Cited by Zero-Dimensional Organic-inorganic Hybrid Indium Halide Perovskite with Broadband Yellow Light Emission

Organic−Inorganic Hybrid Perovskite-Like Indium Chloride with Strong Red Emission DOI

Shuilong Kang,

Qingqing He,

Yueqi Shen

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 13, 2025

Low-dimensional organic-inorganic hybrid metal halide materials have attracted widespread attention due to their excellent and tunable photoelectric properties. However, the low intrinsic photoluminescence quantum yields (PLQYs) limit further applications in optoelectronic devices. Here, we report synthesis of lead-free zero-dimensional indium chloride crystals, (FA)3InCl6: xSb3+, with strong red-light emission through controlled Sb3+ doping. The optimal composition, 20.16% Sb3+, exhibits PLQY up 30% emits red broadband light centered at 690 nm. enhancement doped samples was investigated by combining temperature-dependent wavelength-dependent spectra, revealing self-trapped exciton (STE) recombination process. clear elucidation complexation process has provided a solid theoretical basis for optimization material properties, which is great significance development new light-emitting materials. Far-red phosphor-converted LED devices been constructed these demonstrate stable efficient various voltages, exhibiting superior stability. This study highlights potential Sb3+-doped halides achieve demonstrates single crystals indoor plant lighting, infrared imaging, photodynamic therapy wound healing.

Language: Английский

Citations

Organic Indium Halides with Near-Unity Photoluminescence Quantum Yields for Highly Efficient Luminescent Inks and White Light Emitting Diodes DOI

Qi Wang, Wei Jiang,

T Liu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: April 9, 2025

Zero-dimensional (0D) organic indium halides have been emerged as promising broadband light emitters with wide application prospects, but most of the present suffer from low photoluminescence quantum yield (PLQY), and a high-power excitation source is needed to obtain desirable performance. In this work, we elaborately select appropriate cations crystal structural engineering obtained series highly efficient 0D bromides. Under UV excitation, these display yellow emissions (550-600 nm) near-unity PLQYs, which represents one highest values in all previously reported halides. Benefiting successful nanoscale engineering, luminescent inks based on are facilely prepared by dispersing nanocrystals into various solvents. The ink can be utilized print anticounterfeiting patterns, displays photoreversible switching visible/invisible transformation under alternating irradiation visible light. Furthermore, white emitting diodes fabricated high color rendering index above 90 using down-conversion phosphors. This work not only promotes development also significantly broadens solid-state illumination anticounterfeiting, etc.

Language: Английский

Citations

Spatial & Temporal Dual-Resolved Anti-Counterfeiting Applications in a Long Afterglow System Based on Bismuth Halides DOI

Xin Zhang, Jie Hao, Maolin Cai

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

While anticounterfeiting systems based on long persistent luminescence (LPL) materials demonstrate a mature trend, the integration of tunable luminescent lifetimes and emission colors in LPL-based remains challenge. Herein, we propose temporal spatial strategy utilizing novel zero dimensional (0D) metal halides, specifically (PBA)3BiCl6:xSb3+ (PBA = 4-Phenylbenzylamine, x 0, 0.05, 0.1, 0.15), which exhibit characteristics. A controllable color transition can be observed from green to white orange by varying excitation wavelength, accompanied different afterglow durations LPL emission. Additionally, various are at delay times. Furthermore, controlled duration is achieved through Sb3+ doping (PBA)3BiCl6, attributed triplet energy transfer (TET) process. noticeable when using mobile phone's flashlight as source, enhancing portability light source. The multifaceted tuning modulation establish foundation for multicolor time-resolved anticounterfeiting, significantly elevating security level advanced portable systems.

Language: Английский

Citations

Yellow-Orange Emission in Sb³⁺-Doped Hexakis(thiocarbamidium) Hexabromoindium(III) Tribromide DOI

Nicolay N. Golovnev, Marina A. Gerasimova,

Irina M. Belash

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(20), P. 9175 - 9183

Published: May 9, 2024

A luminescent zero-dimensional organic-inorganic hybrid indium halide (TUH)

Language: Английский

Citations

Zero-Dimensional Indium-Based Hybrid Halides with Fast Digital Encryption and Decryption, High-Efficiency Wled Via Antimony-Doped DOI

Lulu Jiang, Ling-Kun Wu,

Haiyan Sun

et al.

Published: Jan. 1, 2024

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Language: Английский

Citations

Lead Bromide Complex in Tri‐n‐octylphosphine Oxide Matrix with Bright Photoluminance and Exceptional Thermoplasticity DOI

Yu Hou, Yuting Sun, Jingjing He

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 23, 2024

Abstract Metal halide materials have recently drawn increasing research interest for their excellent opto‐electronic properties and structural diversity, but resulting rigid structures render them brittle poor formability during manufacturing. Here we demonstrate a thermoplastic luminant hybrid lead solid by integrating bromide complex into tri‐n‐octylphosphine oxide (TOPO) matrix. The construction of the can be achieved simple dissolution process, in which TOPO molecules act as solvents ligands to yield monodispersed clusters. combination these functional units enables near‐room‐temperature melt‐processing targeted geometry molding or printing techniques, offer possibilities fluorescent writing inks with outstanding self‐healing capacity physical damage. intermarriage between metal clusters expands range practical applications materials.

Language: Английский

Citations

On–Off Switching of Singlet Self‐Trapped Exciton Emission Endows Antimony‐Doped Indium Halides with Excitation‐Wavelength‐Dependent Luminescence DOI

Xinyu Yang, Hongyuan Zhao,

Ziying Wen

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 2, 2024

Excitation-wavelength-dependent (Ex-De) emitters are a fascinating category of luminescent materials whose emission properties vary with the wavelength light used for excitation. Antimony (Sb

Language: Английский

Citations

Gradient Luminescence Enhancement in Organic Metal Halide Perovskites via the Suppression of [SbCl_n]^3–n Unit Distortion DOI

Zixun Zeng,

Guodong Zhang,

Yingsheng Wang

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 9, 2024

Intrinsic stereochemical activity of the 5s

Language: Английский

Citations

Discerning the Structure–Photophysical Property Correlation in Zero-Dimensional Antimony(III)-Doped Indium(III) Halide Hybrids DOI

Alisha Basheer Shamla,

D. S. Sarma, Deep Kumar Das

et al.

The Journal of Physical Chemistry Letters, Journal Year: 2024, Volume and Issue: 15(32), P. 8224 - 8232

Published: Aug. 5, 2024

Zero-dimensional (0D) metal halide hybrids incorporating optically emissive Sb

Language: Английский

Citations

White Light Emission in Zero-Dimensional Indium Hybrid with Hydrogen Bond DOI

Jiawei Lin,

Niu Sun,

Ruonan Yao

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(42), P. 19819 - 19826

Published: Oct. 9, 2024

Low-dimensional organic-inorganic metal halides (OIMHs) have been explored as single-component white light emitters for applications in solid-state lighting. Herein, we report a zero-dimensional (0D) In-based OIMH (TMPDA)[InCl

Language: Английский

Citations