Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178374 - 178374
Published: Dec. 1, 2024
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178374 - 178374
Published: Dec. 1, 2024
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125174 - 125174
Published: Feb. 1, 2025
Language: Английский
Citations
1Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 697, P. 134474 - 134474
Published: June 5, 2024
Language: Английский
Citations
6Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 684, P. 254 - 261
Published: Jan. 7, 2025
Language: Английский
Citations
0Journal of Cleaner Production, Journal Year: 2025, Volume and Issue: unknown, P. 145293 - 145293
Published: March 1, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 691, P. 137465 - 137465
Published: March 30, 2025
Language: Английский
Citations
0ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(11), P. 13147 - 13155
Published: May 31, 2024
To obtain a recyclable and environmentally friendly solid catalyst with excellent catalytic properties selectivity for 4-nitrophenol (4-NP) hydrogenation, herein, covalent organic frameworks (COFs) are used as the support. Tiny PdCo alloy particles confined in pores of COFs to acquire PdCo/COFs, an extremely narrow PtCo size distribution (6.28 ± 2.85 nm). The effect Pd+Co loading Pd/Co atomic ratio on behaviors PdCo/COFs 4-NP hydrogenation is explored. as-gained (Pd─1.72, Co─1.23 wt %) exhibits good (conversion─90.5%, 4-aminophenol (4-AP) > 99.0%, conversion─11.0%, TOF─turnover frequency─44.2 min–1) under quite moderate reaction conditions (40 °C, 3.0 MPa hydrogen pressure), have superior stability. Additionally, property better than that monometallic supported catalysts (Pd/COFs or Co/COFs) PdNi/COFs. It can be considered formation beneficial activation 4-NP. analyzed by XRD, XPS, ICP-OES, SEM-EDX, BET, TEM, HRTEM, STEM-EDX elemental analysis, aberration-corrected STEM (AC-STEM), confirming tiny uniformly loaded COFs. samples advantages outstanding stability thus their own desired industrial application potential.
Language: Английский
Citations
3Fuel, Journal Year: 2024, Volume and Issue: 374, P. 132447 - 132447
Published: July 15, 2024
Language: Английский
Citations
3European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(25)
Published: May 18, 2024
Abstract Hydrogenation of N‐heteroarenes to saturated N‐heterocycles is an important reaction in organic synthesis. Hydrogen a green reducing reagent and has been widely applied industrial production. The development appropriate catalyst realize hydrogenation at low pressure temperature desired. In this study, we developed cobalt‐based derived from ZIF‐67 that exhibits high activity for N‐heteroarene under 5–20 bar hydrogen, which relatively as compared reported catalytic systems. This nano‐cobalt shows broad substrate scope can be reused without obvious loss.
Language: Английский
Citations
2Published: Jan. 1, 2024
Hexavalent chromium (Cr(VI)) is mainly detected as a harmful anion in aquatic ecosystems. In this study, novel nanohybrid layered clay composite decorated with polyaniline (PANI) (PANI/LDH@MMt) was successfully synthesized by layer-by-layer assembly strategy and utilized for Cr(VI) removal. Layered double hydroxide (LDH) montmorillonite (MMt) (LDH@MMt) can facilitate elimination through reinforced reduction. Some key experimental parameters were evaluated detail their potential impact on The results illustrated that PANI/LDH@MMt displayed high removal efficiency (>99%) at most appropriate conditions maintained over 95% performance even ionic coexistence natural water environments. Kinetic models, isothermal thermodynamic analyses also employed to explore the behavior PANI/LDH@MMt. Finally, mechanism analysis suggested could be captured electrostatic interaction of -NH-+, -N=+, –OH2+, exchange LDH, reduced Cr(III) -NH-. Subsequently, chelate -N=, −NH−, −OH, complex OH-, immobilized MMt cation exchange. This study presents new insight into reasonable construction highly efficient adsorbents low cost
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178374 - 178374
Published: Dec. 1, 2024
Language: Английский
Citations
0