Sulfur functionalized diamondoid phosphines enable building nanocomposites interfacing sp3-carbon and gold nanolayer DOI

Moad Bouzid,

Didier Poinsot,

Clève Dionel Mboyi

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 23, 2024

Interfacing metal frameworks with carbon-based materials is attractive for the bottom-up construction of nanocomposite functional materials. The stepwise layering difunctionalized diamantanes and gold from physical chemical vapor deposition preparation nanocomposites inverts conventional metal-organic (MOFs) self-assemblies, where introduced first, this method delivers surfaces modified properties originating sp3-carbon core. However, appropriate diamondoid candidates such an approach are rare. By mild organometallic complex MeAuPMe3, coating achieved on a diamantane SP(V) sulfide primary phosphine diamantanol 2. This later leads to polysulfide surface rearrangement provides suitable substrate formation through fully-dry process, advantage, in contrast P(III) phosphinodiamantanol 1, being resistant uncontrolled oxidation at phosphorus during (PVD) (CVD) processing.

Language: Английский

Metal‐Organic Frameworks (MOFs): Classification, Synthesis, Modification, and Biomedical Applications DOI
Dayang Wang,

Huanchen Yao,

Jiashuo Ye

et al.

Small, Journal Year: 2024, Volume and Issue: 20(47)

Published: Aug. 16, 2024

Abstract Metal‐organic frameworks (MOFs) are a new variety of solid crystalline porous functional materials. As an extension inorganic materials, it has made important progress in preparation and application. MOFs widely used various fields such as gas adsorption storage, drug delivery, sensing, biological imaging due to their high specific surface area, porosity, adjustable pore size, abundant active sites, modification by introducing groups. In this paper, the types classified, synthesis methods mechanisms materials summarized. Finally, application prospects challenges metal‐organic framework biomedical field discussed, hoping promote multidisciplinary fields.

Language: Английский

Citations

17
Smart Nano-Hybrid Metal-Organic Frameworks: Revolutionizing Advancements, Applications, and Challenges in Biomedical Therapeutics and Diagnostics DOI Creative Commons
Dilip Kumar Chandra, Awanish Kumar, Chinmaya Mahapatra

et al.

Hybrid Advances, Journal Year: 2025, Volume and Issue: unknown, P. 100406 - 100406

Published: Feb. 1, 2025

Language: Английский

Citations

2
Novel bio-carriers for radionuclide delivery in cancer radiotherapy DOI

Lishan Wang,

Qing‐Yu He,

Jianping Man

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 533, P. 216557 - 216557

Published: Feb. 26, 2025

Language: Английский

Citations

0
Recent advances in metal-organic frameworks (MOFs)-based colorimetric sensors for visual detection of food freshness DOI

Weicheng Sun,

Yapeng Huo,

Xueying Feng

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 535, P. 216638 - 216638

Published: March 27, 2025

Language: Английский

Citations

0
2D Coordination Polymer [Fe(piv)2(dab)2]n DOI Creative Commons

V. A. Bushuev,

Dmitriy S. Yambulatov, Stanislav A. Nikolaevskii

et al.

Molbank, Journal Year: 2025, Volume and Issue: 2025(2), P. M1987 - M1987

Published: March 31, 2025

The interaction of preorganized iron(II) pivalate complexes with aromatic N-donor ligand (pyridine (py) or 2,2′-bipyridine (bpy)) and 1,4-diaminobutane (dab, putrescine) in anhydrous acetonitrile yielded a new 2D coordination polymer [Fe(piv)2(dab)2]n (1, piv = Me3CCO2–). molecular structure 1 crystal was determined by single-crystal X-ray diffraction analysis ATR-FTIR spectroscopy.

Language: Английский

Citations

0
Advances and applications of metal–organic framework/molecularly imprinted polymer (MOF/MIP) for fluorescence detection DOI

Yuxuan Mao,

Ruru Xiong,

Jingjing Tian

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 537, P. 216691 - 216691

Published: April 17, 2025

Language: Английский

Citations

0
Contemporary Progress on Multifarious Coordination Polymers for Organocatalytic, Sensing and Energy Mimetic Applications DOI
Shankab J. Phukan,

Suraj Goswami,

Neeraj K. Sah

et al.

Materials Today Energy, Journal Year: 2024, Volume and Issue: 46, P. 101703 - 101703

Published: Oct. 9, 2024

Language: Английский

Citations

1
Sulfur functionalized diamondoid phosphines enable building nanocomposites interfacing sp3-carbon and gold nanolayer DOI

Moad Bouzid,

Didier Poinsot,

Clève Dionel Mboyi

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 23, 2024

Interfacing metal frameworks with carbon-based materials is attractive for the bottom-up construction of nanocomposite functional materials. The stepwise layering difunctionalized diamantanes and gold from physical chemical vapor deposition preparation nanocomposites inverts conventional metal-organic (MOFs) self-assemblies, where introduced first, this method delivers surfaces modified properties originating sp3-carbon core. However, appropriate diamondoid candidates such an approach are rare. By mild organometallic complex MeAuPMe3, coating achieved on a diamantane SP(V) sulfide primary phosphine diamantanol 2. This later leads to polysulfide surface rearrangement provides suitable substrate formation through fully-dry process, advantage, in contrast P(III) phosphinodiamantanol 1, being resistant uncontrolled oxidation at phosphorus during (PVD) (CVD) processing.

Language: Английский

Citations

0