Synthetic Versatility: The C-P Bond Odyssey DOI
Peng Zhang, Yinan Wang, Zixin Deng

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 15, 2024

The review thoroughly examines recent progress in C–P bond formation reactions and considers the future directions this area of research.

Language: Английский

Selective Synthesis of Mono- and Bis-Phosphorylated (Dihydro)pyrans via TMSCl-Mediated Cascade Phosphorylation Cycloisomerization of Enynones DOI
Yi‐Feng Qiu, Qiang Wang,

Jian-He Cao

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 26, 2024

A chlorotrimethylsilane (TMSCl)-mediated cascade phosphorylation and cycloisomerization of enynones with diphenylphosphine oxides is presented. This methodology enables the highly selective synthesis monophosphorylated 2

Language: Английский

Citations

2
Rhodium‐Catalyzed Enantio‐ and Regioselective Allylation of Indoles with gem‐Difluorinated Cyclopropanes DOI

Hui Yang,

Yaxin Zeng,

Xiangyu Song

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(22)

Published: March 22, 2024

Abstract The use of gem ‐difluorinated cyclopropanes ( ‐DFCPs) as fluoroallyl surrogates under transition‐metal catalysis has drawn considerable attention recently but such reactions are restricted to producing achiral or racemic mono‐fluoroalkenes. Herein, we report the first enantioselective allylation indoles rhodium with ‐DFCPs. This reaction shows exceptional branched regioselectivity towards ‐DFCPs, which provides an efficient route enantioenriched fluoroallylated wide substrate scope and good functional group tolerance.

Language: Английский

Citations

1
Recent Progress in Metal-Catalyzed C(sp³)-P Bond Formation DOI
Jia‐Lin Tu, Zhengjia Shen, Binbin Huang

et al.

Tetrahedron, Journal Year: 2024, Volume and Issue: 168, P. 134352 - 134352

Published: Nov. 1, 2024

Language: Английский

Citations

1
Nucleophilic Ring Opening of Donor–Acceptor Cyclopropanes through Umpolung Reactivity of Organochlorophosphines: Phosphine Oxide-Functionalized Boron-Pendanted Compounds DOI

Braj Gopal,

Manisha Lamba, Apoorv Kushwaha

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 27, 2024

We present a novel set of frustrated Lewis pair (FLP) systems that exhibit remarkable ability to promote the ring opening donor-acceptor cyclopropanes (DACs). This FLP-promoted protocol offers umpolung reactivity R

Language: Английский

Citations

0
(XantPhos)AgBr as a cheap and readily available catalyst for the bromofluorocyclopropanation of electron-rich alkenes DOI
Maxim A. Novikov, Angelina Yu. Bobrova,

Anton A. Servetnik

et al.

Mendeleev Communications, Journal Year: 2024, Volume and Issue: 34(5), P. 698 - 700

Published: Sept. 1, 2024

Language: Английский

Citations

0
Potassium Phosphate‐Mediated Synthesis of C4‐Phosphorylated Quinolines via Cascade Cycloisomerization of Ynones DOI Open Access
Yi‐Feng Qiu,

Jin-Hao Li,

Qiang Wang

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 5, 2024

Abstract A cascade phosphorylation cycloisomerization of readily accessible ynones and diphenylphosphine oxides facilitated by potassium phosphate is described, allowing for the straightforward synthesis C4‐phosphorylated quinoline scaffolds. The formation a C−P bond C−N achieved in single procedure without need pre‐assembled cores prior to phosphorylation. This transformation operates requirement metals or oxidants exhibits excellent compatibility with various functional groups. Furthermore, antimicrobial activity evaluation demonstrated that synthesized derivatives exhibited potent inhibitory against Staphylococcus aureus.

Language: Английский

Citations

0
Synthetic Versatility: The C-P Bond Odyssey DOI
Peng Zhang, Yinan Wang, Zixin Deng

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 15, 2024

The review thoroughly examines recent progress in C–P bond formation reactions and considers the future directions this area of research.

Language: Английский

Citations

0