeholders explore sustainable initiatives green chemistry achieve economic, social, prosperity protection future generations.

Language: Английский

Citations

11
Water Framework Directive micropollutant monitoring mirrors catchment land use: Importance of agricultural and urban sources revealed DOI Creative Commons
Nele Markert, Christian Schürings, Christian K. Feld

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 917, P. 170583 - 170583

Published: Feb. 1, 2024

River monitoring programs worldwide consistently unveil micropollutant concentrations (pesticide, pharmaceuticals, and industrial chemicals) exceeding regulatory quality targets with deteriorating effects on aquatic communities. However, both the composition individual of micropollutants are likely to vary catchment land use, in particular regarding urban agricultural area as primary sources micropollutants. In this study, we used a dataset 109 governmental sites monitored across Federal State North Rhine-Westphalia, Germany, investigate relationship between high-resolution use (distinguishing urban, forested grassland well 22 different crop types) 39 using Linear Mixed Models (LMMs). Ecotoxicological risks were indicated for mixtures pharmaceutical chemicals 100 % pesticides 55 sites. The proportion was positively related most pharmaceuticals (R2 up 0.54), whereas proportions areas generally showed negative relations. Cropland overall weak positive relationships 0.29). Individual types, particularly vegetables permanent crops, higher relations 0.46). findings suggest that type-specific pesticide applications mirrored detected concentrations. This highlights need spatial magnitude dynamics exposure relevant pollution sources, which would remain undetected highly aggregated classifications. Moreover, imply tailored management measures reduce from their ecological effects. Urban point could be managed by advanced wastewater treatment. reduction diffuse uses requires additional measures, prevent entering environment targets.

Language: Английский

Citations

4