Advanced Healthcare Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 10, 2024
Conductive
hydrogel
has
garnered
significant
attention
as
an
emergent
candidate
for
diverse
wearable
sensors,
owing
to
its
remarkable
and
tailorable
properties
such
flexibility,
biocompatibility,
strong
electrical
conductivity.
These
attributes
make
it
highly
suitable
various
sensor
applications
(e.g.,
biophysical,
bioelectrical,
biochemical
sensors)
that
can
monitor
human
health
conditions
provide
timely
interventions.
Among
these
applications,
conductive
hydrogel-based
temperature
sensors
are
especially
important
healthcare
disease
surveillance.
This
review
aims
a
comprehensive
overview
of
sensors.
First,
this
work
summarizes
different
types
fillers-based
hydrogel,
highlighting
their
recent
developments
advantages
Next,
discusses
the
sensing
characteristics
focusing
on
sensitivity,
dynamic
stability,
stretchability,
signal
output.
Then,
state-of-the-art
introduced,
ranging
from
body
detection
wound
monitoring.
Finally,
identifies
remaining
challenges
prospects
facing
field.
By
addressing
with
potential
solutions,
hopes
shed
some
light
future
research
innovations
in
promising
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 20, 2024
Abstract
The
last
decades
have
witnessed
the
rapid
growth
of
hydrogel
bioelectronics.
Traditional
hydrogels
face
challenges
when
working
under
extreme
conditions,
causing
a
loss
stabilities
and
functionalities.
This
review
provides
systematic
overview
capable
with
focus
on
their
applications
in
bioelectronic
systems.
These
are
summarized
into
categories
anti‐mechanical
damage,
anti‐detachment,
anti‐swelling,
anti‐freezing,
anti‐foreign
body
response.
Strategies
including
material
development
structural
design
that
can
endow
above
properties
introduced.
Finally,
current
new
opportunities
developing
devices
systems
discussed.
Ion-conductive
hydrogels
have
attracted
tremendous
attention
and
are
considered
promising
for
ionic
skin.
However,
the
simultaneous
incorporation
of
excellent
mechanical
strength,
low-temperature
tolerance,
high
conductivity
transparency
remains
a
great
challenge,
which
will
restrict
their
scope
applications.
Here,
transparent,
freezing-tolerant,
mechanically
robust
ion-conductive
hydrogel
based
on
double-network
structure
(k-carrageenan/poly(acrylic
acid))
in
binary
solvent
system
(ionic
liquid/water)
is
proposed
strain-sensing
application.
The
liquid
([EMIM]Cl)
introduced
into
double
network
by
simple
one-pot
polymerization
method,
followed
subsequent
drying
treatment.
Benefiting
from
presence
liquid,
prepared
transparent
(>90%
transmittance)
demonstrates
properties,
including
fracture
stretchability
(>3000%
strain),
tensile
strength
(>0.45
MPa),
low
Young's
modulus
(65
kPa).
Meanwhile,
due
to
reduction
water
system,
exhibit
good
freezing
tolerance
(<−25
°C),
while
maintaining
up
0.25
S/m
at
room
temperature.
In
addition,
benefiting
hydrogel-based
flexible
strain
sensors
studied
demonstrated
various
applications
toward
deformation
detect
human
motion
signals,
such
as
finger
bending
walking.
This
work
can
provide
strategy
construct
with
environmental
stability
potential
wearable
sensors.
Scientific Reports,
Journal Year:
2025,
Volume and Issue:
15(1)
Published: March 1, 2025
Abstract
The
application
of
flexible
hydrogel
sensors
in
extreme
environments,
such
as
low
temperatures,
underwater,
or
significant
mechanical
deformations,
poses
considerable
challenges.
Here,
we
present
a
simple
one-pot
method
to
fabricate
ultra-tough,
swelling-
and
freezing-resistant
conductive
organohydrogels
without
external
freeze-resistant
fillers.
During
gelation,
by-products
(C
6
H
15
NHCl,
KCl)
provide
both
conductivity
antifreeze
properties,
thus
eliminating
compatibility
issues
dispersion
challenges
associated
with
resulting
gel
exhibits
super
toughness,
tensile
strength
reaching
10.2
MPa
stretchability
up
800%
the
dry
state.
Following
covalent
crosslinking,
demonstrates
excellent
anti-swelling
swelling
ratio
only
15.4%
after
24
h
water
immersion,
while
maintaining
5.8
an
elongation
1000%.
When
fabricated
into
sensors,
these
gels
display
stable
electrical
responsiveness
desired
Gauge
Factor
(0.58–2.25),
effectively
detecting
limb
movements.
Furthermore,
gel’s
superior
resistance
freezing
ensures
reliable
signal
stability
under
−
20
°C
underwater
conditions.
These
combined
properties
render
promising
candidate
for
sensing
components
robotic
bionic
applications.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 29, 2024
Abstract
Ionogels
are
considered
as
ideal
candidates
for
constructing
flexible
electronics
due
to
their
superior
electrical
conductivity,
flexibility,
high
thermal
and
electrochemical
stability.
However,
it
remains
a
great
challenge
simultaneously
achieve
sensitivity,
repeated
adhesion,
good
self‐healing,
biocompatibility
through
straightforward
strategy.
Herein,
inspired
by
nucleobase‐tackified
strategy,
multifunctional
adhesive
ionogel
is
developed
one‐step
radical
polymerization
of
acrylated
adenine/uracil
(Aa/Ua)
acrylic
acid
(AA)
monomers
in
sodium
caseinate
(SC)
stabilized
liquid
metal
dispersions.
As
soft
conductive
filler,
the
incorporating
not
only
improves
but
also
enhances
mechanical
strength,
satisfying
stretchable
sensing
application.
The
large
amount
noncovalent
interactions
(hydrogen
bonding,
coordination,
ion‐dipole
interactions)
within
networks
enable
ionogels
possess
excellent
stretchability,
skin‐like
softness,
strong
adhesion.
Based
on
these
desirable
characteristics,
suitable
wearable
strain
sensors
precisely
detect
diverse
human
movements
under
extreme
environments.
Moreover,
seamless
adhesion
with
skin
allows
function
bioelectrode
patch
long‐term
high‐quality
electrophysiological
signal
acquisition.
This
research
provides
promising
strategy
designing
tailored
functionalities
that
satisfy
application
requirements.