Reduction of CO2 to chemicals and Fuels: Thermocatalysis versus electrocatalysis

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 472, P. 145033 - 145033

Published: July 28, 2023

Language: Английский

---

Addressing the CO₂ challenge through thermocatalytic hydrogenation to carbon monoxide, methanol and methane

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(2), P. 490 - 521

Published: Jan. 1, 2023

Addressing the CO 2 challenge is mandatory for well-being of Earth's ecosystem and humanity. catalytic hydrogenation a suitable solution.

Language: Английский

---

The novel contribution of non-noble metal catalysts for intensified carbon dioxide hydrogenation: Recent challenges and opportunities

Energy Conversion and Management, Journal Year: 2023, Volume and Issue: 279, P. 116755 - 116755

Published: Feb. 4, 2023

Language: Английский

---

CO2 hydrogenation to methanol over the copper promoted In2O3 catalyst

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 93, P. 135 - 145

Published: Jan. 24, 2024

Language: Английский

---

Transforming CO2 to valuable feedstocks: Emerging catalytic and technological advances for the reverse water gas shift reaction

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 487, P. 150369 - 150369

Published: March 12, 2024

Language: Английский

---

Copper catalysts for CO2 hydrogenation to CO through reverse water–gas shift reaction for e-fuel production: Fundamentals, recent advances, and prospects

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 492, P. 152283 - 152283

Published: May 19, 2024

E-fuel production, which is achieved using atmospheric or biogenic CO2 and green H2, shows promise for reducing levels curtailing our reliance on fossil fuels. Notably, the hydrogenation of to CO via reverse water–gas shift (RWGS) reaction (CO2 + H2 ↔ H2O) plays a pivotal role in commercial e-fuel production. This approach preferred over direct conversion CO2, remains nascent stage. However, endothermic RWGS energy-intensive it requires high operating temperatures (∼600–800 °C). Therefore, lowering temperature can aid achieving energy efficiency; however, this restricts catalytic activity. Furthermore, low less than 400 °C favor exothermic CH4, resulting CH4 being predominant product instead during hydrogenation. Consequently, studies catalysts have focused as well selectivity low-temperature operation. Among various candidates catalysts, Cu-based are targeted herein particularly potent systems. Cu exhibit selectivity, but face issues such vulnerability sintering. review comprehensively explores from their fundamental properties (effects particle facets, size, dispersion) latest research trends, novel preparation methods (deposition–precipitation, atomic layer deposition, ion sputtering) use supports (CeO2, ZnO, Mo2C) promoters (FeOx alkali metals), future directions spinel oxides layered double hydroxides.

Language: Английский

---

Recent Advances in Hydrogenation of CO₂ to CO with Heterogeneous Catalysts Through the RWGS Reaction

Chemistry - An Asian Journal, Journal Year: 2024, Volume and Issue: 19(4)

Published: Jan. 27, 2024

Abstract With the continuous increase in CO 2 emissions, primarily from combustion of coal and oil, ecosystem faces a significant threat. Therefore, as an effective method to minimize issue, Reverse Water Gas Shift (RWGS) reaction which converts towards attracts much attention, is environmentally‐friendly mitigate climate change lessen dependence on fossil fuels. Nevertheless, inherent thermodynamic stability kinetic inertness big challenge under mild conditions. In addition, it remains another fundamental RWGS owing selectivity issue caused by further hydrogenation CH 4 . Up till now, series catalysis systems have been developed for reduction produce CO. Herein, research progress well‐performed heterogeneous catalysts were summarized, including catalyst design, catalytic performance mechanism. This review will provide insights into efficient utilization promote development reaction.

Language: Английский

---

In–Ni Intermetallic Compounds Derived from Layered Double Hydroxides as Efficient Catalysts toward the Reverse Water Gas Shift Reaction

ACS Catalysis, Journal Year: 2022, Volume and Issue: 12(7), P. 4026 - 4036

Published: March 16, 2022

Intermetallic compounds (IMCs) are widely employed in heterogeneous catalysis. In this paper, the performance and mechanism of In–Ni IMCs with different structures (InNi3, InNi2, InNi, In3Ni2) reverse water gas shift (RWGS) reaction reported. situ spectroscopic microscopic characterizations combined density functional theory (DFT) calculation demonstrated that increase In/Ni ratio enhanced selectivity CO by inhibiting adsorption CO* via "active site isolation." Ni, as active CO2 hydrogenation reaction, was isolated IMCs. Meanwhile, DFT revealed preferentially produced rather than CH4 and/or CH3OH, path for RWGS is redox over IMC. At 500 °C, catalyst achieved a 99.8% at conversion 50.7% more 250 h without any deactivation, rendering it promising candidate industrial application.

Language: Английский

---

Recent advances in metal-organic frameworks for catalytic CO2 hydrogenation to diverse products

Nano Research, Journal Year: 2022, Volume and Issue: 15(12), P. 10110 - 10133

Published: June 30, 2022

Language: Английский

---

Hybrid Catalyst Coupling Zn Single Atoms and CuN_x Clusters for Synergetic Catalytic Reduction of CO₂

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(16)

Published: Feb. 2, 2023

Abstract Reverse water‐gas shift (RWGS) reaction is the initial and necessary step of CO 2 hydrogenation to high value‐added products, regulating selectivity still a fundamental challenge. In present study, an efficient catalyst (CuZnN x @C‐N) composed by Zn single atoms Cu clusters stabilized nitrogen sites reported. It contains saturated four‐coordinate Zn‐N 4 low valence CuN clusters. Monodisperse induces aggregation pyridinic N form structures, which show strong Lewis basicity has adsorption for *CO *COOH intermediates, but weak *CO, thus greatly improves conversion selectivity. The calcined at 700 °C exhibits highest 43.6% under atmospheric pressure, 18.33 times Cu‐ZnO close thermodynamic equilibrium rate (49.9%) . catalytic process, not only adsorbs activates H , also cooperates with adjacent structures jointly activate molecules further promotes This synergistic mechanism will provide new insights developing catalysts.

Language: Английский

---