Investigation of the effect of halide counterions on the potential corrosion inhibitor in imidazolium-based ionic liquids DOI
Abdelmajeed Adam Lagum,

Saroj Sharma,

Anupam Yadav

et al.

Phosphorus, sulfur, and silicon and the related elements, Journal Year: 2024, Volume and Issue: 199(4), P. 308 - 315

Published: April 2, 2024

Imidazolium (IMZ)-based ionic liquids (ILs) with various counter ions were investigated as potential corrosion inhibitors. Furthermore, parameters such bond lengths, angles, and dihedral bonds to demonstrate the adsorption sites of molecules. Moreover, in order compare efficiency inhibitors, other energy gap, hardness, LUMO, HOMO investigated. The LUMO values increased from −4.370 −0.106 eV −4.959 −0.156 eV, respectively, by changing F− I−. softness IMZ base changed 0.469 0.417 increasing radius halide ion. trend band gap value going I− changes 4.264 4.797 eV. total electron density was computed show based on density. According molecular reactivity results, inhibitory inhibitors following order: BMI-F > BMI-Cl BMI-Br BMI-I. Investigating IMZ-based ILs counterions evaluate inhibition profile molecules provides useful insights into computational protocols for study

Language: Английский

Recent trends in the use of cobalt ferrite nanoparticles as an antimicrobial agent for disability infections: A review DOI

Fuád Ameén,

Najwa Majrashi

Inorganic Chemistry Communications, Journal Year: 2023, Volume and Issue: 156, P. 111187 - 111187

Published: Aug. 6, 2023

Language: Английский

Citations

25
Carbon-based catalysts: advances in synthesizing N-heterocyclic compounds using graphene family and graphite oxide DOI
Parvin Beigiazaraghbelagh, Ahmad Poursattar Marjani

Research on Chemical Intermediates, Journal Year: 2024, Volume and Issue: 50(2), P. 485 - 531

Published: Jan. 5, 2024

Language: Английский

Citations

12
Synthesis of CuO@TiO2 nanocomposite and its photocatalytic and electrochemical properties. Application for treatment of azo dyes in industrial wastewater DOI Creative Commons
Rui Wang, Jiashun Cao, Jiajia Liu

et al.

International Journal of Electrochemical Science, Journal Year: 2023, Volume and Issue: 18(12), P. 100316 - 100316

Published: Aug. 10, 2023

In the present study, photocatalytic characteristics of CuO@TiO2 nanocomposite for decolorization Acid Yellow 36 (AY36) are investigated. FE-SEM, XRD, EDS, and XPS structural studies nanostructured photocatalysts showed that CuO TiO2 in (3:5) were successfully incorporated formed heterostructure. Results optical investigations gap energies pure CuO, TiO2, (1:5), (3:5), (5:5), (6:5) 1.88, 3.05, 2.94, 2.81, 2.77, 2.71 eV, respectively. According to findings, is a potential candidate visible light-consumed photocatalyst. Electrochemical analyses exhibited charge transfer resistance was significantly reduced samples, indicating an effective separation photo-excited electron-hole pairs. Photocatalytic reflected fast degradation rate presence nanocomposites compared TiO2. The results 20, 30, 50, 100, 200 mg/L AY36 completely eliminated after 35, 45, 65, 110, 185 minutes exposure simulated sunlight, A effectively used photocatalytically decolorize from actual textile wastewater performance material investigated deionized water industrial wastewater.

Language: Английский

Citations

19
Atroposelective Synthesis of Axially Chiral Naphthylpyrroles by a Catalytic Asymmetric 1,3-Dipolar Cycloaddition/Aromatization Sequence DOI Creative Commons
Ian Maclean,

Enrique Gallent,

Oscar Orozco

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(4), P. 922 - 927

Published: Jan. 24, 2024

A straightforward methodology for the enantioselective preparation of axially chiral 2-naphthylpyrroles has been developed. This protocol is based on a CuI/Fesulphos-catalyzed highly 1,3-dipolar cycloaddition an azomethine ylide followed by pyrrolidine alkylation and to pyrrole oxidation. The mild conditions employed in DDQ/blue light-mediated aromatization process facilitate effective central-to-axial chirality transfer affording corresponding pyrroles with high atroposelectivity.

Language: Английский

Citations

5
Computational Fluid Dynamics Simulation of a Membrane Contactor for CO2 Separation: Two Types of Membrane Evaluation DOI

Z. Alborzi,

Younes Amini,

Parya Amirabedi

et al.

Chemical Engineering & Technology, Journal Year: 2023, Volume and Issue: 46(10), P. 2034 - 2045

Published: July 6, 2023

Abstract Two different types of hollow‐fiber membrane contactors were used for CO 2 separation from the gas stream with monoethanolamine (MEA) absorbent and numerically investigated. After model validation experimental data, removal efficiency, MEA concentration, pressure drop variation examined under conditions by some effective parameters such as velocity, absorption solution porosity, tortuosity. Membrane tortuosity porosity enhancement led to light decrease increase in respectively, but velocity significantly reduced efficiency.

