Diatom-Inspired Nanoscale Heterogeneous Assembly Strategy for Constructing Thermal Insulating Wood-Based Aerogels with Exceptional Strength, Resilience, Degradability, and Flame Retardancy
Zhiyi Liu,
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Tao Liu,
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Hongping Dong
No information about this author
et al.
ACS Nano,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 11, 2025
The
potential
of
thermally
insulated
wood
aerogels
in
energy-efficient
engineering
is
constrained
by
their
mechanical
weakness
and
inadequate
environmental
stability.
Combining
minerals
with
offers
promise
for
enhancing
multifaceted
performance.
However,
fabricating
high-performance
wood-based
via
organic–inorganic
assembly
remains
challenging
due
to
poor
uniformity
weak
interfacial
bonding.
Herein,
inspired
diatoms,
an
ultrastrong
flame-retardant
biomimetic
polymethylsilsesquioxane–wood
aerogel
(MSQW)
fabricated
combining
a
nanoscale
heterogeneous
strategy
sol–gel
process
precisely
engineer
each
level
the
hierarchy.
Meanwhile,
situ
mineralization
amorphous
inorganic
oligomers
firmly
welds
interface,
forming
continuous
homogeneous
monolithic
structure.
resulting
MSQW
exhibits
ultrahigh
stiffness
axial
direction
(Young's
modulus
68.73
±
3.20
MPa)
withstands
over
60%
strain
at
6.97
MPa
radial
direction,
recovering
its
original
shape
after
stress
release,
unique
structural
features.
Additionally,
excellent
combination
properties,
including
outstanding
fire
resistance
(
peak
heat
release
rate
91.13
kW/m2),
hydrophobicity
(water
contact
angle
137.3°),
degradability.
These
advanced
properties
make
ideal
material
thermal
insulation
harsh
environments.
Language: Английский
Strong and Ultrahigh Temperature‐Resistant Metal Oxide Nanobelt Aerogels
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 2, 2024
Abstract
Metal
oxide
aerogels,
inorganic
cousins
of
the
highly
commercialized
metalloid
silica
exhibit
distinct
properties
specific
to
each
type.
Nevertheless,
they
share
a
common
challenge
with
aerogels—brittleness
and
low
mechanical
strength
due
their
particulate
necklace‐like
structure.
In
contrast,
polymer
aerogels
often
boast
significantly
enhanced
thanks
nanofibrillated
networks.
To
enhance
metal
formation
polymeric
nanostructure
is
micro‐templated.
This
method
transforms
microstructure
(e.g.,
Al
2
O
3
Cr
,
Fe
)
into
polymer‐like
nanobelt
Remarkably,
even
after
removing
template
through
calcination
at
600
°C,
structure
remains
intact.
These
(MNB)
exceptional
compressibility
while
retaining
mesoporous
As
demonstration,
resulting
Al‐MNB
aerogel
can
withstand
compression
up
80%
strain
without
fracturing
preserving
its
porous
high
surface
area
228
m
g
−1
pore
volume
0.7
cm
heat
treatment
1300
°C.
work
introduces
an
innovative
strategy
for
creating
distinctive
microstructure,
paving
way
novel
applications
unique
structures
performance.
Language: Английский
Elastic, flexible, and tough hierarchical polyimide aerogels with dynamic reversible physical entanglement structure
C-Q. Li,
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Xiaodong Wang,
No information about this author
Chen Zhang
No information about this author
et al.
Chemical Engineering Journal,
Journal Year:
2025,
Volume and Issue:
unknown, P. 161429 - 161429
Published: March 1, 2025
Language: Английский
Polyvinyltrimethoxysilane-enhanced TEMPO-oxidized cellulose nanofiber aerogels for exceptional anisotropic thermal insulation, flame retardancy and oil/water separation
Ming Zeng,
No information about this author
Qionghao Xu,
No information about this author
Jiangang Yu
No information about this author
et al.
