Recent Advances in the Use of Controlled Nanocatalysts in Methane Conversion Reactions DOI Creative Commons

Felipe Anchieta e Silva,

Thenner S. Rodrigues

Methane, Journal Year: 2024, Volume and Issue: 3(2), P. 359 - 379

Published: June 11, 2024

This study investigates the utilization of controlled nanocatalysts in methane conversion reactions, addressing pressing need for efficient as a feedstock valuable chemicals and clean energy. The methods employed include comprehensive review recent advancements nanocatalyst synthesis, characterization, application, well critical analysis underlying mechanisms controversies activation transformation. main findings reveal significant progress design synthesis nanocatalysts, enabling enhanced activity, selectivity, stability reactions. Moreover, highlights importance resolving surrounding metal–support interactions rational catalyst design. Overall, underscores pivotal role nanotechnology shaping future sustainable energy production, providing insights guiding research directions technological developments this field.

Language: Английский

Current trends in environmental and energy photocatalysis and ISO standardization DOI
Hassan Ali, Milan Masař, Muhammad Yasir

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(6), P. 111541 - 111541

Published: Nov. 23, 2023

Language: Английский

Citations

25
Cu-based catalyst designs in CO2 electroreduction: precise modulation of reaction intermediates for high-value chemical generation DOI Creative Commons

Liangyiqun Xie,

Yujing Jiang, Wenlei Zhu

et al.

Chemical Science, Journal Year: 2023, Volume and Issue: 14(47), P. 13629 - 13660

Published: Jan. 1, 2023

The massive emission of excess greenhouse gases (mainly CO

Language: Английский

Citations

24
Optimizing the reaction pathway of methane photo-oxidation over single copper sites DOI Creative Commons
Chengyang Feng, Shouwei Zuo, Hu Miao

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Oct. 21, 2024

Language: Английский

Citations

15
Contact‐Electro‐Catalysis for Direct Oxidation of Methane under Ambient Conditions DOI
Weixin Li,

Jikai Sun,

Mingda Wang

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(20)

Published: March 16, 2024

Abstract The conversion of methane under ambient conditions has attracted significant attention. Although advancements have been made using active oxygen species from photo‐ and electro‐ chemical processes, challenges such as complex catalyst design, costly oxidants, unwanted byproducts remain. This study exploits the concept contact‐electro‐catalysis, initiating reactions through charge exchange at a solid–liquid interface, to report novel process for directly converting conditions. Utilizing electrification commercially available Fluorinated Ethylene Propylene (FEP) with water ultrasound, we demonstrate how this interaction promote activation molecules. Our results show that yield HCHO CH 3 OH can reach 467.5 151.2 μmol ⋅ g cat −1 , respectively. We utilized electron paramagnetic resonance (EPR) confirm evolution hydroxyl radicals (⋅OH) superoxide (⋅OOH). Isotope mass spectrometry (MS) was employed analyze elemental origin OH, which be further oxidized HCHO. Additionally, conducted density functional theory (DFT) simulations assess reaction energies FEP H 2 O, O 4 these implications methodology, its potential applicability wider array gas‐phase catalytic reactions, underscore advance in catalysis.

Language: Английский

Citations

14
Environmental application of versatile Bi-based perovskite photocatalysts and their Z-scheme and S-scheme heterojunctions DOI
Artem S. Belousov,

Alina A. Parkhacheva,

Artyom N. Markov

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113309 - 113309

Published: June 15, 2024

Language: Английский

Citations

13
Low-Temperature Electrochemical Oxidation of Methane into Alcohols DOI Open Access
Adeel Mehmood, Sang Youn Chae, Eun Duck Park

et al.

Catalysts, Journal Year: 2024, Volume and Issue: 14(1), P. 58 - 58

Published: Jan. 12, 2024

The direct oxidation of methane to methanol is considered challenging due the intrinsically low reactivity C–H bond and formation a large number unstable intermediates (methanol, formaldehyde, formic acid) relative yield methane. However, promising advances have recently been reported in this area based on use electrochemical systems that differ from traditional thermal catalysis. In review, recent indirect conversion with homogeneous catalysts are reviewed discussed, especially under low-temperature conditions. Finally, limitations current technology future research directions discussed.

Language: Английский

Citations

9
Lead-Free Halide Perovskites for Photocatalysis via High-Throughput Exploration DOI
Astita Dubey, Sheryl L. Sanchez, Jonghee Yang

et al.

Chemistry of Materials, Journal Year: 2024, Volume and Issue: 36(5), P. 2165 - 2176

Published: Feb. 27, 2024

This Perspective navigates the transformative synergy between machine learning (ML) techniques and high-throughput (HT) methodologies in realm of photocatalysis, aiming to overcome inefficiencies drawbacks associated with existing photocatalysts. Pb-free hybrid perovskite (HP) nanocrystals (NCs) emerge as promising candidates, offering distinctive physicochemical optical attributes addition nontoxicity. The integration HT automated methods accelerates synthesis characterization novel HP materials while also addressing challenges obtaining large, high-quality data sets for training ML models. proposed multidisciplinary approach, combining experimental computational simulations, aims unravel complexities photocatalytic systems, fostering development innovative strategies development. convergence techniques, is poised revolutionize photocatalysis (PC), propelling field into an era unprecedented discovery innovation.

Language: Английский

Citations

9
Photocatalytic Conversion of Methane to Ethanol at a Three-Phase Interface with Concentration-Matched Hydroxyl and Methyl Radicals DOI

Chun Ju He,

Lan Shang,

Hongfu Zhu

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(17), P. 11968 - 11977

Published: April 17, 2024

The direct oxidation of CH4 to C2H5OH is attractive but challenging owing the intricate processes involving carbon-chain growth and hydroxylation simultaneously. inherent difficulty arises from strong tendency overoxidize in commonly used pressurized powder suspension systems rich reactive oxygen radicals (ROR), which are specifically designed for concentration activation. Meanwhile, nucleophilic attack potent ROR on C–C bond resulting product ultimately leads a higher selectivity C1 oxygenates. This study addresses this multifaceted issue by designing three-phase interface based hydrophilic floating Fe(III)-cross-linked macroporous alginate hydrogel film encapsulated with C3N4 [Fe(III)@ACN] simultaneously enhance accessibility H2O molecules active sites species within channel. properties Fe(III)@ACN allow situ production H2O2 through water reaction under irradiation. concurrent photoinduced Fe(II) triggers Fenton produce •OH. enhanced mass transfer at ensures efficient formation •CH3 reacting •OH, facilitating conversion pathway CH3OH finally •OH present comparable concentrations. Thus, catalyst exhibits remarkable 96% alcohol, achieving 90% alcohol products. rate reaches 171.7 μmol g–1 h–1 without need precious-metal additive.

Language: Английский

Citations

9
Lattice distortion and electronic structure dual engineering of Bi4O5Br2 nanosheets for enhanced photocatalytic activity DOI
Huayang Tian, Yi‐Han Song,

Ruoyang Zhang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161000 - 161000

Published: Feb. 1, 2025

Language: Английский

Citations

1
Understanding Au facet effects in photocatalytic nonoxidative coupling of methane DOI

Zhuo Liu,

Biyang Xu,

Xuanzhao Lu

et al.

Materials Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 8(9), P. 2161 - 2172

Published: Jan. 1, 2024

The strong facet-dependent activity of Au co-catalysts on photocatalytic nonoxidative coupling methane was studied. octahedra with preferentially exposed (111) facets showed the best performance for this reaction.

Language: Английский

Citations

7