Bioresource Technology, Journal Year: 2024, Volume and Issue: 415, P. 131699 - 131699
Published: Oct. 24, 2024
Language: Английский
Bioresource Technology, Journal Year: 2024, Volume and Issue: 415, P. 131699 - 131699
Published: Oct. 24, 2024
Language: Английский
Environmental Science & Technology, Journal Year: 2025, Volume and Issue: unknown
Published: May 15, 2025
Molecular oxygen (O2) activation is pivotal in advancing green chemistry and catalysis, addressing processes such as energy conversion environmental remediation. However, the inherent inertness of O2 necessitates highly efficient catalysts. In this study, an electron-rich CuOx@Al2O3 catalyst with high metal loading dispersion was synthesized via ion-exchange inverse-loading method. The novel significantly enhanced due to accelerated Cu0 → Cu+ Cu2+ redox cycle, achieving 85% chlorobenzene removal Fenton-like reaction. This substantially higher than observed conventional CuOx/Al2O3 (45%). Experiments density functional theory (DFT) calculations revealed that Cu-Cu sites over greatly facilitated charge transfer, weakened O-O bonds, promoted synergistic H2O2 produce •OH O2•-, thereby enhancing oxidants utilization efficiency. study provides a sustainable pathway for pollutant degradation by offers valuable insights designing advanced Cu-based catalysts oxidation
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163872 - 163872
Published: May 1, 2025
Language: Английский
Citations
0Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 75, P. 107898 - 107898
Published: May 19, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 355, P. 129649 - 129649
Published: Sept. 11, 2024
Language: Английский
Citations
3Bioresource Technology, Journal Year: 2024, Volume and Issue: 415, P. 131699 - 131699
Published: Oct. 24, 2024
Language: Английский
Citations
2