Industrial & Engineering Chemistry Research,
Journal Year:
2023,
Volume and Issue:
62(43), P. 18091 - 18104
Published: Oct. 10, 2023
In
this
work,
a
novel
FeNi2S4/TiO2–x
nanocomposite
was
prepared
by
facile
hydrothermal
synthesis,
then
comprehensively
characterized
multitechnique
approach,
and
subsequently
employed
for
round-the-clock
(light
dark)
removal
of
rhodamine
B.
Superior
improvement
the
morphological
thermal
properties
due
to
use
sodium
dodecyl
sulfate
investigated.
An
l-ascorbic
acid-assisted
photo-Fenton
catalyst
can
be
effectively
complete
B
at
30
min
using
10
W
white-light-emitting
diode
(LED)
source
under
wide
range
operating
conditions
compared
other
reported
catalysts.
The
obtained
results
show
significant
synergism
between
components,
which
makes
total
RhB
much
better
than
when
each
used
alone.
This
study
presents
approach
designing
sustainable
multifunctional
with
reusability,
high
catalytic
activity,
environmental
friendliness.
Due
photocatalytic
in
presence
hydrogen
peroxide
ascorbic
acid
visible
light,
there
is
potential
generate
more
electron/hole
carriers
hydroxyl
radicals
(•OH).
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(10), P. 4770 - 4782
Published: Feb. 27, 2024
Photocatalytic
for
hydrogen
peroxide
(H2O2)
production
is
thought
as
a
promising
technology
owing
to
its
clean
and
green
properties
with
the
cheap
easily
available
raw
materials
of
H2O
O2.
Herein,
Pt/g-C3N4
Schottky
junction
photocatalysts
ultralow
Pt
contents
(0.025–0.1
wt
%)
were
successfully
fabricated
by
an
impregnation-reduction
method.
It
can
efficiently
reduce
O2
generate
H2O2
without
sacrificial
agent
under
visible-light
irradiation.
The
yield
produced
over
Pt0.05/g-C3N4
optimal
0.05
%
reached
31.82
μM,
which
was
2.46
times
that
g-C3N4
higher
than
most
those
in
literature.
also
showed
good
stability
three
repeated
tests.
deposition
highly
dispersed
metal
nanoparticles
low
limited
content
expose
enough
active
atoms,
significantly
enhance
separation
efficiency
photogenerated
carriers,
negative
effect
on
decomposition,
resulting
improved
outstanding
production.
·O2–
radicals
found
be
main
species.
mechanism
photocatalytic
confirmed
two-step
single
electron
route
(O2
+
e–→
→
H2O2).
Langmuir,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 12, 2025
The
Fenton-like
reaction
has
been
widely
used
for
environmental
modification.
However,
improvement
of
the
catalytic
efficiency
is
still
a
challenge.
In
this
study,
series
core-shell-shaped
catalysts
(FeNC-x,
x
presents
calcination
temperature)
was
fabricated
through
pyrolysis
Fe-based
metal-organic
frameworks
(Fe-MOF).
Fe
species
were
encapsulated
by
N-doped
carbon
materials
and
changed
from
Fe3O4
to
Fe3C,
α-Fe,
Fe-N4
with
temperature
increasing
500
800
°C.
Simultaneously,
electron
density
atom
obviously
increased.
FeNC-650
exhibited
high
efficiency,
as
more
than
85.6%
TC
(40
mg/L)
instantaneous
removal
H2O2-based
reaction.
turnover
number
about
70
64
times
higher
that
Fe-MOF
FeNC-500.
synergistic
interaction
among
induced
distribution
around
excellent
performances.
Moreover,
interference
resistance
toward
different
anions
humic
acid.
toxicity
intermediate
products
decreased
during
degradation.
This
research
may
give
strategy
synthesis
in
wastewater
purification.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
34(46)
Published: Aug. 20, 2024
Abstract
Mineral
supplementation
is
crucial
for
human
nutrition
to
facilitate
appropriate
growth,
disease
prevention,
and
improved
reproductive
health.
The
conventional
forms
of
mineral
involve
an
ionic
form
elements
mixed
with
biomolecules;
however,
suffer
from
unfavorable
reactions
under
acidic
environment
stomach,
ROS
generation,
poor
absorption
in
the
small
intestine.
To
address
this,
nanominerals
(NMs)
six
essential
are
synthesized
packed
pH‐responsive
microcapsule.
Each
NMs
coated
biomolecules
that
known
rapidly
absorb
through
intestinal
epithelium.
Microcapsules
found
intact
at
pH
(pH:
2.0–6.5);
selectively
release
≥7.0.
vitro
study
demonstrates
mixture
microcapsules
biocompatible
exhibits
excellent
scavenging
ability
physiological
pH.
