Efficient single-component nickel catalysts with tetradentate aminopyridine ligands for cycloaddition reactions of CO2 and epoxides under mild conditions DOI Creative Commons
Congcong Zhang, Minghui Shi, Ning Yu

et al.

RSC Sustainability, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A series of single-component nickel catalysts with tetradentate aminopyridine ligands exhibited excellent capabilities and selectivity for the synthesis cyclic carbonates from epoxides CO 2 , even under 1 atm 0.5 mol% catalyst.

Language: Английский

Programmable Strategies for the Conversion of Aldehydes to Unsymmetrical (Deuterated) Diarylmethanes and Diarylketones DOI Creative Commons
Vipin R. Gavit, Nicole Hanania, Nadim Eghbarieh

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 28, 2025

Herein, we present a versatile method for synthesizing unsymmetrical diarylmethanes and diarylketones from aldehydes arenes. This involves: (1) regioselective Ar-H alkylation to form benzhydrylphosphonium salts via one-pot, four-component reaction with simple reagents (2) chemoselective reductions or oxidations of the benzylic C-P bond. Notably, D2O yield fully deuterated diarylmethanes. high-yielding, straightforward approach offers valuable building blocks enables novel transformations academic pharmaceutical research.

Language: Английский

Citations

0
Efficient single-component nickel catalysts with tetradentate aminopyridine ligands for cycloaddition reactions of CO2 and epoxides under mild conditions DOI Creative Commons
Congcong Zhang, Minghui Shi, Ning Yu

et al.

RSC Sustainability, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A series of single-component nickel catalysts with tetradentate aminopyridine ligands exhibited excellent capabilities and selectivity for the synthesis cyclic carbonates from epoxides CO 2 , even under 1 atm 0.5 mol% catalyst.

Language: Английский

Citations

0