Towards the development of the emerging process of CO₂heterogenous hydrogenation into high-value unsaturated heavy hydrocarbons

Chemical Society Reviews, Journal Year: 2021, Volume and Issue: 50(19), P. 10764 - 10805

Published: Jan. 1, 2021

This review covers recent developments in the synthesis of α-olefins and aromatics from CO 2 hydrogenation via direct indirect routes.

Language: Английский

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Recent advances in CO2 hydrogenation to value-added products — Current challenges and future directions

Progress in Energy and Combustion Science, Journal Year: 2021, Volume and Issue: 85, P. 100905 - 100905

Published: March 13, 2021

Language: Английский

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Remarkably efficient and stable Ni/Y2O3 catalysts for CO2 methanation: Effect of citric acid addition

Applied Catalysis B Environment and Energy, Journal Year: 2021, Volume and Issue: 293, P. 120206 - 120206

Published: April 6, 2021

Language: Английский

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Cu-Based Nanocatalysts for CO₂ Hydrogenation to Methanol

Energy & Fuels, Journal Year: 2021, Volume and Issue: 35(10), P. 8558 - 8584

Published: May 5, 2021

Production of methanol from CO2 hydrogenation is a highly attractive method toward recycling greenhouse gases to form clean, high-value commodity chemicals and fuels, with the aim resolving both environmental issues energy shortages. This review provides an overview Cu-based nanocatalyst development for that has been achieved recently in terms support design, promoter addition, structural improvements, as this line research become very popular. In reaction mechanisms experimental work density functional theory calculations are summarized showcase key factors influencing reaction. The overall yield can be tailored by metal active sites metal–support interaction, well function promoters. technical application challenges production also proposed future directions.

Language: Английский

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Metal-organic framework-derived Ga-Cu/CeO2 catalyst for highly efficient photothermal catalytic CO2 reduction

Applied Catalysis B Environment and Energy, Journal Year: 2021, Volume and Issue: 298, P. 120519 - 120519

Published: July 9, 2021

Language: Английский

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Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles

Nature Catalysis, Journal Year: 2022, Volume and Issue: 5(11), P. 1051 - 1060

Published: Nov. 17, 2022

Language: Английский

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A generalized machine learning framework to predict the space-time yield of methanol from thermocatalytic CO2 hydrogenation

Applied Catalysis B Environment and Energy, Journal Year: 2022, Volume and Issue: 315, P. 121530 - 121530

Published: May 25, 2022

Language: Английский

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Enabling heterogeneous catalysis to achieve carbon neutrality: Directional catalytic conversion of CO₂ into carboxylic acids

Carbon Energy, Journal Year: 2023, Volume and Issue: 6(3)

Published: May 25, 2023

Abstract The increase in anthropogenic carbon dioxide (CO 2 ) emissions has exacerbated the deterioration of global environment, which should be controlled to achieve neutrality. Central core goal achieving neutrality is utilization CO under economic and sustainable conditions. Recently, strong need for led a proliferation studies on direct conversion into carboxylic acids, can effectively alleviate create high‐value chemicals. purpose this review present application prospects acids basic principles through photo‐, electric‐, thermal catalysis. Special attention focused regulation strategy activity abundant catalysts at molecular level, inspiring preparation high‐performance catalysts. In addition, theoretical calculations, advanced technologies, numerous typical examples are introduced elaborate corresponding process influencing factors catalytic activity. Finally, challenges provided future development field. It hoped that will contribute deeper understanding inspire more innovative breakthroughs.

Language: Английский

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Recent advances in CO₂ capture and reduction

Nanoscale, Journal Year: 2022, Volume and Issue: 14(33), P. 11869 - 11891

Published: Jan. 1, 2022

Given the continuous and excessive CO2 emission into atmosphere from anthropomorphic activities, there is now a growing demand for negative carbon technologies, which requires efficient capture conversion of to value-added chemicals. This review highlights recent advances in chemistry processes. It first summarizes various adsorbent materials that have been developed capture, including hydroxide-, amine-, metal organic framework-based adsorbents. then reviews efforts devoted two types reaction: thermochemical hydrogenation electrochemical reduction. While thermal reactions are often accomplished presence H2, realized by direct use electricity can be renewably generated solar wind power. The key success these develop catalysts rationally engineer catalyst-electrolyte interfaces. further covers studies integrating processes so energy efficiency overall optimized. Lastly, briefs some new approaches future directions coupling air technologies as solutions sustainability.

Language: Английский

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Metal-free reduction of CO2 to formate using a photochemical organohydride-catalyst recycling strategy

Nature Chemistry, Journal Year: 2023, Volume and Issue: 15(6), P. 794 - 802

Published: March 23, 2023

Language: Английский

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