Visible Light-Induced Radical Cascade Difluoromethylation/Cyclization of Unactivated Alkenes: Access to CF2H-Substituted Polycyclic Imidazoles
S.J. Lin,
No information about this author
Yuanyuan Deng,
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Hanxun Zhong
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et al.
ACS Omega,
Journal Year:
2024,
Volume and Issue:
9(26), P. 28129 - 28143
Published: June 19, 2024
An
efficient
and
mild
protocol
for
the
visible
light-induced
radical
cascade
difluoromethylation/cyclization
of
imidazoles
with
unactivated
alkenes
using
easily
accessible
bench-stable
difluoromethyltriphenylphosphonium
bromide
as
precursor
-CF
Language: Английский
Alkene Carboxy-Alkylation via CO2•–
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(51), P. 35035 - 35042
Published: Dec. 12, 2024
Herein,
we
introduce
a
new
platform
for
alkene
carboxy-alkylation.
This
reaction
is
designed
around
CO
Language: Английский
Electrochemical Access to Difluoromethyl Groups: An Overview of Scope, Mechanisms, and Challenges
ACS Catalysis,
Journal Year:
2025,
Volume and Issue:
unknown, P. 6826 - 6851
Published: April 14, 2025
Language: Английский
Electroreductive Carboxylation of Benzylphosphonium salts with CO2 Through the Cleavage of the C(sp3)-P Bond
Fen Han,
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Fenfen Xie,
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Mengyun Yin
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et al.
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
22(28), P. 5724 - 5728
Published: Jan. 1, 2024
Herein,
a
novel
electroreductive
carboxylation
of
benzylphosphine
salts
with
CO
2
through
cleavage
the
C(sp
3
)-P
bond
was
reported
under
conditions
without
redox
reagents
and
noble
metal
catalysts.
Language: Английский
Photo-Induced Difluoroalkylation/Cyclization of Alkyne Ketones: A Novel Strategy to Access Difluoroalkyl Thiofavones
Shengjie Song,
No information about this author
Can Luo,
No information about this author
Guan Wang
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et al.
Chemical Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
A
photo-induced
electron
donor-acceptor
(EDA)
complex
enabled
tandem
reaction
of
alkyne
ketones
Language: Английский
Photoredox-catalysed Radical Difluoromethylation/Cyclization of N-Acryloyl-2-arylbenzimidazole to Access CF2H-Substituted Benzimidazo[2,1-a]isoquinolin-6(5H)-ones
Jinwei Yuan,
No information about this author
Hongzhao Qu,
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Wenfeng Jia
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et al.
Organic & Biomolecular Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
A
convenient
visible-light-promoted
difluoromethylation/cyclization
reaction
to
access
various
difluoromethylated
benzo[4,5]imidazo[2,1-
a
]isoquinolin-6(5
H
)-ones
was
developed
using
[Ph
3
PCF
2
H]
+
Br
−
as
reagent.
Language: Английский