Photoredox-catalysed Radical Difluoromethylation/Cyclization of N-Acryloyl-2-arylbenzimidazole to Access CF2H-Substituted Benzimidazo[2,1-a]isoquinolin-6(5H)-ones DOI
Jinwei Yuan,

Hongzhao Qu,

Wenfeng Jia

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A convenient visible-light-promoted difluoromethylation/cyclization reaction to access various difluoromethylated benzo[4,5]imidazo[2,1- a ]isoquinolin-6(5 H )-ones was developed using [Ph 3 PCF 2 H] + Br − as reagent.

Language: Английский

Visible Light-Induced Radical Cascade Difluoromethylation/Cyclization of Unactivated Alkenes: Access to CF2H-Substituted Polycyclic Imidazoles DOI Creative Commons
S.J. Lin, Yuanyuan Deng,

Hanxun Zhong

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(26), P. 28129 - 28143

Published: June 19, 2024

An efficient and mild protocol for the visible light-induced radical cascade difluoromethylation/cyclization of imidazoles with unactivated alkenes using easily accessible bench-stable difluoromethyltriphenylphosphonium bromide as precursor -CF

Language: Английский

Citations

5
Alkene Carboxy-Alkylation via CO2•– DOI
Yun Dang, Jimin Han, Alyah F. Chmiel

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(51), P. 35035 - 35042

Published: Dec. 12, 2024

Herein, we introduce a new platform for alkene carboxy-alkylation. This reaction is designed around CO

Language: Английский

Citations

4
Electrochemical Access to Difluoromethyl Groups: An Overview of Scope, Mechanisms, and Challenges DOI
Seonyoung Kim, Hyunwoo Kim

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 6826 - 6851

Published: April 14, 2025

Language: Английский

Citations

0
Electroreductive Carboxylation of Benzylphosphonium salts with CO2 Through the Cleavage of the C(sp3)-P Bond DOI

Fen Han,

Fenfen Xie,

Mengyun Yin

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(28), P. 5724 - 5728

Published: Jan. 1, 2024

Herein, a novel electroreductive carboxylation of benzylphosphine salts with CO 2 through cleavage the C(sp 3 )-P bond was reported under conditions without redox reagents and noble metal catalysts.

Language: Английский

Citations

2
Photo-Induced Difluoroalkylation/Cyclization of Alkyne Ketones: A Novel Strategy to Access Difluoroalkyl Thiofavones DOI

Shengjie Song,

Can Luo,

Guan Wang

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A photo-induced electron donor-acceptor (EDA) complex enabled tandem reaction of alkyne ketones

Language: Английский

Citations

1
Photoredox-catalysed Radical Difluoromethylation/Cyclization of N-Acryloyl-2-arylbenzimidazole to Access CF2H-Substituted Benzimidazo[2,1-a]isoquinolin-6(5H)-ones DOI
Jinwei Yuan,

Hongzhao Qu,

Wenfeng Jia

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A convenient visible-light-promoted difluoromethylation/cyclization reaction to access various difluoromethylated benzo[4,5]imidazo[2,1- a ]isoquinolin-6(5 H )-ones was developed using [Ph 3 PCF 2 H] + Br − as reagent.

Language: Английский

Citations

1