Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(3), P. 112884 - 112884
Published: April 24, 2024
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(3), P. 112884 - 112884
Published: April 24, 2024
Language: Английский
Water Research, Journal Year: 2023, Volume and Issue: 243, P. 120311 - 120311
Published: July 4, 2023
Language: Английский
Citations
75Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 342, P. 127023 - 127023
Published: March 7, 2024
Language: Английский
Citations
17Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 458, P. 132009 - 132009
Published: July 6, 2023
Language: Английский
Citations
25Water Research, Journal Year: 2023, Volume and Issue: 244, P. 120506 - 120506
Published: Aug. 19, 2023
Language: Английский
Citations
23Environmental Science & Technology, Journal Year: 2023, Volume and Issue: 57(44), P. 17144 - 17153
Published: Oct. 25, 2023
Recent research has primarily focused on the utilization of reductants as activators for Fe(VI) to generate high-valent iron species (Fe(IV)/Fe(V)) degradation emerging organic contaminants (EOCs). However, a significant drawback this approach arises from reaction between and ferrates, leading decrease in oxidation capacity. This study introduces novel discovery that highlights potential iron(III)-(1,10-phenanthroline) (Fe(III)-Phen) complex an activator, effectively enhancing EOCs by augmenting overall capacity Fe(VI). The Fe(VI)/Fe(III)-Phen system is facilitated through two mechanisms: direct electron transfer (DET) process shuttle action. DET involves formation Phen-Fe(III)–Fe(VI)* complex, which exhibits stronger ability than alone can accept electrons directly EOCs. On other hand, utilizes Fe(III)-Phen redox mediator Fe(IV)/Fe(III) or Fe(IV)/Fe(II)/Fe(III) cycle. Moreover, improve efficiency Fe(V) preventing its self-decay. study's findings may present viable option utilizing effective catalyst enhance Fe(V).
Language: Английский
Citations
20Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 475, P. 146109 - 146109
Published: Sept. 18, 2023
Language: Английский
Citations
13Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 343, P. 127121 - 127121
Published: March 15, 2024
Language: Английский
Citations
5Environmental Science & Technology, Journal Year: 2023, Volume and Issue: 57(36), P. 13625 - 13634
Published: Aug. 31, 2023
In this work, we demonstrate for the first time abatement of sulfamethoxazole (SMX) induced by stabilized ortho-semiquinone radicals (o-SQ•–) in MnO2-mediated system presence humic acid. To evaluate performance different MnO2/mediator systems, 16 mediators are examined their effects on MnO2 reactions with SMX. The key role bidentate Mn(II)-o-SQ• complex and surface stabilizing SQ•– is revealed. illustrate formation complex, electron spin resonance, cyclic voltammetry, mass spectra were used. o-SQ• surface, EDTA was used to quench Mn(II)-o-SQ•. high stability o-SQ•– attributed higher potential (0.9643 V) than (0.8598 at pH 7.0. SMX removal rate constant 7.0 ranges from 0.0098 0.2252 min–1. favorable model ln (kobs, 7.0) = 6.002EHOMO(o-Qred) + 33.744(ELUMO(o-Q) – EHOMO(o-Qred)) 32.800, whose parameters represent generation reactivity o-SQ•, respectively. Moreover, aniline cystine competitive substrates coupling o-SQ•–. Due abundance constituents aquatic environments, finding sheds light low-oxidant-demand, low-carbon, highly selective sulfonamide antibiotics.
Language: Английский
Citations
12Water Research, Journal Year: 2023, Volume and Issue: 247, P. 120840 - 120840
Published: Nov. 6, 2023
Language: Английский
Citations
12Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 349, P. 127679 - 127679
Published: May 4, 2024
Language: Английский
Citations
4