Language: Английский

Citations

12
Design, Synthesis, Antifungal Evaluation, Structure–Activity Relationship (SAR) Study, and Molecular Docking of Novel Spirotryprostatin A Derivatives DOI Creative Commons
Yangmin Ma,

Xia Miao,

Bin Jia

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(4), P. 864 - 864

Published: Feb. 15, 2024

Phytopathogenic fungi cause plant diseases and economic losses in agriculture. To efficiently control pathogen infections, a total of 19 spirotryprostatin A derivatives 26 spirooxindole were designed, synthesized, tested for their antifungal activity against ten pathogens. Additionally, the intermediates investigated, including proposing mechanism diastereoselectivity performing amplification experiments. The bioassay results demonstrated that possess good broad-spectrum activities. Compound 4d exhibited excellent vitro, equal to or higher than positive ketoconazole, Helminthosporium maydis, Trichothecium roseum, Botrytis cinerea, Colletotrichum gloeosporioides, Fusarium graminearum, Alternaria brassicae, alternate, solan (MICs: 8–32 µg/mL). 4k also displayed remarkable eight other phytopathogenic fungi, oxysporium f. sp. niveum Mycosphaerella melonis preliminary structure–activity relationships (SARs) further discussed. Moreover, molecular docking studies revealed anchored binding site succinate dehydrogenase (SDH). Therefore, these compounds showed potential as natural compound-based chiral fungicides hold promise candidates enhancements terms structure properties.

Language: Английский

Citations

3
Functionalized mesoporous silica for drug delivery of poorly soluble polyphenols: Synthesis, characterization, and antimicrobial action DOI

Pranita Rananaware,

Varsha Brahmkhatri,

Debatrayee Dasgupta

et al.

Journal of Solid State Chemistry, Journal Year: 2023, Volume and Issue: 326, P. 124214 - 124214

Published: July 23, 2023

Language: Английский

Citations

7
Recent Advances in the Total Synthesis of Spirotryprostatin Alkaloids DOI Creative Commons

Jing Hu,

Zhen-Xi Niu,

Junfeng Wang

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(7), P. 1655 - 1655

Published: April 7, 2024

Spirotryprostatin alkaloids, a class of alkaloids with unique spirocyclic indoledionepiperazine structure, were first extracted from the fermentation broth Aspergillus fumigatus and have garnered significant attention in fields biology pharmacology. The investigation into pharmacological potential this has unveiled promising applications drug discovery development. Notably, certain spirotryprostatin demonstrated remarkable anti-cancer activity, positioning them as candidates for anti-tumor In recent years, organic synthetic chemists dedicated efforts to devise efficient viable strategies total synthesis aiming meet demands within pharmaceutical domain. construction spiro-C atom scaffold chirality control at spiro atomic center emerge pivotal aspects these compounds. This review categorically delineates based on formation mechanism atom.

Language: Английский

Citations

2
Peptide Macrocyclization via Cu-catalyzed 1,3-Dipolar Cycloaddition of Azomethine Ylides DOI Creative Commons
Javier Adrio, Nuria Rodríguez, Juan C. Carretero

et al.

Published: June 25, 2024

Cyclic peptides are highly valued synthetic targets in organic and medicinal chemistry. The development of new methodologies for peptide macrocyclization, different from classical lactamization, is essential the progress field. Herein, we report an efficient diastereoselective macrocyclization strategy synthesis cyclic using 1,3-dipolar cycloaddition azomethine ylides. Linear precursors length bearing diverse amino acids have shown to be compatible with this method (26 examples), giving good yields almost complete diastereoselectivity. DFT calculations suggest a stepwise mechanism which Cu plays key role reagents preorganization.

Language: Английский

Citations

2
Dipolarophile‐Steered Formal Stereodivergent Synthesis of 2,5‐cis/trans‐Pyrrolidines Based on Asymmetric 1,3‐Dipolar Cycloaddition of Imino Lactones DOI

Shohei Furuya,

Kenji Muroi,

Kazuya Kanemoto

et al.

Chemistry - A European Journal, Journal Year: 2023, Volume and Issue: 29(66)

Published: Sept. 11, 2023

The stereodivergent asymmetric synthesis of 2,5-trans/cis pyrrolidines by 1,3-dipolar cycloaddition using two different types activated alkenes is described. When ylidene-isoxazolones were employed as dipolarophiles, the Ag/(S,Sp )-iPr-FcPHOX-catalyzed [3+2] imino lactones proceeded with 2,5-trans selectivity. Subsequent decarboxylation isoxazolone rings produced stereoretention. In reaction acyclic enones alkenes, Ag/(R,Sp )-ThioClickFerrophos complex-catalyzed afforded 2,5-cis substituted in high yields and enantioselectivities. Therefore, these methods can be considered a formal 2,5-cis/trans pyrrolidines.

Language: Английский

Citations

6