Precision-Engineered Construction of Proton-Conducting Metal–Organic Frameworks

Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 17(1)

Published: Dec. 11, 2024

Proton-conducting materials have attracted considerable interest because of their extensive application in energy storage and conversion devices. Among them, metal-organic frameworks (MOFs) present tremendous development potential possibilities for constructing novel advanced proton conductors due to special advantages crystallinity, designability, porosity. In particular, several design strategies the structure MOFs opened new doors advancement MOF conductors, such as charged network construction, ligand functionalization, metal-center manipulation, defective engineering, guest molecule incorporation, pore-space manipulation. With implementation these strategies, proton-conducting developed significantly profoundly within last decade. Therefore, this review, we critically discuss analyze fundamental principles, methods targeted at improving conductivity through representative examples. Besides, structural features, conduction mechanism behavior are discussed thoroughly meticulously. Future endeavors also proposed address challenges practical research. We sincerely expect that review will bring guidance inspiration further motivate research enthusiasm materials.

Language: Английский

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Metal-organic frameworks based solid-state electrolytes for lithium metal batteries: Modifications and future prospects

Next Energy, Journal Year: 2024, Volume and Issue: 6, P. 100191 - 100191

Published: Sept. 11, 2024

Language: Английский

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Exploring MOF-74 composites: From novel synthesis to cutting-edge applications

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114026 - 114026

Published: Jan. 1, 2025

Language: Английский

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Enhancing ionic conductivity and expanding the electrochemical window in polymer electrolytes via ferroelectric-metal-organic-frameworks to manipulate charge spatial distribution

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 685, P. 437 - 448

Published: Jan. 20, 2025

Language: Английский

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Copper-doped metal–organic framework-74 solid-state electrolytes for high performance all-solid-state sodium metal batteries

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 689, P. 137241 - 137241

Published: March 4, 2025

Language: Английский

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Ultra-thin, Scalable, and MOF Network-Reinforced Composite Solid Electrolyte for All-Solid-State Lithium Metal Batteries

Journal of Membrane Science, Journal Year: 2025, Volume and Issue: unknown, P. 124009 - 124009

Published: March 1, 2025

Language: Английский

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Multicomponent Quasi-Solid-State Polymer Electrolyte Incorporating MOFs and Halloysite Nanotubes for Enhanced Sodium Metal Battery Performance

ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: 7(21), P. 10196 - 10202

Published: Oct. 31, 2024

Solid-state sodium metal batteries are among the most promising next-generation energy storage devices. However, developing competent solid-state electrolytes for these remains a significant challenge. Herein, we introduce design quasi-solid-state polymer electrolyte that enhances battery performance. This multicomponent electrolyte, designated PH-MSN-HNT, was synthesized by incorporating modified MOF particles and halloysite nanotubes (HNTs) into PVDF-HFP (PH) matrix. Due to synergistic effects of components, PH-MSN-HNT exhibits superior ion conductivity (>10–3 S cm–1) at room temperature, high Na+ transference number (0.79), wide electrochemical stability window (5.16 V). Furthermore, used as an assemble batteries, which demonstrate efficient dendrite suppression remarkable cycling performance with 98% capacity retention (108.6 mAh g–1 0.1 C) after 100 charge/discharge cycles over 1000 h.

Language: Английский

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A spontaneous spatial network structural metal-organic framework composite polymer electrolytes with excellent lithium transport performance for dendrite-suppressing lithium metal batteries

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 158820 - 158820

Published: Dec. 1, 2024

Language: Английский

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Exploring metal-organic frameworks in battery electrodes, separators, and electrolytes: A comprehensive review

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 532, P. 216501 - 216501

Published: Feb. 21, 2025

Language: Английский

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Tailoring Ce-Centered Metal–Organic Frameworks for Fast Li⁺ Transport in Composite Polymer Electrolyte

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(45), P. 62052 - 62063

Published: Nov. 1, 2024

Regulating metal nodes to innovate the metal–organic framework (MOF) structure is of great interest boost performance MOFs-incorporated composite solid electrolytes. Herein, Ce4+ with a low-lying 4f orbital selected as center coordinate organic ligand prepare MOF Ce-UiO-66. The unsaturated open sites and defected oxygen vacancies furnish Ce-UiO-66 strengthened Lewis acidity, which promotes interacting effectively both poly(ethylene oxide) (PEO) Li salt anions. Accordingly, additive fillers can be uniformly dispersed in PEO matrix form an advanced solid-state electrolyte (Ce-UiO@PEO) accelerated Li+ transport. optimized Ce-UiO@PEO displays boosted ionic conductivity 4.20 × 10–4 S cm–1 improved transference number 0.39 at 60 °C, are highly comparable those other MOFs@PEO Combined mechanical thermal stabilities, such enables Li/Li symmetric Li/LiFePO4 full cells superior cycling stability rate performance. electrolytes potential applied high-performance lithium batteries.

Language: Английский

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