Photocatalytic synthesis of dual acylmethylation derivates of indole[2,1-a]isoquinolinones via tandem cyclization/C3 acyl methylation

Molecular Catalysis, Journal Year: 2025, Volume and Issue: 580, P. 115058 - 115058

Published: April 15, 2025

Language: Английский

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Recent advances in the electrochemical synthesis of organophosphorus compounds

Beilstein Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: 21, P. 770 - 797

Published: April 16, 2025

In this review, we describe recent advances in electrochemical green methods for the synthesis of various organophosphorus compounds through formation phosphorus–carbon, phosphorus–nitrogen, phosphorus–oxygen, phosphorus–sulfur, and phosphorus–selenium bonds. The impact different electrodes is also discussed matter. Graphite, platinum, RVC, nickel have been used extensively compounds. made method a promising preparing structures. This review an introduction to encourage scientists use electrosynthesis as green, precise, low-cost prepare phosphorous

Language: Английский

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Photo-induced phosphorylation/cyclization of N-homoallyl and N-allyl aldehyde hydrazones to access phosphorylated tetrahydropyridazines and dihydropyrazoles

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(35), P. 4687 - 4690

Published: Jan. 1, 2024

A visible-light-induced carbophosphorylation/cyclization of N -homoallyl and -allyl aldehyde hydrazones with phosphine oxides was developed to obtain phosphorylated tetrahydropyridazines dihydropyrazoles.

Language: Английский

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Electrochemical Synthesis of Phosphorylated Indoles and Trp-Containing Oligopeptides

Organic Letters, Journal Year: 2024, Volume and Issue: 26(22), P. 4700 - 4704

Published: May 28, 2024

Cp

Language: Английский

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Cp₂Fe‐Mediated Electrochemical Synthesis of Functionalized Compounds: Recent Advances

European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(12)

Published: Feb. 29, 2024

Abstract Unlike traditional organic methods, electrosynthesis has emerged as an environmentally friendly and sustainable approach to generate a series of functionalized compounds. In this process, the traceless electron serves redox agent, eliminating need for stoichiometric oxidants or reductants. contrast direct electrolysis, redox‐mediated electrolysis ability overcome kinetic inhibitions achieve diverse selectivity under mild conditions. This garnered increasing attention from synthetic community, especially in past few years. review will focus on Cp 2 Fe‐mediated diversified compounds through C−N, C−C, C−P C−O bond formation over decade.

Language: Английский

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Syntheses of Phosphonylated Pyrido-Dihydrofurans by Regioselective 5-Exo-dig Addition to Carbon–Carbon Triple Bond Catalyzed by AgNO₃

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 17, 2024

The tandem nucleophilic addition-cyclization reaction of

Language: Английский

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Palladium-catalyzed cyclization of N-(2-iodophenyl)acrylamides and hydrophosphoryl compounds in the presence of (R,R)-DIOP and (S)-Monophos ligands

Russian Chemical Bulletin, Journal Year: 2024, Volume and Issue: 73(9), P. 2701 - 2707

Published: Sept. 1, 2024

Language: Английский

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Electrochemical Synthesis of Phosphorylated Azaspiro[4.5]di/trienones through Dearomative Spirocyclization

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(57), P. 7351 - 7354

Published: Jan. 1, 2024

Cp 2 Fe-mediated electrochemical synthesis of a diverse array phosphorylated azaspiro[4.5]di/trienones has been developed, which demonstrated broad substrate scope and good diastereoselectivity.

Language: Английский

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Copper Mediated sp³-C—N Bond Cleavage for Synthesizing (Diarylmethyl)diarylphosphine Oxides

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3713 - 3713

Published: Jan. 1, 2024

Language: Английский

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