New Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
A remarkable efficiency of 27.88% was achieved for hierarchical 2D/3D/2D perovskite solar cells using Dion–Jacobson and Ruddlesden–Popper 2D layers.
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159453 - 159453
Published: Jan. 1, 2025
Language: Английский
Citations
2
DeCarbon, Journal Year: 2025, Volume and Issue: unknown, P. 100098 - 100098
Published: Jan. 1, 2025
Language: Английский
Citations
2
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 9, 2025
Developing strategies to manage ion-migration-induced phase segregation in wide-bandgap (WBG) perovskites is crucial for achieving high-performance perovskite-silicon tandem solar cells (TSCs). However, maintaining continuous suppression of from the film crystallization process device operation remains a significant challenge. The present study demonstrates an efficient strategy activating halogen circulation WBG perovskite by using agents (HCA) N-halosuccinimide molecules as sustainable stabilizers, order achieve dynamic equilibrium within precursor solution and film, which blocks migration path Br-/I- ions both aging perovskites. Attempts on situ monitoring halide visually verified enhanced stability activated films devices. Consequently, work achieves champion efficiency up 23.25% with low Voc loss 0.39 V 1.67-eV-bandgap device, HCA-based devices can maintain 88% 93% their initial efficiencies over 1000 h under illumination 2500 at 85 °C N2 atmosphere, respectively. As proof concept, perovskite/silicon monolithic TSCs are fabricated demonstrate high 1.99 power conversion 33.2%.
Language: Английский
Citations
2
Nano Energy, Journal Year: 2024, Volume and Issue: 127, P. 109708 - 109708
Published: May 8, 2024
Language: Английский
Citations
12
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown
Published: June 4, 2024
Abstract Due to the higher photon energy under indoor photovoltaic conditions, using perovskite materials with wider bandgaps has become a consensus. However, updating absorbers requires additional adaptations involving at least two layers of transport and interfaces, increasing development complexity. This study acknowledges that buried interface is primary location for generation photoinduced carriers, achieving efficient carrier separation this will solve most open circuit voltage ( V OC ) loss issues encountered in transitioning from solar photovoltaics photovoltaics. Therefore, class bipolar pseudohalide ammonium salts proposed use as bridging agents effectively resolve lattice misalignment insufficient driving force when broadening bandgap, thereby reducing The optimized device exhibits an excellent photoelectric conversion efficiency (PCE) 41.04%, record‐high 1.08 V. It also demonstrates impressive long‐term operational stability T 80 lifetime 1000 h. Substituting various non‐buried different categories wide‐bandgap does not alter effectiveness, proving its universality.
Language: Английский
Citations
10
Small, Journal Year: 2025, Volume and Issue: unknown
Published: March 17, 2025
Abstract [4‐(3,6‐dimethyl‐9H‐carbazol‐9‐yl)butyl]phosphonic acid (Me‐4PACz) consistently exhibits inhomogeneous distribution on the substrate, which makes it a challenge for growth of high‐quality perovskite film, resulting in undesired interfacial losses at buried interfaces. Moreover, flexible alkyl chains Me‐4PACz are not conducive to intermolecular interactions and hinder charge flow. Here, novel molecule with 4‐Methoxy‐N‐(4‐methoxyphenyl)‐N‐phenylaniline (TPA) carbazole backbone, named CzTPA is designed, constituted Co‐SAM Me‐4PACz. The two carboxyls end will act as an anchoring group cover inadequate coverage NiO x . methoxy TPA can passivation uncoordinated Pb 2+ interface by interaction Pb─O. Additionally, be restrained self‐aggregation interacting CzTPA. cooperation realizes more homogeneous , efficient transport, minimize defects. Accordingly, modification significantly enhance efficiency 1.54‐eV PSCs from 23.53% 25.66% sustain 91.4% its original after 1992 h under continuous illumination 65 °C. More importantly, 1.68 eV wide‐bandgap PSC achieved PCE 22.75% good photostability.
Language: Английский
Citations
1
Small, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Abstract Recent advances in wide‐bandgap (WBG) perovskite solar cells (PSCs) demonstrate a burgeoning potential to significantly enhance photovoltaic efficiencies beyond the Shockley–Queisser limit for single‐junction cells. This review explores multifaceted improvements WBG PSCs, focusing on novel compositions, halide substitution strategies, and innovative device architectures. The of iodine with bromine organic ions such as FA MA Cs lattice is emphasized its effectiveness achieving higher open‐circuit voltages reduced thermalization losses. Furthermore, integration advanced charge transport layers interface engineering techniques discussed critical minimizing voltage ( V OC ) deficits improving photo‐stability these utilization PSCs diverse applications semitransparent devices, indoor photovoltaics, multijunction tandem devices also explored, addressing both their current limitations solutions. culminates comprehensive assessment challenges impeding industrial scale‐up PSC technology offers perspective future research directions aimed at realizing highly efficient stable commercial applications.
Language: Английский
Citations
1
Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 95, P. 357 - 363
Published: April 7, 2024
Language: Английский
Citations
8
Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)
Published: May 2, 2024
Language: Английский
Citations
8
Analytical Chemistry, Journal Year: 2024, Volume and Issue: 96(29), P. 12165 - 12172
Published: July 11, 2024
Exploring the high-performance photoelectronic properties of perovskite quantum dots (QDs) is desirable for paper-based photoelectrochemical (PEC) sensing;however, challenges remain in improving their stability and fundamental performance. Herein, a novel Z-scheme heterostructure with host-guest interaction by confinement CH
Language: Английский
Citations
8