Palladium-Catalyzed Cascade Carbonylation Reaction To Construct Ester Derivatives
Ming Li,
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Shan-Mei Xu,
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Fei Yang
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et al.
The Journal of Organic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 24, 2025
We
have
developed
a
palladium-catalyzed
ester
carbonylation
reaction
that
enables
the
synthesis
of
ester-substituted
benzofuran
derivatives
in
single
step
through
introduction
alkyl
halides
undergoing
situ
hydrolysis
and
alkynyl
aryl
iodides.
This
method
demonstrates
broad
applicability
to
both
primary
secondary
while
maintaining
excellent
functional
group
compatibility
under
low
palladium
loading
conditions.
Notably,
this
strategy
significantly
expands
scope
reactions.
Language: Английский
Tandem [4C + 2C] cyclization reaction of α-acetyl-α-oxo ketene dithioacetals and acrylonitrile: A straightforward synthesis of polysubstituted cyclohex-3-enones
Xiao-Bo Zhao,
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Zixuan Cha,
No information about this author
Xinyue Liu
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et al.
Synthetic Communications,
Journal Year:
2025,
Volume and Issue:
unknown, P. 1 - 12
Published: April 26, 2025
Language: Английский