Visible light-induced PPh3/MI-promoted δ-C(sp3)–H chlorination and cyclization with N-chloro-arylsulfonamides via EDA complexes DOI

Xiaotao Qin,

Hui Liu, Jinkai Hu

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 3, 2024

PPh 3 , MI and N -chloro-arylsulfonamides could generate amidyl radicals via EDA complexes under visible light irradiation, these provide δ-chloro-arylsulfonamide -arylsulfonylpyrrolidine motifs in moderate yields 1,5-HAT process.

Language: Английский

Photoredox-Catalyzed Alkylamination of Alkenes via Oxidative Radical-Polar Crossover and Site-Selective 1,5-Hydrogen Atom Transfer DOI
Tianle Huang, Jianghong Liu,

Zhen-Ye Wu

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(32), P. 6847 - 6852

Published: Aug. 7, 2024

We reported the visible-light-mediated photoredox-catalyzed oxidative radical-polar crossover and 1,5-hydrogen atom transfer combined site-selective remote C(sp

Language: Английский

Citations

4
Aerobic alcoholization via aromatization driven C–C bond cleavage of unstrained ketones DOI
Renzhi Liu, Huiying Zeng

Green Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A novel aerobic aldolization approach that employs aromatization-driven C–C bond cleavage for the deacetylation of unstrained ketones was reported. Various primary and secondary alcohols were generated under oxygen atmosphere without any catalysts.

Language: Английский

Citations

0
Visible-light-driven Net-1,2-Hydrogen Atom Transfer of Amidyl Radicals to Access β-Amido Ketone Derivatives DOI Creative Commons
Yonggang Jiang, Hui Li,

H. Tang

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 3, 2024

Hydrogen atom transfer (HAT) processes provide an important strategy for selective C-H functionalization. Compared with the popularity of 1,5-HAT processes, however, net-1,2-HAT reactions have been reported less frequently. Herein, we report a unique visible-light-mediated amidyl radicals synthesis β-amido ketone derivatives. Single-electron (SET) to

Language: Английский

Citations

2
Azidation and Etherification of Remote C(sp2)–C(sp3) Bonds of Amines Involving 1,4-Aryl Migration DOI
Martin Oestreich, Hendrik F. T. Klare, Phillip Pommerening

et al.

Synfacts, Journal Year: 2024, Volume and Issue: 20(05), P. 0494 - 0494

Published: April 15, 2024

Key words amines - aryl migration azidation C–C bond activation copper catalysis etherification photocatalysis

Language: Английский

Citations

0
Visible light-induced PPh3/MI-promoted δ-C(sp3)–H chlorination and cyclization with N-chloro-arylsulfonamides via EDA complexes DOI

Xiaotao Qin,

Hui Liu, Jinkai Hu

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 3, 2024

PPh 3 , MI and N -chloro-arylsulfonamides could generate amidyl radicals via EDA complexes under visible light irradiation, these provide δ-chloro-arylsulfonamide -arylsulfonylpyrrolidine motifs in moderate yields 1,5-HAT process.

Language: Английский

Citations

0