Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157795 - 157795
Published: Nov. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157795 - 157795
Published: Nov. 1, 2024
Language: Английский
Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 20, 2025
The cation-π interaction is an important noncovalent binding force that impacts all areas of chemistry and biology. Extensive computational gas phase experimental studies have established the potential strength essential nature interaction. Previous reviews emphasized model systems a variety biological examples. This work includes discussion those but emphasizes other are perhaps less well appreciated. These include novel ability alkali metals in water; application to organic synthesis chemical biology; cooperative behaviors multiple interactions, including adhesive proteins from mussels similar organisms formation modulation biomolecular condensates (phase separation); interactions involved recognizing DNA/RNA.
Language: Английский
Citations
2Biomacromolecules, Journal Year: 2025, Volume and Issue: 26(1), P. 689 - 704
Published: Jan. 1, 2025
Chitosan-based materials are known for their excellent biocompatibility and inherent hemostatic properties. However, efficiency is significantly affected by poor wettability mechanical strength. Herein, we developed a novel super elastic sponge from mussel-inspired chitosan modified with long alkyl catechol functional groups (HMCC) via simple freezing-drying procedure. The incorporation of decanal in the HMCC enhances its antimicrobial antioxidant properties facilitates multiple interactions blood cells, thus promoting enrichment rapid hemostasis. Moreover, sponges exhibit high compressibility fluid-induced size recovery capacity, enabling wound shape adaptation to ensure minimizing irritation. In vivo experiments revealed that possessed enhanced procoagulant, hemostasis abilities, favorable degradability could promote healing rat skin model. These results highlight potential as promising solution clinical management major bleeding.
Language: Английский
Citations
1ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 24, 2024
Metal adhesive synthesis typically involves heating and solvents, the resultant adhesives lack degradability suffer from recycling sustainable problems. Herein, we developed a solvent-free chemically degradable biobased (p(Elp-TA)+PVP) thioctic acid (TA), its derivative (Elp), polyvinylpyrrolidone (PVP). Through rapid acid-triggered cationic ring-opening polymerization of dithiolane at ambient conditions, p(Elp-TA)+PVP could build up strong lap shear strength 1123 kPa in air an underwater 534 to copper plate. Molecular dynamics simulations show that compared p(Elp-TA), presence appropriate amount PVP can significantly enhance binding energy molecules metal substrate, adhesion substrates was achieved through synergistically dynamic adaptive network enhanced by hydrogen bonding, reversible coordination bonding 40 ps. More importantly, applied be easily degraded reverted small-molecular-weight lipoic species. Upon exposure dithiothreitol, green reducing agent, average molecular weight quickly decrease 1603 kDa 274 Da. This constructed simple method provides promising general strategy for developing controlled recoverable natural resources.
Language: Английский
Citations
6Biomaterials Science, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
The development of new multi-responsive injectable hydrogels with cascades or even synergistic effects will be great significance in the field precision medicine.
Language: Английский
Citations
4Advances in Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 338, P. 103398 - 103398
Published: Jan. 9, 2025
Biopolymers derived from natural resources are highly abundant, biodegradable, and biocompatible, making them promising candidates to replace non-renewable fossil fuels mitigate environmental health impacts. Nano-fibrous biopolymers possessing advantages of entangle with each other through inter-/intra-molecular interactions, serving as ideal building blocks for gel construction. These biopolymer nanofibers often synergize nano-building enhance gels desirable functions eco-friendliness across various applications in biomedical, environmental, energy sectors. The interactions directly affect the assembly blocks, which determines structure gels, integrity connected influencing mechanical properties performance specific applications. This review focuses on four (cellulose, chitin, silk, collagen), commonly used preparations, representatives polysaccharides polypeptides. covalent non-covalent between materials have been categorized discussed relation resulting network structures properties. Nanomechanical characterization techniques, such surface forces apparatus (SFA) atomic force microscopy (AFM), employed precisely quantify intermolecular blocks. these classified correlated their act "sewing threads", connecting all establish suitable functions. aims provide a comprehensive understanding involved preparation design principles needed achieve targeted functional gels.
Language: Английский
Citations
0International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 142841 - 142841
Published: April 1, 2025
Language: Английский
Citations
0Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: May 16, 2025
Abstract The exceptional underwater adhesion and self‐healing capabilities of mussels have fascinated researchers for over two decades. Extensive studies shown that these remarkable properties arise from a series reversible dynamic molecular interactions involving mussel foot proteins. Inspired by interaction strategies, numerous functional materials exhibiting strong performance been successfully developed. This review systematically explores the nanomechanical mechanisms mussel‐inspired interactions, mainly revealed direct force measurement techniques such as surface forces apparatus atomic microscopy. development materials, including coacervates, coatings, hydrogels, with properties, is then summarized. Furthermore, macroscopic material performances are correlated underlying mechanisms, providing valuable insights rational design next‐generation enhanced properties.
Language: Английский
Citations
0International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: unknown, P. 144336 - 144336
Published: May 1, 2025
Language: Английский
Citations
0Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 542, P. 216868 - 216868
Published: June 6, 2025
Language: Английский
Citations
0Materials Horizons, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
This study presents azobenzene-based hydrogels for photo-controlled, reversible adhesion. The ABOMe ionic hydrogel exhibits strong adhesion, self-healing, and underwater capabilities, advancing the field of smart biomedical wearable adhesives.
Language: Английский
Citations
1