Industrial Crops and Products,
Journal Year:
2025,
Volume and Issue:
unknown, P. 120862 - 120862
Published: March 1, 2025
Language: Английский
Seed strategy synthesis of porous NASICON structured NaTi2(PO4)3/carbon aerogel nanocomposites for high-performance hybrid capacitive deionization
Separation and Purification Technology,
Journal Year:
2024,
Volume and Issue:
354, P. 129092 - 129092
Published: Aug. 3, 2024
Language: Английский
Stability-enhanced (Cu-, Zn-)MOFs via (Cu, Zn)S composite strategy: A promising approach for oil-water separation
Xinyu Pei,
No information about this author
Jianwen Zhang,
No information about this author
Yujie Tang
No information about this author
et al.
Surface and Coatings Technology,
Journal Year:
2024,
Volume and Issue:
unknown, P. 131316 - 131316
Published: Sept. 1, 2024
Language: Английский
Thermal-Insulation Fillers’ Influences on the Heating Resistance of PDMS-Based Aerogel Layer
Linlin Liu,
No information about this author
Xinyi Zhang,
No information about this author
Weizhen Li
No information about this author
et al.
Coatings,
Journal Year:
2024,
Volume and Issue:
14(8), P. 976 - 976
Published: Aug. 2, 2024
PDMS-based
aerogel
layers
were
synthesized
as
insulation
by
adopting
mullite
fiber
(MF),
hollow
glass
microspheres
(HGM)
and
silica
(SA)
the
main
fillers,
their
loading
amounts
content
ratios
checked
to
investigate
effects
on
thermal
properties
in
PDMS
composites
conductivity,
stability,
insulation.
The
amount
of
nanofillers
can
significantly
influence
insulation-layer
performance,
best
performance
with
lowest
conductivity
0.0568
W/(m·K)
was
obtained
10
wt%
MF:SA:HGM
=
2:2:1,
which
achieve
a
temperature
difference
(∆T)
67
°C
200
hotplate.
Moreover,
variation
filler
also
affect
behavior
when
is
fixed
at
wt%,
barrier
be
found
for
sample
more
SA
(MF:SA:HGM
1:3:1).
formed
had
stability
property,
stand
9
min
flame
test
without
burning
butane
spray
gun,
backside
showed
∆T
>
500
whole
test.
Language: Английский
Polymer Composite Coatings Enhanced with Superhydrophobic Properties for Flexible Electronics Applications: A Review
Polymer-Plastics Technology and Materials,
Journal Year:
2024,
Volume and Issue:
64(4), P. 552 - 573
Published: Oct. 26, 2024
Language: Английский
Nano‐Silica‐Based Double‐Layer Antireflective Coatings with Mildew Resistance and Moisture Resistance for KDP Crystals
Small Methods,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 25, 2024
Abstract
Sol–gel
nano‐silica
antireflective
(AR)
coatings
with
moisture
resistance
are
widely
used
for
optical
elements,
such
as
potassium
dihydrogen
phosphate
(KDP)
crystals,
but
their
mildew
is
often
disregarded.
This
work
reports
a
double‐layer
AR
coating
and
KDP
crystals.
A
polydimethylsiloxane‐modified
dense
silica
quaternary
ammonium
salt
(QAS)
modified
nanoporous
selected
the
bottom
layer
top
layer,
which
effectively
serve
barrier
an
antireflection
respectively.
The
coated
crystal
shows
excellent
properties
maximum
transmittance
of
99.1%
at
532
nm.
Perfluorooctyltriethoxysilane
vapor
treatment
performed
further
to
improve
mildew.
resultant
exhibits
superior
almost
no
change
in
after
3‐month
exposure
high‐humidity
environment.
introduction
QAS
hydrophobicity
provides
exceptional
against
mildew,
achieving
antimicrobial
rate
99.9%
E.
coli
A.
flavus.
Moreover,
laser‐induced
damage
threshold
reaches
17.0
J
cm
−2
(355
nm,
4.5
ns).
imparts
coatings,
providing
valuable
insights
designing
multifunctional
on
components.
Language: Английский