Radical 1,3-Hydrosulfonylation of Vinyldiazo Compounds with Sulfinyl Sulfones DOI
Tian Jing, Yuan‐Li Ding,

Wanting Fu

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 4, 2025

Sulfinyl sulfones, as high-valence sulfurization reagents, are widely used to assemble sulfur sources on carbon skeletons, such one-, two-, and four-carbon synthons, access organosulfur compounds. However, their reaction with three-carbon synthons has remained a mystery until now. We report here radical 1,3-hydrosulfonylation of vinyldiazo compounds sulfinyl sulfones. This not only represents the first example sulfones but also opens up application in monofunctionalization.

Language: Английский

Radical 1,3-Hydrosulfonylation of Vinyldiazo Compounds with Sulfinyl Sulfones DOI
Tian Jing, Yuan‐Li Ding,

Wanting Fu

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 4, 2025

Sulfinyl sulfones, as high-valence sulfurization reagents, are widely used to assemble sulfur sources on carbon skeletons, such one-, two-, and four-carbon synthons, access organosulfur compounds. However, their reaction with three-carbon synthons has remained a mystery until now. We report here radical 1,3-hydrosulfonylation of vinyldiazo compounds sulfinyl sulfones. This not only represents the first example sulfones but also opens up application in monofunctionalization.

Language: Английский

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