Synthesis of aliphatic nitriles from cyclobutanone oxime mediated by sulfuryl fluoride (SO2F2) DOI Creative Commons

Xian‐Lin Chen,

Hua‐Li Qin

Beilstein Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 19, P. 901 - 908

Published: June 22, 2023

A SO2F2-mediated ring-opening cross-coupling of cyclobutanone oxime derivatives with alkenes was developed for the construction a range δ-olefin-containing aliphatic nitriles (E)-configuration selectivity. This new method features wide substrate scope, mild conditions, and direct N-O activation.

Language: Английский

A guide to organic electroreduction using sacrificial anodes DOI
Yufeng Li, Li‐Rong Wen, Wei‐Si Guo

et al.

Chemical Society Reviews, Journal Year: 2023, Volume and Issue: 52(4), P. 1168 - 1188

Published: Jan. 1, 2023

This review focuses on recent advances in sacrificial anode-enabled organic electroreductions.

Language: Английский

Citations

62
Recent Advances in Electrochemical Carboxylation with CO2 DOI

Guo‐Quan Sun,

Li‐Li Liao,

Chuan‐Kun Ran

et al.

Accounts of Chemical Research, Journal Year: 2024, Volume and Issue: 57(18), P. 2728 - 2745

Published: Sept. 3, 2024

ConspectusCarbon dioxide (CO

Citations

33
Electroreductive Ring-Opening Carboxylation of 1,3-Oxazolidin-2-ones with CO2 for Accessing β-Amino Acids DOI
Tao Li, Xiaofei Liu,

Bai‐Hao Ren

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(2), P. 542 - 546

Published: Jan. 8, 2024

Electrocarboxylation of the C(sp3)–O bond in 1,3-oxazolidin-2-ones with CO2 to achieve β-amino acids is developed. The C–O substrates can be selectively cleaved via single electron transfer on surface a cathode or through CO2• – intermediate under additive-free conditions. A great diversity obtained moderate excellent yield and readily converted various biologically active compounds.

Language: Английский

Citations

4
Organo-electroreduction enables arylcarboxylation of styrenes DOI
Yanwei Wang, Qian Wang, Zile Zhu

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 27, 2024

Language: Английский

Citations

4
Electroreductive Carboxylation of Benzylphosphonium salts with CO2 Through the Cleavage of the C(sp3)-P Bond DOI

Fen Han,

Fenfen Xie,

Mengyun Yin

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(28), P. 5724 - 5728

Published: Jan. 1, 2024

Herein, a novel electroreductive carboxylation of benzylphosphine salts with CO 2 through cleavage the C(sp 3 )-P bond was reported under conditions without redox reagents and noble metal catalysts.

Language: Английский

Citations

2
Recent Advances in Electrochemical Carboxylation of Inert Chemical Bonds with Carbon Dioxide DOI
Xiaotong Gao,

Yuqing Zhong,

Nan Feng

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(10), P. 3043 - 3043

Published: Jan. 1, 2024

Language: Английский

Citations

2
Synthesis of Carboxylic Acid by Electrochemical Fixation of Carbon Dioxide: A Review of Electrochemical Carboxylation from Past to Latest DOI
Hisanori Senboku

Current Organic Chemistry, Journal Year: 2023, Volume and Issue: 28(2), P. 76 - 88

Published: Sept. 18, 2023

Abstract: Electrochemical reduction of organic compounds in the presence carbon dioxide results fixation into substrates with carbon-carbon bond forming reaction to yield corresponding carboxylic acids. The is called “electrochemical carboxylation” or “electrocarboxylation”. Various kinds acids have been synthesized using as a carboxyl group source by electrochemical carboxylation. In this mini-review, several representative from carboxylation are briefly summarized/introduced, comparing past and latest.

Language: Английский

Citations

6
Nickel-Catalyzed Electrochemical Cyclizative Carboxylation of Alkene-Tethered Carbamoyl Chlorides with Carbon Dioxide DOI
Linlin Wang, Xiaofei Liu, Wen‐Zhen Zhang

et al.

Synthesis, Journal Year: 2023, Volume and Issue: 55(18), P. 2951 - 2958

Published: May 16, 2023

Abstract Nickel-catalyzed electrochemical cyclizative carboxylation of alkene-tethered carbamoyl chlorides with atmospheric carbon dioxide in an undivided cell under simple constant current conditions is reported. This reaction conducted high efficiency mild conditions, providing a convenient and green access to valuable 2-oxoindolin-3-ylacetic acids 2-oxo-tetrahydroquinoline-4-carboxylic acids.

Language: Английский

Citations

4
Enhancing electrocarboxylation reactions efficiency by cathode material selection DOI Creative Commons
Didjay F. Bruggeman,

Charlotte Graefin von Quadt,

Cássia Sidney Santana

et al.

Current Research in Green and Sustainable Chemistry, Journal Year: 2023, Volume and Issue: 7, P. 100380 - 100380

Published: Jan. 1, 2023

Electrocarboxylation reactions hold significant promise as a sustainable and efficient method for carbon-carbon bond formation driven by electricity enabling the direct conversion of carbon dioxide (CO2) into valuable organic compounds. Despite potential advantages electrocarboxylation over traditional methods, there are still challenges to address their widespread implementation. In this contribution, our objective is shed light on role these in recycling converting CO2 chemicals. Specifically, we focus exploring correlations between performance CO2-based carboxylation choice working electrode material combination with functional groups present substrates.

Language: Английский

Citations

4
A comparative overview of the electrochemical valorization and incorporation of CO2 in industrially relevant compounds DOI Creative Commons
Jef R. Vanhoof,

Sander Spittaels,

Dirk De Vos

et al.

EES Catalysis, Journal Year: 2024, Volume and Issue: 2(3), P. 753 - 779

Published: Jan. 1, 2024

This review covers the recent work on electrochemical valorization of CO 2 towards key industrial compounds like carboxylic acids, urea and dimethyl carbonate by combining eCO RR intermediates with other active (in)organic reagents.

Language: Английский

Citations

1