Oral
administration
NMs‐loaded
rats
shows
enhanced
levels
minerals,
vitamin
B12,
hemoglobin,
total
antioxidant
activity
blood.
liver,
kidneys,
spleen
show
expression
Cu/Zn‐SOD
Mn‐SOD
enzymes
due
high
bioavailability
ZnO,
Cu
2
O,
MnO
Thus,
hold
promise
effectively
stealth
encapsulated
nutrient
materials
stomach
precisely
deliver
them
Physical Chemistry Chemical Physics,
Journal Year:
2024,
Volume and Issue:
26(15), P. 12070 - 12083
Published: Jan. 1, 2024
Development
and
fabrication
of
a
novel
gas
sensor
with
superb
performance
are
crucial
for
enabling
real-time
monitoring
ethylene
(C
2
H
4
)
formaldehyde
(H
CO)
emissions
from
industrial
manufacture.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(29), P. 13602 - 13612
Published: July 8, 2024
Metal
nanozymes
have
offered
attractive
opportunities
for
biocatalysis
and
biomedicine.
However,
fabricating
simultaneously
possessing
highly
catalytic
selectivity
activity
remains
a
great
challenge
due
to
the
lack
of
three-dimensional
(3D)
architecture
pocket
in
natural
enzymes.
Here,
we
integrate
rhodium
nanocluster
(RhNC),
reduced
graphene
oxide
(rGO),
protamine
(PRTM,
typical
arginine-rich
peptide)
into
composite
facilely
based
on
single
peptide.
Remarkably,
PRTM-RhNC@rGO
displays
outstanding
selectivity,
activity,
stability
degradation
uric
acid.
The
reaction
rate
constant
acid
oxidation
catalyzed
by
is
about
1.88
×
10–3
s–1
(4
μg/mL),
which
37.6
times
higher
than
that
reported
RhNP
(k
=
5
10–5
s–1,
20
μg/mL).
Enzyme
kinetic
studies
reveal
exhibits
similar
affinity
as
uricase.
Furthermore,
uricase-like
presence
sulfur
substances
halide
ions,
displaying
incredibly
well
antipoisoning
abilities.
analysis
structure–function
relationship
indicates
features
substrate
binding
site
near
confined
space
contributed
2D
rGO
PRTM,
resulting
high-performance
nanozyme.
Based
interaction
PRTM
acid,
can
retard
urate
crystallization
significantly.
present
work
provides
new
insights
design
metal
with
suitable
sites
mimicking
pocket-like
structures
enzymes
simple
peptides,
conducing
broadening
practical
application
biomedical
fields.
Inorganic Chemistry,
Journal Year:
2023,
Volume and Issue:
63(1), P. 824 - 832
Published: Dec. 19, 2023
The
catalytic
oxidation
of
ethylbenzene
(EB)
into
acetophenone
(AP)
is
a
vibrant
area,
with
growing
number
researchers
paying
attention
to
this
thematic
investigation.
Herein,
we
demonstrate
that
spinel-type
(Co,Mn)(Co,Mn)2O4
can
function
as
an
efficient
catalyst
for
the
solvent-free
EB
molecular
oxygen.
incorporation
Mn
Co3O4
network
break
local
structural
symmetry
Co–O–Co
linkages
due
bond
competition,
inducing
formation
asymmetrical
Co–O–Mn
configuration
electron
exchange
interaction.
sites
facilitate
perturbation
nonpolar
O2
and
thus
contribute
generation
abundant
•O2–
species
initiating
EB.
We
envision
study
not
only
provides
promising
but
also
affords
new
insight
design
advanced
spinel
oxides
selective
reactions.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(15), P. 6701 - 6713
Published: April 2, 2024
The
singlet
oxygen
(1O2)
oxidation
process
activated
by
metal-free
catalysts
has
recently
attracted
considerable
attention
for
organic
pollutant
degradation;
however,
the
1O2
formation
remains
controversial.
Simultaneously,
catalytic
activity
of
catalyst
limits
practical
application.
In
this
study,
carbon
nitride
(HCCN)
containing
an
intramolecular
homojunction,
a
kind
catalyst,
exhibits
excellent
compared
to
g-C3N4
(CN)
and
crystalline
(HCN)
tetracycline
hydrochloride
degradation
through
H2O2-based
Fenton-like
reaction.
rate
constant
HCCN
increased
about
16.1
8.9
times
than
that
CN
HCN,
respectively.
was
enhanced,
dominant
reactive
species
(ROS)
changed
from
hydroxyl
radicals
(•OH)
with
increase
in
pH
4.5
11.5.
A
novel
pathway
revealed.
This
result
is
different
normal
reference,
which
•OH
always
primary
ROS
study
may
provide
possible
strategy
investigation
on
nonradical
